Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Researchers Help Show New Way to Study and Improve Catalytic Reactions

24.07.2013
University of Pennsylvania leads collaboration to test catalyst structures and enhance nanotechnology performance and fabrication

Catalysts are everywhere. They make chemical reactions that normally occur at extremely high temperatures and pressures possible within factories, cars and the comparatively balmy conditions within the human body. Developing better catalysts, however, is mainly a hit-or-miss process.


Matteo Cargnello

By precisely designing a series of nanocrystals with different sizes, shapes and compositions, researchers showed that the efficiency of certain catalysts depends on the interface between their two materials.

Now, a study by researchers at the University of Pennsylvania, the University of Trieste and Brookhaven National Laboratory has shown a way to precisely design the active elements of a certain class of catalysts, showing which parameters are most critical for improving performance.

This highly controlled process could be a new paradigm for fine-tuning catalysts used in everything from making new materials to environmental remediation.

The research is the result of a highly collaborative effort between the three institutions. It was led by Christopher Murray, a Penn Integrates Knowledge Professor with appointments in the Department of Chemistry in the School of Arts and Sciences and the Department of Materials Science and Engineering in the School of Engineering and Applied Science, and Matteo Cargnello, a postdoctoral fellow in Murray's group. Cargnello was a graduate student in Paolo Fornasiero's group at the University of Trieste when the research began and also worked with Raymond Gorte, professor in the Department of Chemical and Biomolecular Engineering, after coming to Penn. Penn graduate students Vicky Doan-Nguyen and Thomas R. Gordon, as well as Brookhaven's Rosa Diaz and Eric Stach, also contributed to the study.

It was published in the journal Science.

Murray's team set out to improve the process for designing a class of reaction-promoting materials known as supported catalysts. These catalysts are made of two different solid substances—one supporting the other—but existing techniques for fabricating them don't provide much in the way of precisely controlling their parameters. Because of the lack of uniformity in conventional catalysts, it can be difficult to tell which aspects of their combination lead to better systems.

"In putting together materials design, functional testing and state-of-the art-characterization tools, we're looking to develop a feedback loop," Murray said. "Improving our understanding about the active components of these catalysts can tell us what to emphasize in future systems."

Capitalizing on the Murray lab's expertise in creating nanocrystals with precisely defined sizes, shapes and compositions, the researchers created a series of supported catalysts and tested them against one another on a model catalytic reaction: the oxidation of carbon monoxide.

This basic example of catalysis is also common in real-world applications, as it turns carbon monoxide, which is toxic, into carbon dioxide. Carbon monoxide is a common byproduct of the incomplete combustion of organic compounds, so it is produced in car engines and many industrial processes. Catalytic filters and converters are often required by law to cut down carbon monoxide pollution.

Catalysts are often used for this reaction as simply adding carbon monoxide and oxygen in an enclosed chamber is not sufficient to cause them to combine. Without additional pressure or heat—up to several hundreds of degrees Celsius—the gas molecules do not collide frequently or energetically enough to produce carbon dioxide.

Adding a catalyst is a more efficient alternative to adding heat or pressure. The catalyst materials are not consumed during the reaction but provide a template of sorts that helps the reactants find one another and bond. This active material is typically a metal, as metallic elements are able to form many kinds of bonds. Increasing the surface area of this material increases the reaction rate, as it provides more places for the reacting molecules to bond, so the metal is often broken down to as small particles as possible.

These small metal particles are often deposited on the second material—a support—which is typically made of a metal oxide. Supports are generally inert, simply providing a thermally stable platform for the metal particles, but some are "active" in that they are also involved in the bonds that speed along the catalytic reaction. For carbon monoxide oxidation using active supports, it is theorized that the metal particles hold carbon monoxide molecules while the support donates oxygen molecules, bringing the two gases together in a more consistent and faster way than if both had to bond to the metal alone.

This theory would suggest that increasing the percentage of atoms at the interface between the metal particles and the support is more important than increasing the surface area of the metal.

"For this family of supported catalysts, however, we had only fragmentary knowledge about what regions of the whole catalytic system are critically active," Murray said. "Now, with better tools and the ability to make better samples, we can go in and pull out the things that really matter."

To test the theory, the researchers made nanocrystals of three sizes with three metals: nickel, palladium and platinum. They then deposited these nanocrystals on both an inert support, aluminum oxide, and an active support, cerium oxide. Transmission electron microscopy, performed at Brookhaven, was critical in enabling the researchers to confirm each of the 18 combinations came together correctly prior to comparing their performances in the carbon monoxide oxidation reaction.

The results began to confirm their hypothesis.

"For the aluminum oxide support," Cargnello said, "there was basically no difference in the catalytic activity between the different sizes of particles when normalized per number of metal atoms, which is what the literature has suggested for the past few decades. The surprise came when, in Trieste, we tested the cerium oxide supported samples, where we found that the smaller particles were more active than the larger ones, on the same basis. That means that structural differences in the particles were related to the different active sites for the reaction."

Returning the 18 combinations to Brookhaven, the researchers used the transmission electron microscope to create a computer model of the interfaces between the nanocrystals and supports. Able to count the individual atoms in this model, they saw that, the greater the proportion of a nanocrystal's atoms were at the interface with the support, the better it performed.

"We saw this proportion made a much bigger difference in the catalyst performance than the material the nanocrystals were made of," Cargnello said. "This is important in that nickel is much less expensive than platinum and palladium, so, if we can figure out how to fine-tune nickel nanocrystals, we may be able to make much cheaper catalysts that work just as well."

More than showing a path to improving this particular reaction, the study represents a new way of studying catalytic reactions in general, as well as a more straight-forward way of designing the materials at their core.

"We're flipping the vision of catalysis," Cargnello said. "Usually, people see that a material performs well, then study its structure to determine why it behaves the way it does. Here, we're preparing the structure based on how we think the material is going to be behave, then see how it performs."

The research was supported by European Cooperation in Science and Technology, the U.S. Department of Energy through its Office of Basic Energy Sciences and its Advanced Research Projects Agency, the National Science Foundation through Penn's Nano/Bio Interface Center and the Air Force Office of Scientific Research.

Thomas R. Gordon is now a postdoctoral fellow at Pennsylvania State University.

NOTE: This press release was issued by the University of Pennsylvania. Scientists Rosa Diaz and Eric Stach of Brookhaven National Laboratory's Center for Functional Nanomaterials (CFN) combined results from two electron microscopes to reveal crucial information on the size and configuration of the catalysts. The collaboration correlated the CFN structural analysis with reactivity tests to determine the active sites of the catalysts.

University of Pennsylvania Media contact: Evan Lerner at elerner@upenn.edu

Justin Eure | Newswise
Further information:
http://www.bnl.gov

More articles from Physics and Astronomy:

nachricht Tiny lasers from a gallery of whispers
20.09.2017 | American Institute of Physics

nachricht New quantum phenomena in graphene superlattices
19.09.2017 | Graphene Flagship

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Tiny lasers from a gallery of whispers

New technique promises tunable laser devices

Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...

Im Focus: Ultrafast snapshots of relaxing electrons in solids

Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!

When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...

Im Focus: Quantum Sensors Decipher Magnetic Ordering in a New Semiconducting Material

For the first time, physicists have successfully imaged spiral magnetic ordering in a multiferroic material. These materials are considered highly promising candidates for future data storage media. The researchers were able to prove their findings using unique quantum sensors that were developed at Basel University and that can analyze electromagnetic fields on the nanometer scale. The results – obtained by scientists from the University of Basel’s Department of Physics, the Swiss Nanoscience Institute, the University of Montpellier and several laboratories from University Paris-Saclay – were recently published in the journal Nature.

Multiferroics are materials that simultaneously react to electric and magnetic fields. These two properties are rarely found together, and their combined...

Im Focus: Fast, convenient & standardized: New lab innovation for automated tissue engineering & drug

MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems Holding GmbH about commercial use of a multi-well tissue plate for automated and reliable tissue engineering & drug testing.

MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems...

Im Focus: Silencing bacteria

HZI researchers pave the way for new agents that render hospital pathogens mute

Pathogenic bacteria are becoming resistant to common antibiotics to an ever increasing degree. One of the most difficult germs is Pseudomonas aeruginosa, a...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

“Lasers in Composites Symposium” in Aachen – from Science to Application

19.09.2017 | Event News

I-ESA 2018 – Call for Papers

12.09.2017 | Event News

EMBO at Basel Life, a new conference on current and emerging life science research

06.09.2017 | Event News

 
Latest News

Molecular Force Sensors

20.09.2017 | Life Sciences

Producing electricity during flight

20.09.2017 | Power and Electrical Engineering

Tiny lasers from a gallery of whispers

20.09.2017 | Physics and Astronomy

VideoLinks
B2B-VideoLinks
More VideoLinks >>>