Power and Electrical Engineering

Durable, Efficient, Sustainable: The Rise of Cerium Oxide Thermal Switches

High-performance cerium oxide-based thermal switch for efficient heat flow control and sustainable energy systems.

An artistic representation of a thermal switch. (Illustration provided by Hiromichi Ohta). Copyright: Hiromichi Ohta

Groundbreaking cerium oxide-based thermal switches achieve remarkable performance, transforming heat flow control with sustainable and efficient technology.

Cerium Oxide-Based Thermal Switches Revolutionize Heat Flow Control

Thermal switches, which electrically control heat transfer, are essential for the advancement of sophisticated thermal management systems. Historically, electrochemical thermal switches have been constrained by suboptimal performance, which impedes their extensive utilization in the electronics, energy, and waste heat recovery sectors.

A Novel Approach: Cerium Oxide Thin Films

(From left) Hiromichi Ohta, Mitsuki Yoshimura and Ahrong Jeong of the research team. (Photo: Hiromichi Ohta). Copyright: Hiromichi Ohta

A research team led by Professor Hiromichi Ohta of the Research Institute for Electronic Science, Hokkaido University employed a novel approach of using cerium oxide (CeO2) thin films as the active material in thermal switches, providing a highly efficient and sustainable alternative. Their findings have been published in Science Advances.

Exceptional Performance Metrics

Schematic device structure of a CeO2-based solid-state electrochemical thermal switch. (Ahrong Jeong, Mitsuki Yoshimura, et al. Science Advances. January 1, 2025). Copyright: Ahrong Jeong, Mitsuki Yoshimura, et al. Science Advances. January 1, 2025

The research team showed that CeO2-based thermal switch performance can exceed prior benchmarks. “The novel device features an on/off thermal conductivity ratio of 5.8 and a thermal conductivity (κ)-switching width of 10.3 W/m·K, establishing a new benchmark for electrochemical thermal switches,” Ohta explains. “The thermal conductivity in its minimal state (off-state) is 2.2 W/m·K, but in the oxidized state (on-state), it significantly rises to 12.5 W/m·K. These performance metrics remain consistent after 100 cycles of reduction and oxidation, demonstrating remarkable durability and reliability for extended usage in practical applications.”

Sustainability and Abundance of Cerium Oxide

Photograph of a CeO2-based thermal switch operating at 280 °C in air. (Ahrong Jeong, Mitsuki Yoshimura, et al. Science Advances. January 1, 2025). Copyright: Ahrong Jeong, Mitsuki Yoshimura, et al. Science Advances. January 1, 2025.

A notable benefit of this technology is the utilization of cerium oxide, a substance abundant in the earth, recognized for its economic viability and ecological sustainability. In contrast to conventional thermal switches that depend on scarce and costly materials, CeO2 offers a sustainable and readily available alternative, reducing expenses and the ecological footprint of thermal management solutions. This enhances the technology’s efficiency, scalability, and applicability across diverse industrial sectors.

Evolutionary Applications Across Industries

The development of CeO2-based thermal switches represents a significant breakthrough in thermal management technology, offering broad applications across industries such as electronics cooling and renewable energy systems. These switches, utilized in thermal shutters and advanced displays, efficiently regulate infrared heat transfer, enhance waste heat recovery, and contribute to energy-efficient systems.

Original Source: https://www.global.hokudai.ac.jp/blog/revolutionizing-heat-management-with-high-performance-cerium-oxide-thermal-switches/

Expert Contact
Professor Hiromichi Ohta
Hokkaido University
Email: hiromichi.ohta@es.hokudai.ac.jp
Phone Number (Office): +81-11-706-9428
Website address: https://www.global.hokudai.ac.jp/

Original Publication
Ahrong Jeong, Mitsuki Yoshimura, Hyeonjun Kong, Zhiping Bian, Jason Tam, Bin Feng, Yuichi Ikuhara, Takashi Endo, Yasutaka Matsuo, and Hiromichi Ohta 
Journal: Science Advances
Article Title: High-performance solid-state electrochemical thermal switches with earth-abundant cerium oxide
Article Publication Date: 1-Jan-2025
DOI: 10.1126/sciadv.ads6137

Media Contact
Sohail Keegan Pinto
Hokkaido University
Phone Number (Office): +81-11-706-2186
Email ID:
en-press@general.hokudai.ac.jp

Source: EurekAlert! (https://www.eurekalert.org/news-releases/1069037)

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