Based on arrays containing as many as 20,000 zinc oxide nanowires in each nanogenerator, the devices can produce up to 1.2 volts of output voltage, and are fabricated with a chemical process designed to facilitate low-cost manufacture on flexible substrates. Tests done with nearly one thousand nanogenerators – which have no mechanical moving parts – showed that they can be operated over time without loss of generating capacity.
Details of the improved nanogenerator and self-powered nanosensors were scheduled to be reported March 28 in the journal Nature Nanotechnology. The research was supported by the National Science Foundation, the Defense Advanced Research Projects Agency, and the U.S. Department of Energy.
“We have demonstrated a robust way to harvest energy and use it for powering nanometer-scale sensors,” said Zhong Lin Wang, a Regents professor in the School of Materials Science and Engineering at the Georgia Institute of Technology. “We now have a technology roadmap for scaling these nanogenerators up to make truly practical applications.”
For the past five years, Wang’s research team has been developing nanoscale generators that use the piezoelectric effect – which produces electrical charges when wires made from zinc oxide are subjected to strain. The strain can be produced by simply flexing the wires, and current from many wires can be constructively combined to power small devices. The research effort has recently focused on increasing the amount of current and voltage generated and on making the devices more robust.
In the paper, Wang and collaborators report on a new configuration for the nanowires that embeds both ends of the tiny structures in a polymer substrate. The wires can then generate current as they are compressed in a flexible nanogenerator enclosure, eliminating the contact with a metallic electrode that was required in earlier devices. Because the generators are completely enclosed, they can be used in a variety of environments.
“We can now grow the wires chemically on substrates that are foldable and flexible and the processing can now be done at substrate temperatures of less than 100 degrees Celsius – about the temperature of coffee,” explained Wang. “That will allow lower cost fabrication and growth on just about any substrate.”
The nanogenerators are produced using a multi-step process that includes fabrication of electrodes that provide both Ohmic and Shottky contacts for the nanowires. The arrays can be grown both vertically and laterally. To maximize current and voltage, the growth and assembly requires alignment of crystalline growth, as well as the synchronization of charging and discharging cycles.
Production of vertical nanogenerators begins with growing zinc oxide nanowires on a gold-coated surface using a wet chemical method. A layer of polymethyl-methacrylate is then spun-coated onto the nanowires, covering them from top to bottom. Oxygen plasma etching is then performed, leaving clean tips on which a piece of silicon wafer coated with platinum is placed. The coated silicon provides a Shottky barrier, which is essential for maintaining electrical current flow.
The alternating current output of the nanogenerators depends on the amount of strain applied. “At a strain rate of less than two percent per second, we can produce output voltage of 1.2 volts,” said Wang. “The power output is matched with the external load.”
Lateral nanogenerators integrating 700 rows of zinc oxide nanowires produced a peak voltage of 1.26 volts at a strain of 0.19 percent. In a separate nanogenerator, vertical integration of three layers of zinc oxide nanowire arrays produced a peak power density of 2.7 milliwatts per cubic centimeter.
Wang’s team has so far produced two tiny sensors that are based on zinc oxide nanowires and powered by the nanogenerators. By measuring the amplitude of voltage changes across the device when exposed to different liquids, the pH sensor can measure the acidity of liquids. An ultraviolet nanosensor depends on similar voltage changes to detect when it is struck by ultraviolet light.
In addition to Wang, the team authoring the paper included Sheng Xu, Yong Qin, Chen Xu, Yaguang Wei, and Rusen Wang, all from Georgia Tech’s School of Materials Science and Engineering.
The new generator and nanoscale sensors open new possibilities for very small sensing devices that can operate without batteries, powered by mechanical energy harvested from the environment. Energy sources could include the motion of tides, sonic waves, mechanical vibration, the flapping of a flag in the wind, pressure from shoes of a hiker or the movement of clothing.
“Building devices that are small isn’t sufficient,” Wang noted. “We must also be able to power them in a sustainable way that allows them to be mobile. Using our new nanogenerator, we can put these devices into the environment where they can work independently and sustainably without requiring a battery.”
John Toon | Newswise Science News
Astronomers find unexpected, dust-obscured star formation in distant galaxy
24.03.2017 | University of Massachusetts at Amherst
Gravitational wave kicks monster black hole out of galactic core
24.03.2017 | NASA/Goddard Space Flight Center
Astronomers from Bonn and Tautenburg in Thuringia (Germany) used the 100-m radio telescope at Effelsberg to observe several galaxy clusters. At the edges of these large accumulations of dark matter, stellar systems (galaxies), hot gas, and charged particles, they found magnetic fields that are exceptionally ordered over distances of many million light years. This makes them the most extended magnetic fields in the universe known so far.
The results will be published on March 22 in the journal „Astronomy & Astrophysics“.
Galaxy clusters are the largest gravitationally bound structures in the universe. With a typical extent of about 10 million light years, i.e. 100 times the...
Researchers at the Goethe University Frankfurt, together with partners from the University of Tübingen in Germany and Queen Mary University as well as Francis Crick Institute from London (UK) have developed a novel technology to decipher the secret ubiquitin code.
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Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are less stable. Now researchers at the Technical University of Munich (TUM) have, for the first time ever, produced a composite material combining silicon nanosheets and a polymer that is both UV-resistant and easy to process. This brings the scientists a significant step closer to industrial applications like flexible displays and photosensors.
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are...
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to simulate these confined natural conditions in artificial vesicles for the first time. As reported in the academic journal Small, the results are offering better insight into the development of nanoreactors and artificial organelles.
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to...
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