Future computers may run a little sweeter, thanks to a refinement in the manufacture of graphene at Rice University.
Rice researchers have learned to make pristine sheets of graphene, the one-atom-thick form of carbon, from plain table sugar and other carbon-based substances. They do so in a one-step process at temperatures low enough to make graphene easy to manufacture.
The lab of Rice chemist James Tour reported in the online version of the journal Nature this week that large-area, high-quality graphene can be grown from a number of carbon sources at temperatures as low as 800 degrees Celsius (1,472 F). As hot as that may seem, the difference between running a furnace at 800 and 1,000 degrees Celsius is significant, Tour said.
"At 800 degrees, the underlying silicon remains active for electronics, whereas at 1,000 degrees, it loses its critical dopants," said Tour, Rice's T.T. and W.F. Chao Chair in Chemistry as well as a professor of mechanical engineering and materials science and of computer science.
Zhengzong Sun, a fourth-year graduate student in Tour's lab and primary author of the paper, found that depositing carbon-rich sources on copper and nickel substrates produced graphene in any form he desired: single-, bi- or multilayer sheets that could be highly useful in a number of applications.
Sun and his colleagues also found the process adapts easily to producing doped graphene; this allows the manipulation of the material's electronic and optical properties, which is important for making switching and logic devices.
For pristine graphene, Sun started with a thin film of poly (methyl methacrylate) (PMMA) -- perhaps best known in its commercial guise as Plexiglas -- spun onto a copper substrate that acted as a catalyst. Under heat and low pressure, flowing hydrogen and argon gas over the PMMA for 10 minutes reduced it to pure carbon and turned the film into a single layer of graphene. Changing the gas-flow rate allowed him to control the thickness of the PMMA-derived graphene.
Then it got more interesting, Sun said. He turned to other carbon sources, including a fine powder of sucrose -- aka table sugar. "We thought it would be interesting to try this stuff," Sun said. "While other labs were changing the metal catalysts, we tried changing the carbon sources."
Sun put 10 milligrams of sugar (and later fluorene) on a square-centimeter sheet of copper foil and subjected it to the same reactor conditions as the PMMA. It was quickly transformed into single-layer graphene. Sun had expected defects in the final product, given the chemical properties of both substances (a high concentration of oxygen in sucrose, five-atom rings in fluorene); but he found potential topological defects would self-heal as the graphene formed.
"As we looked deeper and deeper into the process, we found it was not only interesting, but useful," Sun said.
He tried and failed to grow graphene on silicon and silicon oxide, which raised the possibility of growing patterned graphene from a thin film of shaped copper or nickel deposited onto silicon wafers.
Doped graphene opens more possibilities for electronics use, Tour said, and Sun found it fairly simple to make. Starting with PMMA mixed with a doping reagent, melamine, he discovered that flowing the gas under atmospheric pressure produced nitrogen-doped graphene. Pristine graphene has no bandgap, but doped graphene allows control of the electrical structure, which the team proved by building field-effect transistors.
"Each day, the growth of graphene on silicon is approaching industrial-level readiness, and this work takes it an important step further," Tour said.
Co-authors of the study were Rice graduate students Zheng Yan, Jun Yao and Elvira Beitler and postdoctoral research associate Yu Zhu.
The Air Force Office of Scientific Research and the Office of Naval Research Multidisciplinary Research Program on graphene supported the research.
David Ruth | EurekAlert!
Astronomers find unexpected, dust-obscured star formation in distant galaxy
24.03.2017 | University of Massachusetts at Amherst
Gravitational wave kicks monster black hole out of galactic core
24.03.2017 | NASA/Goddard Space Flight Center
Astronomers from Bonn and Tautenburg in Thuringia (Germany) used the 100-m radio telescope at Effelsberg to observe several galaxy clusters. At the edges of these large accumulations of dark matter, stellar systems (galaxies), hot gas, and charged particles, they found magnetic fields that are exceptionally ordered over distances of many million light years. This makes them the most extended magnetic fields in the universe known so far.
The results will be published on March 22 in the journal „Astronomy & Astrophysics“.
Galaxy clusters are the largest gravitationally bound structures in the universe. With a typical extent of about 10 million light years, i.e. 100 times the...
Researchers at the Goethe University Frankfurt, together with partners from the University of Tübingen in Germany and Queen Mary University as well as Francis Crick Institute from London (UK) have developed a novel technology to decipher the secret ubiquitin code.
Ubiquitin is a small protein that can be linked to other cellular proteins, thereby controlling and modulating their functions. The attachment occurs in many...
In the eternal search for next generation high-efficiency solar cells and LEDs, scientists at Los Alamos National Laboratory and their partners are creating...
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are less stable. Now researchers at the Technical University of Munich (TUM) have, for the first time ever, produced a composite material combining silicon nanosheets and a polymer that is both UV-resistant and easy to process. This brings the scientists a significant step closer to industrial applications like flexible displays and photosensors.
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are...
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to simulate these confined natural conditions in artificial vesicles for the first time. As reported in the academic journal Small, the results are offering better insight into the development of nanoreactors and artificial organelles.
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to...
20.03.2017 | Event News
14.03.2017 | Event News
07.03.2017 | Event News
24.03.2017 | Materials Sciences
24.03.2017 | Physics and Astronomy
24.03.2017 | Physics and Astronomy