Chemists at the University of Illinois at Chicago say it's possible, reporting that graphene can become quite pliable using only a nanodroplet of water to do the job.
"Up until now, it wasn't thought we could controllably fold these structures," said Petr Král, assistant professor of chemistry at UIC. "But now we know how to shape graphene by using weak forces between nanodroplets carefully positioned on graphene sheets."
Král and two of his graduate students described the process in a recent article in Nano Letters, which is highlighted in Nature's "news and views" section Dec. 17.
Engineers already cut graphene into narrow ribbons and other shapes, expanding the set of carboneous systems such as fullerenes, carbon nanotubes and nano-diamonds. Using computer simulations, Král showed that weak molecular interactions called van der Waals forces between water nanodroplets and graphene can shape it into a wide variety of forms, without the water and graphene chemically binding.
"Depending on the size of the water droplet and the shape and size of graphene flake used, we can fold it in different shapes for various applications," said Král. "It's similar to the way proteins are folded in biological cells with the help of chaperone proteins."
Král and his students discovered they could use water droplets to roll, bend, slide and shape graphene into different complex structures such as capsules, sandwiches, knots and rings –- all potential building blocks of nanodevices with unique mechanical, electrical or optical properties. By using special techniques like atomic force microscopy and carefully guided microscopic needles, water droplets and other materials can be carefully positioned on graphene to shape it into desired forms, he says.
Král's laboratory is studying potential uses of nanoscale graphene, such as ways to coat it with phospholipid molecules that would allow it to become part of biological cell membranes where it might perform specific functions. His lab is also designing graphene sheet nanoscale pores that allow the building of novel ion and molecular separation membranes for use in desalination and other applications.
While the materials he works with are inorganic, Král sees a growing trend to developing hybrid multifunctional systems that combine inorganic nanostructures with biological cellular systems.
"We're trying to detect signals from the biological world or pass signals to the biological world," he said. "In the future, perhaps proteins will evolve to interact with inorganic systems. It's a way of evolution to form a new interface, or hybrid system, working together on novel functions."
The Nano Letters article was co-authored by Niladri Patra, a UIC chemistry doctoral student and first author on the paper, and former UIC doctoral student Boyang Wang, now a post-doctoral fellow at Northwestern University.
Král's research is supported by the National Science Foundation.
Paul Francuch | Newswise Science News
Water forms 'spine of hydration' around DNA, group finds
26.05.2017 | Cornell University
How herpesviruses win the footrace against the immune system
26.05.2017 | Helmholtz-Zentrum für Infektionsforschung
Staphylococcus aureus is a feared pathogen (MRSA, multi-resistant S. aureus) due to frequent resistances against many antibiotics, especially in hospital infections. Researchers at the Paul-Ehrlich-Institut have identified immunological processes that prevent a successful immune response directed against the pathogenic agent. The delivery of bacterial proteins with RNA adjuvant or messenger RNA (mRNA) into immune cells allows the re-direction of the immune response towards an active defense against S. aureus. This could be of significant importance for the development of an effective vaccine. PLOS Pathogens has published these research results online on 25 May 2017.
Staphylococcus aureus (S. aureus) is a bacterium that colonizes by far more than half of the skin and the mucosa of adults, usually without causing infections....
Physicists from the University of Würzburg are capable of generating identical looking single light particles at the push of a button. Two new studies now demonstrate the potential this method holds.
The quantum computer has fuelled the imagination of scientists for decades: It is based on fundamentally different phenomena than a conventional computer....
An international team of physicists has monitored the scattering behaviour of electrons in a non-conducting material in real-time. Their insights could be beneficial for radiotherapy.
We can refer to electrons in non-conducting materials as ‘sluggish’. Typically, they remain fixed in a location, deep inside an atomic composite. It is hence...
Two-dimensional magnetic structures are regarded as a promising material for new types of data storage, since the magnetic properties of individual molecular building blocks can be investigated and modified. For the first time, researchers have now produced a wafer-thin ferrimagnet, in which molecules with different magnetic centers arrange themselves on a gold surface to form a checkerboard pattern. Scientists at the Swiss Nanoscience Institute at the University of Basel and the Paul Scherrer Institute published their findings in the journal Nature Communications.
Ferrimagnets are composed of two centers which are magnetized at different strengths and point in opposing directions. Two-dimensional, quasi-flat ferrimagnets...
An Australian-Chinese research team has created the world's thinnest hologram, paving the way towards the integration of 3D holography into everyday...
24.05.2017 | Event News
23.05.2017 | Event News
22.05.2017 | Event News
26.05.2017 | Life Sciences
26.05.2017 | Life Sciences
26.05.2017 | Physics and Astronomy