In the June issue of the journal Nature Nanotechnology, Ohio State University researchers describe how they created surfaces that, seen with the eye, look as flat and transparent as a sheet of glass. But seen up close, the surfaces are actually carpeted with tiny fibers.
The patent-pending technology involves a method for growing a bed of fibers of a specific length, and using chemical treatments to tailor the fibers' properties, explained Arthur J. Epstein, Distinguished University Professor of chemistry and physics and director of the university's Institute for Magnetic and Electronic Polymers.
"One of the good things about working with these polymers is that you're able to structure them in many different ways," Epstein said. "Plus, we found that we can coat almost any surface with these fibers."
For this study, the scientists grew fibers of different heights and diameters, and were able to modify the fibers' molecular structures by exposing them to different chemicals.
They devised one treatment that made the fibers attract water, and another that made the fibers repel water. They found they could also make the surfaces attract or repel oil. Depending on what polymer they start with, the fibers can also be made to conduct electricity.
The ability to tailor the properties of the fibers opens the surface to many different applications, he said.
Since dirt, water, and oil don't stick to the repellant fibers, windows coated with them would stay cleaner longer.In contrast, the attracting fibers would make a good anti-fog coating, because they pull at water droplets and cause them to spread out flat on the surface.
Epstein said scientists could use the fibers as a platform to study how DNA interacts with other molecules. They could also use the spread-out DNA to build new nanostructures.
"We're very excited about where this kind of development can take us," he added.
Epstein's research centers on polymers that conduct electricity, and light up or change color. Depending on the choice of polymer, the nano-fiber surface can also conduct electricity. The researchers were able to use the surface to charge an organic light-emitting device -- a find that could pave the way for transparent plastic electronics.
Finally, they also showed that the fibers could be used to control the flow of water in microfluidic devices --- a specialty of study co-author L. James Lee, professor of chemical and biomolecular engineering and head of Ohio State's Center for Affordable Nanoengineering of Polymeric Biomedical Devices.
Lee and Epstein are advisors to former graduate student Nan-Rong Chiou, who developed the technology to earn his doctorate. He is now a visiting scholar at the university. Other co-authors on the paper included former doctoral students Chunmeng Lu and Jingjiao Guan.
The technology is a merger of two different chemical processes for growing polymer molecules: one grows tiny dots of polymer "seeds" on a flat surface, and the other grows vertical fibers out from the top of the seeds. The fibers grow until the scientists cut off the chemical reaction, forming a carpet of uniform height.
The university will license the technology, and Epstein and his colleagues are looking for new applications for it.
Aside from anti-fog windows, self-cleaning windows, and organic LEDs, Chiou said that he foresees the surfaces working in glucose sensors, gene therapy devices, artificial muscles, field emission displays, and electromagnetic interference shielding.
This research was partially funded by the National Science Foundation.
Arthur J. Epstein | EurekAlert!
A tale of two pulsars' tails: Plumes offer geometry lessons to astronomers
18.01.2017 | Penn State
Studying fundamental particles in materials
17.01.2017 | Max-Planck-Institut für Struktur und Dynamik der Materie
Yersiniae cause severe intestinal infections. Studies using Yersinia pseudotuberculosis as a model organism aim to elucidate the infection mechanisms of these...
Researchers from the University of Hamburg in Germany, in collaboration with colleagues from the University of Aarhus in Denmark, have synthesized a new superconducting material by growing a few layers of an antiferromagnetic transition-metal chalcogenide on a bismuth-based topological insulator, both being non-superconducting materials.
While superconductivity and magnetism are generally believed to be mutually exclusive, surprisingly, in this new material, superconducting correlations...
Laser-driving of semimetals allows creating novel quasiparticle states within condensed matter systems and switching between different states on ultrafast time scales
Studying properties of fundamental particles in condensed matter systems is a promising approach to quantum field theory. Quasiparticles offer the opportunity...
Among the general public, solar thermal energy is currently associated with dark blue, rectangular collectors on building roofs. Technologies are needed for aesthetically high quality architecture which offer the architect more room for manoeuvre when it comes to low- and plus-energy buildings. With the “ArKol” project, researchers at Fraunhofer ISE together with partners are currently developing two façade collectors for solar thermal energy generation, which permit a high degree of design flexibility: a strip collector for opaque façade sections and a solar thermal blind for transparent sections. The current state of the two developments will be presented at the BAU 2017 trade fair.
As part of the “ArKol – development of architecturally highly integrated façade collectors with heat pipes” project, Fraunhofer ISE together with its partners...
At TU Wien, an alternative for resource intensive formwork for the construction of concrete domes was developed. It is now used in a test dome for the Austrian Federal Railways Infrastructure (ÖBB Infrastruktur).
Concrete shells are efficient structures, but not very resource efficient. The formwork for the construction of concrete domes alone requires a high amount of...
10.01.2017 | Event News
09.01.2017 | Event News
05.01.2017 | Event News
18.01.2017 | Power and Electrical Engineering
18.01.2017 | Materials Sciences
18.01.2017 | Life Sciences