Copper ions flow like liquid through crystalline structures

An artistic rendition of the intriguing superionic crystalline structure of CuCrSe2, which has copper ions that move like liquid between solid layers of chromium and selenium, giving rise to useful electrical properties. Credit: Oak Ridge National Laboratory/Jill Hemman

Materials scientists have sussed out the physical phenomenon underlying the promising electrical properties of a class of materials called superionic crystals. A better understanding of such materials could lead to safer and more efficient rechargeable batteries than the current standard-bearer of lithium ion.

Becoming a popular topic of study only within the past five years, superionic crystals are a cross between a liquid and a solid. While some of their molecular components retain a rigid crystalline structure, others become liquid-like above a certain temperature, and are able to flow through the solid scaffold.

In a new study, scientists from Duke University, Oak Ridge National Laboratory (ORNL) and Argonne National Laboratory (ANL) probed one such superionic crystal containing copper, chromium and selenium (CuCrSe2) with neutrons and X-rays to determine how the material's copper ions achieve their liquid-like properties. The results appear online on Oct. 8 in the journal Nature Physics.

“When CuCrSe2 is heated above 190 degrees Fahrenheit, its copper ions fly around inside the layers of chromium and selenium about as fast as liquid water molecules move,” said Olivier Delaire, associate professor of mechanical engineering and materials science at Duke and senior author on the study. “And yet, it's still a solid that you could hold in your hand. We wanted to understand the molecular physics behind this phenomenon.”

To probe the copper ions' behavior, Delaire and his colleagues turned to two world-class facilities: the Spallation Neutron Source at Oak Ridge and the Advanced Photon Source at Argonne. Each machine provided a unique piece of the puzzle.

By pinging a large sample of powdered CuCrSe2 made at Oak Ridge with powerful neutrons, the researchers got a wide-scale view of the material's atomic structure and dynamics, revealing both the vibrations of the stiff scaffold of chromium and selenium atoms as well as the random jumps of copper ions within.

For a narrower but more detailed look at vibration modes, the researchers bombarded a tiny single grain of CuCrSe2 crystal with high-resolution X-rays. This allowed them to examine how the rays scattered off of its atoms and how scaffold vibrations enabled shear waves to propagate, a hallmark of solid behavior.

With both sets of information in hand, Delaire's group ran quantum simulations of the material's atomic behavior at the National Energy Research Scientific Computing Center to explain their findings. Below the phase transition temperature of 190 degrees Fahrenheit, the copper atoms vibrate around isolated sites, trapped in pockets of the material's scaffold structure. But above that temperature, they are able to hop randomly between multiple available sites. This allows the copper ions to flow throughout the otherwise solid crystal.

While more work is needed to understand how the copper atoms interact with one another once both sites become occupied, the findings offer clues as to how to use similar materials in future electronic applications.

“Most commercial lithium ion batteries use a liquid electrolyte to transfer ions between the positive and negative terminals of the battery,” Delaire said. “While efficient, this liquid can be dangerously flammable, as many laptop and smartphone owners have unfortunately discovered.”

“There are variants of superionic crystals that contain ions like lithium or sodium that behave like the copper in CuCrSe2,” Delaire said. “If we can understand how superionic crystals work through this study and future research, we could perhaps find a better, solid solution for transporting ions in rechargeable batteries.”

###

This research was supported by the Department of Energy (DE-SC0016166, DE-SC0001299, DE-AC02-06CH11357, DE-AC02-05CH11231, DEAC05-00OR22725).

CITATION: “Selective Breakdown of Phonon Quasiparticles across Superionic Transition in CuCrSe2.” J. L. Niedziela, Dipanshu Bansal, Andrew F. May, Jingxuan Ding, Tyson Lanigan-Atkins, Georg Ehlers, Douglas L. Abernathy, Ayman Said, & Olivier Delaire. Nature Physics, 2018. DOI: 10.1038/s41567-018-0298-2

Media Contact

Ken Kingery
KEN.KINGERY@DUKE.EDU
919-660-8414

 @DukeU

http://www.duke.edu 

Media Contact

Ken Kingery EurekAlert!

All latest news from the category: Materials Sciences

Materials management deals with the research, development, manufacturing and processing of raw and industrial materials. Key aspects here are biological and medical issues, which play an increasingly important role in this field.

innovations-report offers in-depth articles related to the development and application of materials and the structure and properties of new materials.

Back to home

Comments (0)

Write a comment

Newest articles

Lighting up the future

New multidisciplinary research from the University of St Andrews could lead to more efficient televisions, computer screens and lighting. Researchers at the Organic Semiconductor Centre in the School of Physics and…

Researchers crack sugarcane’s complex genetic code

Sweet success: Scientists created a highly accurate reference genome for one of the most important modern crops and found a rare example of how genes confer disease resistance in plants….

Evolution of the most powerful ocean current on Earth

The Antarctic Circumpolar Current plays an important part in global overturning circulation, the exchange of heat and CO2 between the ocean and atmosphere, and the stability of Antarctica’s ice sheets….

Partners & Sponsors