Surprising result could pave way to cheaper, higher capacity batteries
Scientists at three Department of Energy national laboratories have discovered how to keep a promising new type of lithium ion battery cathode from developing a crusty coating that degrades its performance. The solution: Use a simple manufacturing technique to form the cathode material into tiny, layered particles that store a lot of energy while protecting themselves from damage.
These are images of particles made from a promising battery cathode material called NMC. Scientists found a simple method for making layered NMC particles that store more energy while protecting themselves from degradation. The smallest particles, at bottom, are just 100 billionths of a meter in diameter; they clump into larger spherical particles, top. The color image at center shows the uneven distribution of chemical elements on a particle's surface, which is key to its improved performance. The black-and-white images were made with an electron microscope at Brookhaven National Laboratory; color images are based on X-ray studies at SLAC.
Credit: SLAC National Accelerator Laboratory
Test batteries that incorporated this cathode material held up much better when charged and discharged at the high voltages needed to fast-charge electric vehicles, the scientists report in a paper published Jan. 11 in the inaugural issue of Nature Energy.
"We were able to engineer the surface in a way that prevents rapid fading of the battery's capacity," said Yijin Liu, a staff scientist at SLAC National Accelerator Laboratory and a co-author of the report. The results are potentially significant because they pave the way for making lithium-ion batteries that are cheaper and have higher energy density.
Good Nickel, Bad Nickel
Chemistry is at the heart of all lithium-ion rechargeable batteries, which power portable electronics and electric cars by shuttling lithium ions between positive and negative electrodes bathed in an electrolyte solution. As lithium ions move into the cathode, chemical reactions generate electrons that can be routed to an external circuit for use. Recharging pulls lithium ions out of the cathode and sends them to the anode.
Cathodes made of nickel manganese cobalt oxide, or NMC, are an especially hot area of battery research because they can operate at the relatively high voltages needed to store a lot of energy in a very small space.
But while the nickel in NMC gives it a high capacity for storing energy, it's also reactive and unstable, with a tendency to undergo destructive side reactions with the electrolyte. Over time this forms a rock salt-like crust that blocks the flow of lithium ions, said study co-author Huolin Xin of Brookhaven National Laboratory.
In this study, the researchers experimented with ways to incorporate nickel but protect it from the electrolyte.
Particles that Protect Themselves
A team led by Marca Doeff at Lawrence Berkeley National Laboratory sprayed a solution of lithium, nickel, manganese and cobalt through an atomizer nozzle to form droplets that decomposed to form a powder. Repeatedly heating and cooling the powder triggered the formation of tiny particles that assembled themselves into larger, spherical and sometimes hollow structures.
This technique, called spray pyrolysis, is cheap, widely used and easily scaled up for commercial production. And in this case it did something unexpected. Like a cake batter that sorts itself into distinct layers during baking, the NMC particles emerged from the process with their basic ingredients redistributed.
The new structure became clear when the cathode particles were examined in detail at SLAC and Brookhaven. At SLAC's Stanford Synchrotron Radiation Lightsource, Liu and his colleagues used X-rays to probe the particles at a scale of 10-20 microns, or millionths of a meter. At Brookhaven's Center for Functional Nanomaterials, Xin and his team used a scanning transmission electron microscope to zoom in on details as small as billionths of a meter, a realm known as the nanoscale. A Simple Road to Higher Capacity
With both techniques and at every scale they looked, the particles had a different structure than the original starting material. When the SSRL team looked at tiny 3-D areas within the material, for instance, only 70 percent of them contained all three of the starting metals - nickel, manganese and cobalt.
"The particles have more nickel on the inside, to store more energy, and less on the surface, where it would cause problems," Liu said. At the same time, the surface of the particles was enriched in manganese, which acted like a coat of paint to protect the interior.
"We're not the first ones who have come up with idea of decreasing nickel on the surface. But we were able to do it in one step using a very simple procedure," Doeff said. "We still want to increase the nickel content even further, and this gives us a possible avenue for doing that. The more nickel you have, the more practical capacity you may have at voltages that are practical to use."
In future experiments, the researchers plan to probe the NMC cathode with X-rays while it's charging and discharging to see how its structure and chemistry change. They also hope to improve the material's safety: As a metal oxide, it could release oxygen during operation and potentially cause a fire.
"To make a real, functional battery that can be commercialized, you have to look beyond performance," Liu said. "Safety and many other things have to be considered."
Other researchers who contributed to this work were lead author Feng Lin and Matthew Quan of Berkeley Lab; Dennis Nordlund and Tsu-Chien Weng of SLAC; and Lei Cheng of Berkeley Lab and the University of California, Berkeley. This work was supported by DOE's Vehicle Technologies Office. SLAC's Stanford Synchrotron Radiation Lightsource and Brookhaven's Center for Functional Nanomaterials are DOE Office of Science User Facilities.
Portions of this press release were based on press releases from Lawrence Berkeley National Laboratory and Brookhaven National Laboratory.
Citation: F. Lin et al., Nature Energy, 11 January 2016, (0.1038/nenergy.2015.4)
SLAC is a multi-program laboratory exploring frontier questions in photon science, astrophysics, particle physics and accelerator research. Located in Menlo Park, California, SLAC is operated by Stanford University for the U.S. Department of Energy Office of Science. To learn more, please visit http://www.
SLAC National Accelerator Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov.
Andrew Gordon | EurekAlert!
Beyond conventional solution-process for 2-D heterostructure
22.06.2018 | Science China Press
Graphene assembled film shows higher thermal conductivity than graphite film
22.06.2018 | Chalmers University of Technology
In a recent publication in the renowned journal Optica, scientists of Leibniz-Institute of Photonic Technology (Leibniz IPHT) in Jena showed that they can accurately control the optical properties of liquid-core fiber lasers and therefore their spectral band width by temperature and pressure tuning.
Already last year, the researchers provided experimental proof of a new dynamic of hybrid solitons– temporally and spectrally stationary light waves resulting...
Scientists from the University of Freiburg and the University of Basel identified a master regulator for bone regeneration. Prasad Shastri, Professor of...
Moving into its fourth decade, AchemAsia is setting out for new horizons: The International Expo and Innovation Forum for Sustainable Chemical Production will take place from 21-23 May 2019 in Shanghai, China. With an updated event profile, the eleventh edition focusses on topics that are especially relevant for the Chinese process industry, putting a strong emphasis on sustainability and innovation.
Founded in 1989 as a spin-off of ACHEMA to cater to the needs of China’s then developing industry, AchemAsia has since grown into a platform where the latest...
The BMBF-funded OWICELLS project was successfully completed with a final presentation at the BMW plant in Munich. The presentation demonstrated a Li-Fi communication with a mobile robot, while the robot carried out usual production processes (welding, moving and testing parts) in a 5x5m² production cell. The robust, optical wireless transmission is based on spatial diversity; in other words, data is sent and received simultaneously by several LEDs and several photodiodes. The system can transmit data at more than 100 Mbit/s and five milliseconds latency.
Modern production technologies in the automobile industry must become more flexible in order to fulfil individual customer requirements.
An international team of scientists has discovered a new way to transfer image information through multimodal fibers with almost no distortion - even if the fiber is bent. The results of the study, to which scientist from the Leibniz-Institute of Photonic Technology Jena (Leibniz IPHT) contributed, were published on 6thJune in the highly-cited journal Physical Review Letters.
Endoscopes allow doctors to see into a patient’s body like through a keyhole. Typically, the images are transmitted via a bundle of several hundreds of optical...
13.06.2018 | Event News
08.06.2018 | Event News
05.06.2018 | Event News
22.06.2018 | Materials Sciences
22.06.2018 | Earth Sciences
22.06.2018 | Life Sciences