Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

First Atomic-Scale Real-Time Movies of Platinum Nanocrystal Growth in Liquids

20.04.2012
Berkeley Scientists Create Graphene Liquid Cells for Electron Microscopy Studies of Nanocrystal Formation

They won’t be coming soon to a multiplex near you, but movies showing the growth of platinum nanocrystals at the atomic-scale in real-time have blockbuster potential.

A team of scientists with the Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California (UC) Berkeley has developed a technique for encapsulating liquids of nanocrystals between layers of graphene so that chemical reactions in the liquids can be imaged with an electron microscope. With this technique, movies can be made that provide unprecedented direct observations of physical, chemical and biological phenomena that take place in liquids on the nanometer scale.

“Watching real-time chemical reactions in liquids at the atomic-scale is a dream for chemists and physicists,” says Jungwon Park, a member of the team who holds joint appointments with Berkeley Lab’s Materials Sciences Division and UC Berkeley’s chemistry department. “Using our new graphene liquid cell, we’re able to capture a small amount of liquid sample under a high vacuum condition for taking real-time movies of nanoparticle growth reactions. Since graphene is chemically inert and extremely thin, our liquid cell provides realistic sample conditions for achieving high resolution and contrast.”

Park was the lead author, along with Jong Min Yuk, of a paper in the journal Science that describes this research titled “High-Resolution EM of Colloidal Nanocrystal Growth Using Graphene Liquid Cells.” The research was done as a collaboration between the research groups of Paul Alivisatos, director of Berkeley Lab and UC Berkeley’s Larry and Diane Bock Professor of Nanotechnology, and Alex Zettl, who holds joint appointments with Berkeley Lab’s Materials Sciences Division and UC Berkeley’s Physics Department where he directs the Center of Integrated Nanomechanical Systems. Both are corresponding authors of the Science paper along with Jeong Yong Lee of Korea’s Advanced Institute of Science and Technology (KAIST). Other authors were Peter Ercius, Kwanpyo Kim, Daniel Hellebusch and Michael Crommie.

In using a beam of electrons rather than a beam of light for illumination and magnification, electron microscopes can “see” objects hundreds and even thousands of times smaller than what can be resolved with an optical microscope. However, electron microscopes can only operate in a high vacuum as molecules in the air disrupt the electron beam. Since liquids evaporate in high vacuum, liquid samples must be hermetically sealed in special solid containers – called cells – with a viewing window before they can be imaged in an electron microscope. Until now, such liquid cells have featured viewing windows made from silicon nitride or silicon oxide. While this has permitted studies of some nanoscale phenomena in liquids, the silicon-based cell windows are too thick to allow strong penetration by the electron beam and this has limited resolution to only a few nanometers. In addition to not allowing true atomic-resolution, the thick silicon-based cell windows also appear to perturb the natural state of the liquid or sample suspended in the liquid.

“Graphene is single carbon atom in thickness, making it one of the thinnest known membranes,” says Park, a member of the Alivisatos’ research group. “It does not scatter the electron beam but lets it pass through. Furthermore, graphene is also very strong and impermeable, as well as being chemically non-reactive, and this helps protects the sample in the liquid cell from the high-energy beam of an electron microscope.”

To make their graphene liquid cell, the Alivisatos-Zettl collaboration encapsulated a platinum growth solution between two laminated graphene layers that were suspended over holes in a conventional transmission electron microscope (TEM) grid. The graphene was grown on a copper foil substrate via chemical vapor deposition and then directly transferred onto a gold TEM mesh with a perforated amorphous carbon support. The platinum growth solution was pipetted directly atop two graphene-coated TEM grids facing in opposite directions.

“Upon wetting the system, the solution wicks between the graphene and amorphous carbon layers, allowing one of the graphene sheets to detach from its associated TEM grid,” says co-author Kim, a member of the Zettl research group. “Because the van derWaals interaction between graphene sheets is relatively strong, liquid droplets ranging in thickness from six to 200 nanometers can be securely trapped in a pocket or blister between the graphene sheets.”

To test their graphene liquid cells, the collaborators used the world’s most powerful electron microscope, the TEAM I at the National Center for Electron Microscopy (NCEM), which is housed at Berkeley Lab. TEAM stands for Transmission Electron Aberration-corrected Microscope and the TEAM I instrument is capable of producing images with a half-angstrom resolution, which is less than the diameter of a single hydrogen atom. With TEAM I and their new graphene liquid cells, the Alivisatos-Zettl collaboration was able to directly observe at the highest resolution possible to date and with minimal sample perturbation, the growth of nanocrystals of platinum, one of the best metal catalysts in use today.

“Direct atomic-resolution imaging allowed us to visualize critical steps in the platinum nanocrystal growth process, including a host of previously unexpected phenomena, such as site-selective coalescence, structural reshaping after coalescence, and surface faceting,” says Park.

Three years ago, Park and Alivisatos were part of a team that used another TEM at NCEM and liquid cells featuring silicon nitride windows to record the first ever images of colloidal platinum nanocrystals growing in solution at subnanometer resolution. Their results showed that while some crystals in solution grew steadily in size via classical nucleation and aggregation – meaning molecules collide and join together – others grew in fits and spurts, driven by “coalescence events,” in which small crystals randomly collide and fuse together into larger crystals. Despite their distinctly different growth trajectories, these two processes ultimately yielded nanocrystals of approximately the same size and shape.

“In that earlier study, however, we lacked the resolution to fully understand how these nanoparticles merge and reorganize their shape in the coalescence growth trajectory,” Park says. “With the graphene liquid cells we used in this study, we were able to resolve the oriented coalescence along a specific crystal direction and see how they reorganized their overall structure into a final shape.”

With the graphene liquid cells and the greater resolution of TEAM I, the Alivisatos-Zettl collaboration was able to observe that most coalescence events proceed along the same crystallographic direction – the {111} plane of the crystal. This points to a specific nanocrystal orientation for coalescence not seen before in metal nanoparticles.

“We were able to resolve atomistic arrangement at the moment two of the platinum nanoparticles merged and visualize oriented attachment, a phenomenon known to be one the of major growth mechanisms of anisotropic particles,” Park says. “This oriented coalescence could be one of the formation mechanisms behind another phenomenon we observed, twin boundaries, which occurs when nanoparticles merge together along the same {111} direction but on a mirror plane in the crystal.”

In the future, the collaborators plan to use their graphene liquid cells to study the growth of many different types of nanoparticles, including metals, semiconductors and other useful materials. The graphene cells could also be applied to biomaterials, such as DNA and proteins, which exist naturally in solution.

“The one atom thick graphene membranes are ideal for liquid encapsulation,” says co-author Ercius, the NCEM staff member who ran the TEAM I microscope for this study. “When combined with the aberration corrected imaging of TEAM I, we can reach the ultimate in image contrast and resolution for in-situ liquid experiments. The graphene liquid cell technique could be easily applied to other electron microscopes and I think it will become instrumental in answering questions regarding the synthesis of materials in liquids at the atomic scale.”

This work was supported by the U.S. Department of Energy’s Office of Science, and in part through the National Research Foundation of Korea.

Lawrence Berkeley National Laboratory addresses the world’s most urgent scientific challenges by advancing sustainable energy, protecting human health, creating new materials, and revealing the origin and fate of the universe. Founded in 1931, Berkeley Lab’s scientific expertise has been recognized with 13 Nobel prizes. The University of California manages Berkeley Lab for the U.S. Department of Energy’s Office of Science.

Lynn Yarris | EurekAlert!
Further information:
http://www.lbl.gov
http://newscenter.lbl.gov/feature-stories/2012/04/19/atomic-scale-real-time-movies-of-nanocrystal-growth-in-liquids/

More articles from Physics and Astronomy:

nachricht Study offers new theoretical approach to describing non-equilibrium phase transitions
27.04.2017 | DOE/Argonne National Laboratory

nachricht SwRI-led team discovers lull in Mars' giant impact history
26.04.2017 | Southwest Research Institute

All articles from Physics and Astronomy >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Making lightweight construction suitable for series production

More and more automobile companies are focusing on body parts made of carbon fiber reinforced plastics (CFRP). However, manufacturing and repair costs must be further reduced in order to make CFRP more economical in use. Together with the Volkswagen AG and five other partners in the project HolQueSt 3D, the Laser Zentrum Hannover e.V. (LZH) has developed laser processes for the automatic trimming, drilling and repair of three-dimensional components.

Automated manufacturing processes are the basis for ultimately establishing the series production of CFRP components. In the project HolQueSt 3D, the LZH has...

Im Focus: Wonder material? Novel nanotube structure strengthens thin films for flexible electronics

Reflecting the structure of composites found in nature and the ancient world, researchers at the University of Illinois at Urbana-Champaign have synthesized thin carbon nanotube (CNT) textiles that exhibit both high electrical conductivity and a level of toughness that is about fifty times higher than copper films, currently used in electronics.

"The structural robustness of thin metal films has significant importance for the reliable operation of smart skin and flexible electronics including...

Im Focus: Deep inside Galaxy M87

The nearby, giant radio galaxy M87 hosts a supermassive black hole (BH) and is well-known for its bright jet dominating the spectrum over ten orders of magnitude in frequency. Due to its proximity, jet prominence, and the large black hole mass, M87 is the best laboratory for investigating the formation, acceleration, and collimation of relativistic jets. A research team led by Silke Britzen from the Max Planck Institute for Radio Astronomy in Bonn, Germany, has found strong indication for turbulent processes connecting the accretion disk and the jet of that galaxy providing insights into the longstanding problem of the origin of astrophysical jets.

Supermassive black holes form some of the most enigmatic phenomena in astrophysics. Their enormous energy output is supposed to be generated by the...

Im Focus: A Quantum Low Pass for Photons

Physicists in Garching observe novel quantum effect that limits the number of emitted photons.

The probability to find a certain number of photons inside a laser pulse usually corresponds to a classical distribution of independent events, the so-called...

Im Focus: Microprocessors based on a layer of just three atoms

Microprocessors based on atomically thin materials hold the promise of the evolution of traditional processors as well as new applications in the field of flexible electronics. Now, a TU Wien research team led by Thomas Müller has made a breakthrough in this field as part of an ongoing research project.

Two-dimensional materials, or 2D materials for short, are extremely versatile, although – or often more precisely because – they are made up of just one or a...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

Expert meeting “Health Business Connect” will connect international medical technology companies

20.04.2017 | Event News

Wenn der Computer das Gehirn austrickst

18.04.2017 | Event News

7th International Conference on Crystalline Silicon Photovoltaics in Freiburg on April 3-5, 2017

03.04.2017 | Event News

 
Latest News

Bare bones: Making bones transparent

27.04.2017 | Life Sciences

Study offers new theoretical approach to describing non-equilibrium phase transitions

27.04.2017 | Physics and Astronomy

From volcano's slope, NASA instrument looks sky high and to the future

27.04.2017 | Earth Sciences

VideoLinks
B2B-VideoLinks
More VideoLinks >>>