Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Pitt team first to detect exciton in metal

02.06.2014

Team gives a microscopic quantum mechanical description of how light excites electrons in metals

University of Pittsburgh researchers have become the first to detect a fundamental particle of light-matter interaction in metals, the exciton. The team will publish its work online June 1 in Nature Physics.

Mankind has used reflection of light from a metal mirror on a daily basis for millennia, but the quantum mechanical magic behind this familiar phenomenon is only now being uncovered.

Physicists describe physical phenomena in terms of interactions between fields and particles, says lead author Hrvoje Petek, Pitt's Richard King Mellon Professor in the Department of Physics and Astronomy within Kenneth P. Dietrich School of Arts and Sciences. When light (an electromagnetic field) reflects from a metal mirror, it shakes the metal's free electrons (the particles), and the consequent acceleration of electrons creates a nearly perfect replica of the incident light (the reflection).

The classical theory of electromagnetism provides a good understanding of inputs and outputs of this process, but a microscopic quantum mechanical description of how the light excites the electrons is lacking.

Petek's team of experimental and theoretical physicists and chemists from the University of Pittsburgh and Institute of Physics in Zagreb, Croatia, report on how light and matter interact at the surface of a silver crystal. They observe, for the first time, an exciton in a metal.

Excitons, particles of light-matter interaction where light photons become transiently entangled with electrons in molecules and semiconductors, are known to be fundamentally important in processes such as plant photosynthesis and optical communications that are the basis for the Internet and cable TV. The optical and electronic properties of metals cause excitons to last no longer than approximately 100 attoseconds (0.1 quadrillionth of a second). Such short lifetimes make it difficult for scientists to study excitons in metals, but it also enables reflected light to be a nearly perfect replica of the incoming light.

Yet, Branko Gumhalter at the Institute of Physics predicted, and Petek and his team experimentally discovered, that the surface electrons of silver crystals can maintain the excitonic state more than 100 times longer than the bulk metal, enabling the excitons in metals to be experimentally captured by a newly developed multidimensional coherent spectroscopic technique.

The ability to detect excitons in metals sheds light on how light is converted to electrical and chemical energy in plants and solar cells, and in the future it may enable metals to function as active elements in optical communications. In other words, it may be possible to control how light is reflected from a metal.

###

The paper, "Transient Excitons at Metal Surfaces," will be published June 1 in the online edition of Nature Physics. The work was supported by a grant from the Division of Chemical Sciences, Geosciences, and Biosciences of the Office of Basic Energy Sciences of the U.S. Department of Energy.

Joseph Miksch | Eurek Alert!

Further reports about: Energy Geosciences Physics electrons exciton excitons mirror particles phenomenon photons technique

More articles from Physics and Astronomy:

nachricht Astronomers discover dizzying spin of the Milky Way galaxy's 'halo'
26.07.2016 | NASA/Goddard Space Flight Center

nachricht Lonely Atoms, Happily Reunited
26.07.2016 | Technische Universität Wien

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Self-assembling nano inks form conductive and transparent grids during imprint

Transparent electronics devices are present in today’s thin film displays, solar cells, and touchscreens. The future will bring flexible versions of such devices. Their production requires printable materials that are transparent and remain highly conductive even when deformed. Researchers at INM – Leibniz Institute for New Materials have combined a new self-assembling nano ink with an imprint process to create flexible conductive grids with a resolution below one micrometer.

To print the grids, an ink of gold nanowires is applied to a substrate. A structured stamp is pressed on the substrate and forces the ink into a pattern. “The...

Im Focus: The Glowing Brain

A new Fraunhofer MEVIS method conveys medical interrelationships quickly and intuitively with innovative visualization technology

On the monitor, a brain spins slowly and can be examined from every angle. Suddenly, some sections start glowing, first on the side and then the entire back of...

Im Focus: Newly discovered material property may lead to high temp superconductivity

Researchers at the U.S. Department of Energy's (DOE) Ames Laboratory have discovered an unusual property of purple bronze that may point to new ways to achieve high temperature superconductivity.

While studying purple bronze, a molybdenum oxide, researchers discovered an unconventional charge density wave on its surface.

Im Focus: Mapping electromagnetic waveforms

Munich Physicists have developed a novel electron microscope that can visualize electromagnetic fields oscillating at frequencies of billions of cycles per second.

Temporally varying electromagnetic fields are the driving force behind the whole of electronics. Their polarities can change at mind-bogglingly fast rates, and...

Im Focus: Continental tug-of-war - until the rope snaps

Breakup of continents with two speed: Continents initially stretch very slowly along the future splitting zone, but then move apart very quickly before the onset of rupture. The final speed can be up to 20 times faster than in the first, slow extension phase.phases

Present-day continents were shaped hundreds of millions of years ago as the supercontinent Pangaea broke apart. Derived from Pangaea’s main fragments Gondwana...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

GROWING IN CITIES - Interdisciplinary Perspectives on Urban Gardening

15.07.2016 | Event News

SIGGRAPH2016 Computer Graphics Interactive Techniques, 24-28 July, Anaheim, California

15.07.2016 | Event News

Partner countries of FAIR accelerator meet in Darmstadt and approve developments

11.07.2016 | Event News

 
Latest News

New movie screen allows for glasses-free 3-D

26.07.2016 | Information Technology

Scientists develop painless and inexpensive microneedle system to monitor drugs

26.07.2016 | Health and Medicine

Astronomers discover dizzying spin of the Milky Way galaxy's 'halo'

26.07.2016 | Physics and Astronomy

VideoLinks
B2B-VideoLinks
More VideoLinks >>>