Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Designing a better catalyst for ’artificial photosynthesis’

10.09.2003


Scientists studying the conversion of carbon dioxide (CO2) to carbon monoxide (CO) -- a crucial step in transforming CO2 to useful organic compounds such as methanol -- are trying to mimic what plants do when they convert CO2 and water to carbohydrates and oxygen in the presence of chlorophyll and sunlight. Such "artificial photosynthesis" could produce inexpensive fuels and raw materials for the chemical industry from renewable solar energy. But achieving this goal is no simple task.



"Nature has found a way to do this over eons," says Etsuko Fujita, a chemist at the Department of Energy’s Brookhaven National Laboratory. "It’s very complicated chemistry."

Nature uses chlorophyll as a light absorber and electron-transfer agent. However, chlorophyll does not directly react with CO2. If you take it out of the plant and place it in an artificial system, it decomposes rather quickly, resulting in only a small amount of CO production.


So Fujita and others trying to mimic photosynthesis have turned to artificial catalysts made from robust transition metal complexes such as rhenium complexes. These catalysts absorb solar energy and transfer electrons to CO2, releasing CO. But until now, no one had explained how these processes work in detail. By studying these reactions over very short and long timescales (ranging from 10-8 seconds to hours), Fujita and her colleagues at Brookhaven have discovered an important intermediate step. A most intriguing result is the involvement of two energetic metal complexes to activate one CO2 molecule. Without CO2, the complexes dimerize much more slowly than expected.

The Brookhaven scientists’ work, incorporating a combined experimental and theoretical approach, may help to explain why the reaction proceeds so slowly, which may ultimately contribute to the design of more efficient catalysts.

Fujita will present a talk on this work, which will be published in the Oct. 1 Journal of the American Chemical Society, during the "Organometallic Catalysis" session on Tuesday, September 9, 2003, at 2:30 p.m. in the Jacob Javits Convention Center, room 1A29. This work was funded by the Division of Chemical Sciences, Office of Basic Energy Sciences at DOE’s Office of Science.

Karen McNulty Walsh | EurekAlert!
Further information:
http://www.bnl.gov/

More articles from Life Sciences:

nachricht Cancer diagnosis: no more needles?
25.05.2018 | Christian-Albrechts-Universität zu Kiel

nachricht Less is more? Gene switch for healthy aging found
25.05.2018 | Leibniz-Institut für Alternsforschung - Fritz-Lipmann-Institut e.V. (FLI)

All articles from Life Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Powerful IT security for the car of the future – research alliance develops new approaches

The more electronics steer, accelerate and brake cars, the more important it is to protect them against cyber-attacks. That is why 15 partners from industry and academia will work together over the next three years on new approaches to IT security in self-driving cars. The joint project goes by the name Security For Connected, Autonomous Cars (SecForCARs) and has funding of €7.2 million from the German Federal Ministry of Education and Research. Infineon is leading the project.

Vehicles already offer diverse communication interfaces and more and more automated functions, such as distance and lane-keeping assist systems. At the same...

Im Focus: Molecular switch will facilitate the development of pioneering electro-optical devices

A research team led by physicists at the Technical University of Munich (TUM) has developed molecular nanoswitches that can be toggled between two structurally different states using an applied voltage. They can serve as the basis for a pioneering class of devices that could replace silicon-based components with organic molecules.

The development of new electronic technologies drives the incessant reduction of functional component sizes. In the context of an international collaborative...

Im Focus: LZH showcases laser material processing of tomorrow at the LASYS 2018

At the LASYS 2018, from June 5th to 7th, the Laser Zentrum Hannover e.V. (LZH) will be showcasing processes for the laser material processing of tomorrow in hall 4 at stand 4E75. With blown bomb shells the LZH will present first results of a research project on civil security.

At this year's LASYS, the LZH will exhibit light-based processes such as cutting, welding, ablation and structuring as well as additive manufacturing for...

Im Focus: Self-illuminating pixels for a new display generation

There are videos on the internet that can make one marvel at technology. For example, a smartphone is casually bent around the arm or a thin-film display is rolled in all directions and with almost every diameter. From the user's point of view, this looks fantastic. From a professional point of view, however, the question arises: Is that already possible?

At Display Week 2018, scientists from the Fraunhofer Institute for Applied Polymer Research IAP will be demonstrating today’s technological possibilities and...

Im Focus: Explanation for puzzling quantum oscillations has been found

So-called quantum many-body scars allow quantum systems to stay out of equilibrium much longer, explaining experiment | Study published in Nature Physics

Recently, researchers from Harvard and MIT succeeded in trapping a record 53 atoms and individually controlling their quantum state, realizing what is called a...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

VideoLinks
Industry & Economy
Event News

In focus: Climate adapted plants

25.05.2018 | Event News

Save the date: Forum European Neuroscience – 07-11 July 2018 in Berlin, Germany

02.05.2018 | Event News

Invitation to the upcoming "Current Topics in Bioinformatics: Big Data in Genomics and Medicine"

13.04.2018 | Event News

 
Latest News

In focus: Climate adapted plants

25.05.2018 | Event News

Flow probes from the 3D printer

25.05.2018 | Machine Engineering

Less is more? Gene switch for healthy aging found

25.05.2018 | Life Sciences

VideoLinks
Science & Research
Overview of more VideoLinks >>>