The discovery of what is essentially a 3D version of graphene – the 2D sheets of carbon through which electrons race at many times the speed at which they move through silicon – promises exciting new things to come for the high-tech industry, including much faster transistors and far more compact hard drives.
Beamline 10.0.1 at Berkeley Lab’s Advanced Light Source is optimized for the study of for electron structures and correlated electron systems. (Photo by Roy Kaltschmidt)
A collaboration of researchers at the U.S Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) has discovered that sodium bismuthate can exist as a form of quantum matter called a three-dimensional topological Dirac semi-metal (3DTDS).
This is the first experimental confirmation of 3D Dirac fermions in the interior or bulk of a material, a novel state that was only recently proposed by theorists.
“A 3DTDS is a natural three-dimensional counterpart to graphene with similar or even better electron mobility and velocity,” says Yulin Chen, a physicist with Berkeley Lab’s Advanced Light Source (ALS) when he initiated the study that led to this discovery, and now with the University of Oxford.
“Because of its 3D Dirac fermions in the bulk, a 3DTDS also features intriguing non-saturating linear magnetoresistance that can be orders of magnitude higher than the materials now used in hard drives, and it opens the door to more efficient optical sensors.”
Chen is the corresponding author of a paper in Science reporting the discovery. The paper is titled “Discovery of a Three-dimensional Topological Dirac Semimetal, Na3Bi.” Co-authors were Zhongkai Liu, Bo Zhou, Yi Zhang, Zhijun Wang, Hongming Weng, Dharmalingam Prabhakaran, Sung-Kwan Mo, Zhi-Xun Shen, Zhong Fang, Xi Dai and Zahid Hussain.
Two of the most exciting new materials in the world of high technology today are graphene and topological insulators, crystalline materials that are electrically insulating in the bulk but conducting on the surface. Both feature 2D Dirac fermions (fermions that aren’t their own antiparticle), which give rise to extraordinary and highly coveted physical properties. Topological insulators also possess a unique electronic structure, in which bulk electrons behave like those in an insulator while surface electrons behave like those in graphene.
“The swift development of graphene and topological insulators has raised questions as to whether there are 3D counterparts and other materials with unusual topology in their electronic structure,” says Chen. “Our discovery answers both questions. In the sodium bismuthate we studied, the bulk conduction and valence bands touch only at discrete points and disperse linearly along all three momentum directions to form bulk 3D Dirac fermions. Furthermore, the topology of a 3DTSD electronic structure is also as unique as those of topological insulators.”
The discovery was made at the Advanced Light Source (ALS), a DOE national user facility housed at Berkeley Lab, using beamline 10.0.1, which is optimized for electron structure studies. The collaborating research team first developed a special procedure to properly synthesize and transport the sodium bismuthate, a semi-metal compound identified as a strong 3DTDS candidate by co-authors Fang and Dai, theorists with the Chinese Academy of Sciences.
At ALS beamline 10.0.1, the collaborators determined the electronic structure of their material using Angle-Resolved Photoemission Spectroscopy (ARPES), in which x-rays striking a material surface or interface cause the photoemission of electrons at angles and kinetic energies that can be measured to obtain a detailed electronic spectrum.
“ALS beamline 10.0.1 is perfect for exploring new materials, as it has a unique capability whereby the analyzer is moved rather than the sample for the ARPES measurement scans,” Chen says. “This made our work much easier as the cleaved sample surface of our material sometimes has multiple facets, which makes the rotating-sample measurement schemes typically employed for ARPES measurements difficult to carry out.”
Sodium bismuthate is too unstable to be used in devices without proper packaging, but it triggers the exploration for the development of other 3DTDS materials more suitable for everyday devices, a search that is already underway. Sodium bismuthate can also be used to demonstrate potential applications of 3DTDS systems, which offer some distinct advantages over graphene.
“A 3DTDS system could provide a significant improvement in efficiency in many applications over graphene because of its 3D volume,” Chen says. “Also, preparing large-size atomically thin single domain graphene films is still a challenge. It could be easier to fabricate graphene-type devices for a wider range of applications from 3DTDS systems.”
In addition, Chen says, a 3DTDS system also opens the door to other novel physical properties, such as giant diamagnetism that diverges when energy approaches the 3D Dirac point, quantum magnetoresistance in the bulk, unique Landau level structures under strong magnetic fields, and oscillating quantum spin Hall effects. All of these novel properties can be a boon for future electronic technologies. Future 3DTDS systems can also serve as an ideal platform for applications in spintronics.
This research was supported by the DOE Office of Science and by the National Science Foundation of China.
Lawrence Berkeley National Laboratory addresses the world’s most urgent scientific challenges by advancing sustainable energy, protecting human health, creating new materials, and revealing the origin and fate of the universe. Founded in 1931, Berkeley Lab’s scientific expertise has been recognized with 13 Nobel prizes. The University of California manages Berkeley Lab for the U.S. Department of Energy’s Office of Science. For more, visit www.lbl.gov.
The Advanced Light Source is a third-generation synchrotron light source producing light in the x-ray region of the spectrum that is a billion times brighter than the sun. A DOE national user facility, the ALS attracts scientists from around the world and supports its users in doing outstanding science in a safe environment. For more information visit http://www.als.lbl.gov/.
DOE’s Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit the Office of Science website at science.energy.gov/.
Lynn Yarris | EurekAlert!
In borophene, boundaries are no barrier
17.07.2018 | Rice University
Research finds new molecular structures in boron-based nanoclusters
13.07.2018 | Brown University
For the first time ever, scientists have determined the cosmic origin of highest-energy neutrinos. A research group led by IceCube scientist Elisa Resconi, spokesperson of the Collaborative Research Center SFB1258 at the Technical University of Munich (TUM), provides an important piece of evidence that the particles detected by the IceCube neutrino telescope at the South Pole originate from a galaxy four billion light-years away from Earth.
To rule out other origins with certainty, the team led by neutrino physicist Elisa Resconi from the Technical University of Munich and multi-wavelength...
For the first time a team of researchers have discovered two different phases of magnetic skyrmions in a single material. Physicists of the Technical Universities of Munich and Dresden and the University of Cologne can now better study and understand the properties of these magnetic structures, which are important for both basic research and applications.
Whirlpools are an everyday experience in a bath tub: When the water is drained a circular vortex is formed. Typically, such whirls are rather stable. Similar...
Physicists working with Roland Wester at the University of Innsbruck have investigated if and how chemical reactions can be influenced by targeted vibrational excitation of the reactants. They were able to demonstrate that excitation with a laser beam does not affect the efficiency of a chemical exchange reaction and that the excited molecular group acts only as a spectator in the reaction.
A frequently used reaction in organic chemistry is nucleophilic substitution. It plays, for example, an important role in in the synthesis of new chemical...
Optical spectroscopy allows investigating the energy structure and dynamic properties of complex quantum systems. Researchers from the University of Würzburg present two new approaches of coherent two-dimensional spectroscopy.
"Put an excitation into the system and observe how it evolves." According to physicist Professor Tobias Brixner, this is the credo of optical spectroscopy....
Ultra-short, high-intensity X-ray flashes open the door to the foundations of chemical reactions. Free-electron lasers generate these kinds of pulses, but there is a catch: the pulses vary in duration and energy. An international research team has now presented a solution: Using a ring of 16 detectors and a circularly polarized laser beam, they can determine both factors with attosecond accuracy.
Free-electron lasers (FELs) generate extremely short and intense X-ray flashes. Researchers can use these flashes to resolve structures with diameters on the...
13.07.2018 | Event News
12.07.2018 | Event News
03.07.2018 | Event News
17.07.2018 | Information Technology
17.07.2018 | Materials Sciences
17.07.2018 | Power and Electrical Engineering