Carbon Nanotube ‘Ink’ May Lead to Thinner, Lighter Transistors and Solar Cells

The method, which involves treating carbon nanotubes with fluorine-based molecules, is reported in the Jan. 9 issue of the journal Science (Vol. 323 No. 234).

The research was jointly led by Graciela B. Blanchet, a research fellow at DuPont, and George Malliaras, Cornell associate professor of materials science and engineering and the Lester B. Knight Director of the Cornell NanoScale Science and Technology Facility. Helen Lu, a research chemist at Dupont, and Mandakini Kanungo, a former Cornell postdoctoral fellow now at Xerox, also worked on the project.

Carbon nanotubes are good candidates for transistors in low-cost, printable electronics, but only after large quantities of them have been converted into semiconductors. When carbon nanotubes are grown in the lab, some are semiconducting but others are metallic, and they are difficult to separate from each other.

This mix is a major drawback in creating transistors from nanotubes, Malliaras said. The Cornell/DuPont team concentrated on a new, inexpensive way to eliminate the metallic tubes, preparing them for such applications as suspension in semiconducting ink for printing.

To do so, the researchers brought fluorine-based molecules into contact with the nanotubes. Through a process called cycloaddition, the fluorine molecules efficiently attacked or converted the metallic nanotubes, leaving the semiconducting tubes alone, and creating a perfect batch of solely semiconducting nanotubes.

“Our work suggests that careful control of the chemical reaction enables the complete conversion of metallic tubes without the degradation of semiconducting tubes,” Blanchet said.

The work should lead to exploration of a wide range of devices, such as novel organic photovoltaic structures, Malliaras added.

For the past several years, scientists from Cornell and DuPont have worked together on a variety of projects involving flexible electronics. The research is funded by a grant from the U.S. Air Force for developing transistors from carbon nanotubes.

Media Contact

Blaine Friedlander Newswise Science News

All latest news from the category: Life Sciences and Chemistry

Articles and reports from the Life Sciences and chemistry area deal with applied and basic research into modern biology, chemistry and human medicine.

Valuable information can be found on a range of life sciences fields including bacteriology, biochemistry, bionics, bioinformatics, biophysics, biotechnology, genetics, geobotany, human biology, marine biology, microbiology, molecular biology, cellular biology, zoology, bioinorganic chemistry, microchemistry and environmental chemistry.

Back to home

Comments (0)

Write a comment

Newest articles

Lighting up the future

New multidisciplinary research from the University of St Andrews could lead to more efficient televisions, computer screens and lighting. Researchers at the Organic Semiconductor Centre in the School of Physics and…

Researchers crack sugarcane’s complex genetic code

Sweet success: Scientists created a highly accurate reference genome for one of the most important modern crops and found a rare example of how genes confer disease resistance in plants….

Evolution of the most powerful ocean current on Earth

The Antarctic Circumpolar Current plays an important part in global overturning circulation, the exchange of heat and CO2 between the ocean and atmosphere, and the stability of Antarctica’s ice sheets….

Partners & Sponsors