New materials will have applications in electronic and optoelectronic devices, electrocatalysis, electroanalysis and sensors
Four different topological types, named UCR-20, UCR-21, UCR-22 and UCR-23, that the new zeolite analog materials possess. Each topological type can be made in a variety of chemical compositions. (A) The 3-dimensional sodalite-based framework in UCR-20. (B) Supertetrahedral clusters are joined into a 6-membered ring in UCR-21 with a cubic ZnS (zinc sulfide) type framework. (C) The 3-dimensional framework of UCR-22 with the cubic ZnS type framework decorated with the core-less supertetrahedral cluster. (D) The 3-dimensional framework of UCR-23 showing channels with the pore size consisting of 16 tetrahedral atoms.
Scientists at the University of California, Riverside have synthesized a large family of semiconducting porous materials that have an unprecedented and diverse chemical composition.
The new materials show several different properties such as photoluminescence, ion exchange, and gas sorption. They also have a large surface area and uniform pore sizes. In addition, they have a pore size larger than zeolites. The synthetic approach has the potential to generate new materials with even larger pore sizes, the scientists report in Science.
Iqbal Pittalwala | University of California - River
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20.07.2018 | Princeton University
Relax, just break it
20.07.2018 | DOE/Argonne National Laboratory
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Whirlpools are an everyday experience in a bath tub: When the water is drained a circular vortex is formed. Typically, such whirls are rather stable. Similar...
Physicists working with Roland Wester at the University of Innsbruck have investigated if and how chemical reactions can be influenced by targeted vibrational excitation of the reactants. They were able to demonstrate that excitation with a laser beam does not affect the efficiency of a chemical exchange reaction and that the excited molecular group acts only as a spectator in the reaction.
A frequently used reaction in organic chemistry is nucleophilic substitution. It plays, for example, an important role in in the synthesis of new chemical...
Optical spectroscopy allows investigating the energy structure and dynamic properties of complex quantum systems. Researchers from the University of Würzburg present two new approaches of coherent two-dimensional spectroscopy.
"Put an excitation into the system and observe how it evolves." According to physicist Professor Tobias Brixner, this is the credo of optical spectroscopy....
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