The combination of ORNL's high-capacity reusable adsorbents and a Florida company's high-surface-area polyethylene fibers creates a material that can rapidly, selectively and economically extract valuable and precious dissolved metals from water.
The material, HiCap, vastly outperforms today's best adsorbents, which perform surface retention of solid or gas molecules, atoms or ions. HiCap also effectively removes toxic metals from water, according to results verified by researchers at Pacific Northwest National Laboratory.
"We have shown that our adsorbents can extract five to seven times more uranium at uptake rates seven times faster than the world's best adsorbents," said Chris Janke, one of the inventors and a member of ORNL's Materials Science and Technology Division.
Results were presented today at the fall meeting of the American Chemical Society in Philadelphia.
HiCap effectively narrows the fiscal gap between what exists today and what is needed to economically extract some of the ocean's estimated 4.5 billion tons of uranium. Although dissolved uranium exists in concentrations of just 3.2 parts per billion, the sheer volume means there would be enough to fuel the world's nuclear reactors for centuries.
The goal of extracting uranium from the oceans began with research and development projects in the 1960s, with Japan conducting the majority of the work. Other countries pursuing this dream include Russia, China, Germany, Great Britain, India, South Korea, Turkey and the United States. Many adsorbent materials have been developed and evaluated, but none has emerged as being economically viable.
What sets the ORNL material apart is that the adsorbents are made from small diameter, round or non-round fibers with high surface areas and excellent mechanical properties. By tailoring the diameter and shape of the fibers, researchers can significantly increase surface area and adsorption capacity. This and ORNL's patent pending technology to manufacture the adsorbent fibers results in a material able to selectively recover metals more quickly and with increased adsorption capacity, thereby dramatically increasing efficiency.
"Our HiCap adsorbents are made by subjecting high-surface area polyethylene fibers to ionizing radiation, then reacting these pre-irradiated fibers with chemical compounds that have a high affinity for selected metals," Janke said.
After the processing, scientists can place HiCap adsorbents in water containing the targeted material, which is quickly and preferentially trapped. Scientists then remove the adsorbents from the water and the metals are readily extracted using a simple acid elution method. The adsorbent can then be regenerated and reused after being conditioned with potassium hydroxide.
In a direct comparison to the current state-of-the-art adsorbent, HiCap provides significantly higher uranium adsorption capacity, faster uptake and higher selectivity, according to test results. Specifically, HiCap's adsorption capacity is seven times higher (146 vs. 22 grams of uranium per kilogram of adsorbent) in spiked solutions containing 6 parts per million of uranium at 20 degrees Celsius. In seawater, HiCap's adsorption capacity of 3.94 grams of uranium per kilogram of adsorbent was more than five times higher than the world's best at 0.74 grams of uranium per kilogram of adsorbent. The numbers for selectivity showed HiCap to be seven times higher.
"These results clearly demonstrate that higher surface area fibers translate to higher capacity," Janke said.
ORNL researchers conducted field tests of the material at the Marine Sciences Laboratory of Pacific Northwest National Laboratory in Sequim, Wash., and at the Rosenstiel School of Marine & Atmospheric Science and Broad Key Island in collaboration with the University of Miami.
Other members of the team include Yatsandra Oyola, Sheng Dai, Richard Mayes, Tomonori Saito, Xiao-Guang Sun, Costas Tsouris of ORNL, and Jim Brang and Jeff Haggard of Hills Inc. of West Melbourne, Fla.
Funding for this project was provided by DOE's Office of Nuclear Energy. HiCap was recognized in June by R&D Magazine as one of the year's most significant technological innovations, winning an R&D 100 Award. UT-Battelle manages ORNL for the Office of Science. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States and is working to address some of the most pressing challenges of our time. For more information, please visit http://science.energy.gov/
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