Burning of fossil fuels pumps chemicals into the air that react on surfaces such as buildings and roads to create photochemical smog-forming chlorine atoms, UC Irvine scientists report in a new study.
Under extreme circumstances, this previously unknown chemistry could account for up to 40 parts per billion of ozone – nearly half of California's legal limit on outdoor air pollution. This reaction is not included in computer models used to predict air pollution levels and the effectiveness of ozone control strategies that can cost billions of dollars.
Ozone can cause coughing, throat irritation, chest pain and shortness of breath. Exposure to it has been linked to asthma, bronchitis, cardiopulmonary problems and premature death.
"Realistically, this phenomenon probably accounts for much less than 40 parts per billion, but our results show it could be significant. We should be monitoring it and incorporating it into atmospheric models," said Barbara Finlayson-Pitts, Distinguished Professor of Chemistry and lead author of the study. "We still don't really understand important elements of the atmosphere's chemistry."
Study results appear the week of July 20 in the Proceedings of the National Academy of Sciences.
When fossil fuels burn, compounds called nitrogen oxides are generated. Previously, scientists believed these would be eliminated from the atmosphere upon contact with surfaces.
But UCI scientists discovered that when nitrogen oxides combine with hydrochloric acid from airborne sea salt on buildings, roads and other particles in the air, highly reactive chlorine atoms are created that speed up smog formation.
Hydrochloric acid also is found indoors in cleaning products. When it interacts with nitrogen oxides from appliances such as gas stoves, chlorine compounds form that cause unusual chemistry and contribute to corrosion indoors.
The study was undertaken by scientists involved with AirUCI, an Environmental Molecular Sciences Institute funded by the National Science Foundation. UCI's Jonathan Raff conducted experiments; Bosiljka Njegic and Benny Gerber made theoretical predictions; and Wayne Chang and Donald Dabdub did the modeling. Mark Gordon of Iowa State University also helped with theory.
Said Finlayson-Pitts: "This is a great example of how our unique collaborative group can produce some really great science."
About the University of California, Irvine: Founded in 1965, UCI is a top-ranked university dedicated to research, scholarship and community service. Led by Chancellor Michael Drake since 2005, UCI is among the fastest-growing University of California campuses, with more than 27,000 undergraduate and graduate students, 1,100 faculty and 9,200 staff. The top employer in dynamic Orange County, UCI contributes an annual economic impact of $4.2 billion. For more UCI news, visit www.today.uci.edu.
News Radio: UCI maintains on campus an ISDN line for conducting interviews with its faculty and experts. Use of this line is available for a fee to radio news programs/stations that wish to interview UCI faculty and experts. Use of the ISDN line is subject to availability and approval by the university.
UCI maintains an online directory of faculty available as experts to the media. To access, visit www.today.uci.edu/experts. For UCI breaking news, visit www.zotwire.uci.edu.
Jennifer Fitzenberger | EurekAlert!
Discovery of a Key Regulatory Gene in Cardiac Valve Formation
24.05.2017 | Universität Basel
Carcinogenic soot particles from GDI engines
24.05.2017 | Empa - Eidgenössische Materialprüfungs- und Forschungsanstalt
Physicists from the University of Würzburg are capable of generating identical looking single light particles at the push of a button. Two new studies now demonstrate the potential this method holds.
The quantum computer has fuelled the imagination of scientists for decades: It is based on fundamentally different phenomena than a conventional computer....
An international team of physicists has monitored the scattering behaviour of electrons in a non-conducting material in real-time. Their insights could be beneficial for radiotherapy.
We can refer to electrons in non-conducting materials as ‘sluggish’. Typically, they remain fixed in a location, deep inside an atomic composite. It is hence...
Two-dimensional magnetic structures are regarded as a promising material for new types of data storage, since the magnetic properties of individual molecular building blocks can be investigated and modified. For the first time, researchers have now produced a wafer-thin ferrimagnet, in which molecules with different magnetic centers arrange themselves on a gold surface to form a checkerboard pattern. Scientists at the Swiss Nanoscience Institute at the University of Basel and the Paul Scherrer Institute published their findings in the journal Nature Communications.
Ferrimagnets are composed of two centers which are magnetized at different strengths and point in opposing directions. Two-dimensional, quasi-flat ferrimagnets...
An Australian-Chinese research team has created the world's thinnest hologram, paving the way towards the integration of 3D holography into everyday...
In the race to produce a quantum computer, a number of projects are seeking a way to create quantum bits -- or qubits -- that are stable, meaning they are not much affected by changes in their environment. This normally needs highly nonlinear non-dissipative elements capable of functioning at very low temperatures.
In pursuit of this goal, researchers at EPFL's Laboratory of Photonics and Quantum Measurements LPQM (STI/SB), have investigated a nonlinear graphene-based...
24.05.2017 | Event News
23.05.2017 | Event News
22.05.2017 | Event News
24.05.2017 | Physics and Astronomy
24.05.2017 | Physics and Astronomy
24.05.2017 | Event News