Neutron scattering has revealed, in real time, the fundamental mechanisms behind the conversion of sunlight into energy in hybrid perovskite materials. A better understanding of this behavior will enable manufacturers to design solar cells with increased efficiency.
The multi-institutional team of researchers from the Department of Energy's Oak Ridge National Laboratory, Hunan University and the University of Nebraska-Lincoln used photoluminescence measurements, along with neutron and x-ray scattering, to study the relationship between the material's microscopic structure and its optoelectronic properties.
By examining the material under varying degrees of temperature, the researchers were able to track atomic structural changes and establish how hydrogen bonding plays a key role in the material's performance. Their results are published in the journal Advanced Materials.
Hybrid perovskites hold promise to be more efficient in converting light into energy than traditional solar cell materials. They are also easier to manufacture as they can be spin cast from solution and do not require high-vacuum chambers for synthesis.
Unlike their singular silicon or germanium counterparts, hybrid perovskites are made of both organic and inorganic molecules. The structure is built from inorganic lead and bromine molecules arranged in octahedral units that form cages around the organic methylammonium cations (positively charged ions) consisting of carbon, nitrogen and hydrogen.
"The advantage of having both organic and inorganic molecules in a well-defined crystal structure means we can tailor the material by tuning either one group or the other to optimize the properties," said Kai Xiao, a researcher at ORNL's Center for Nanophase Materials Sciences.
"But even though researchers have been studying these materials for several years, we still don't fully understand on a fundamental level how the organic components are affecting the properties."
Finding the right combination and molecular orientation of the organic/inorganic components is the key to unlocking more functionality, but understanding those interactions requires the right tools.
"Neutrons are very good at this because they're sensitive to lighter elements like hydrogen," said ORNL instrument scientist Xiaoping Wang. "Because we're able to track each neutron, we get information about things like where the atoms are, what their temperature is, and how they're behaving."
Using the TOPAZ instrument at ORNL's Spallation Neutron Source, the team was able to observe the hydrogen bonding interactions at the atomic scale.
The experiment revealed the material undergoes significant structural changes between approximately 150 and 130 Kelvin (roughly -190 and -225 degrees Fahrenheit). Cooling the material slowed the movement of the organic component into an ordered state, in which precise in situ measurements were made in real time to observe exactly how the organic molecules were binding to the lead-bromine component through hydrogen bonds.
"We saw the ordering is directly related to the hydrogen bonding in the structure, and how any changes can affect the energy gap of the material," said Wang. "That lets us know how well sunlight is being absorbed and what that could mean in terms of applications for photovoltaic materials."
Complementary photoluminescence and x-ray scattering measurements, along with crystal synthesis, were conducted at CNMS. Theoretical calculations were performed by scientists in ORNL's Materials Science and Technology Division.
"Hybrid perovskites are already a good material," said Xiao. "Now that we know how the orientation of the organic molecules impacts the crystal structure, and how we can tune them further to change the desired properties, this new fundamental understanding will enable us to design new materials with even greater potential."
Xiao and Wang's coauthors include lead author Bin Yang, Wenmei Ming, Mao-Hua Du, Jong K. Keum, Alexander A. Puretzky, Christopher M. Rouleau, Jonsong Huang and David B. Geohegan.
The research was supported by DOE's Office of Science. The Spallation Neutron Source and the Center for Nanophase Materials Sciences are DOE Office of Science User Facilities. ORNL is managed by UT-Battelle for the Department of Energy's Office of Science, the single largest supporter of basic research in the physical sciences in the United States. DOE's Office of Science is working to address some of the most pressing challenges of our time. For more information, please visit http://science.
Jeremy Rumsey | EurekAlert!
Theoretical tubulanes inspire ultrahard polymers
14.11.2019 | Rice University
New spin directions in pyrite an encouraging sign for future spintronics
14.11.2019 | ARC Centre of Excellence in Future Low-Energy Electronics Technologies
Nanooptical traps are a promising building block for quantum technologies. Austrian and German scientists have now removed an important obstacle to their practical use. They were able to show that a special form of mechanical vibration heats trapped particles in a very short time and knocks them out of the trap.
By controlling individual atoms, quantum properties can be investigated and made usable for technological applications. For about ten years, physicists have...
An international team of scientists, including three researchers from New Jersey Institute of Technology (NJIT), has shed new light on one of the central mysteries of solar physics: how energy from the Sun is transferred to the star's upper atmosphere, heating it to 1 million degrees Fahrenheit and higher in some regions, temperatures that are vastly hotter than the Sun's surface.
With new images from NJIT's Big Bear Solar Observatory (BBSO), the researchers have revealed in groundbreaking, granular detail what appears to be a likely...
The Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM in Dresden has succeeded in using Selective Electron Beam Melting (SEBM) to...
Carbon nanotubes (CNTs) are valuable for a wide variety of applications. Made of graphene sheets rolled into tubes 10,000 times smaller than a human hair, CNTs have an exceptional strength-to-mass ratio and excellent thermal and electrical properties. These features make them ideal for a range of applications, including supercapacitors, interconnects, adhesives, particle trapping and structural color.
New research reveals even more potential for CNTs: as a coating, they can both repel and hold water in place, a useful property for applications like printing,...
If you've ever tried to put several really strong, small cube magnets right next to each other on a magnetic board, you'll know that you just can't do it. What happens is that the magnets always arrange themselves in a column sticking out vertically from the magnetic board. Moreover, it's almost impossible to join several rows of these magnets together to form a flat surface. That's because magnets are dipolar. Equal poles repel each other, with the north pole of one magnet always attaching itself to the south pole of another and vice versa. This explains why they form a column with all the magnets aligned the same way.
Now, scientists at ETH Zurich have managed to create magnetic building blocks in the shape of cubes that - for the first time ever - can be joined together to...
15.11.2019 | Event News
15.11.2019 | Event News
05.11.2019 | Event News
19.11.2019 | Life Sciences
19.11.2019 | Physics and Astronomy
19.11.2019 | Health and Medicine