Studying this ‘mini-cellulose’ molecule reveals for the first time the chemical reactions that take place in wood and prairie grasses during high-temperature conversion to biofuel. The new technical discovery was reported in the January 2012 issue of the journal Energy & Environmental Science and highlighted in Nature Chemistry.
The “mini-cellulose” molecule, called á-cyclodextrin, solves one of the major roadblocks confronting high-temperature biofuels processes such as pyrolysis or gasification. The complex chemical reactions that take place as wood is rapidly heated and breaks down to vapors are unknown. And current technology doesn’t allow the use of computer models to track the chemical reactions taking place, because the molecules in wood are too large and the reactions far too complicated.
Paul Dauenhauer, assistant professor of chemical engineering and leader of the UMass Amherst research team, says the breakthrough achieved by studying the smaller surrogate molecule opens up the possibility of using computer simulations to study biomass. He says, “We calculated that it would take about 10,000 years to simulate the chemical reactions in real cellulose. The same biofuel reactions with ‘mini-cellulose’ can be done in a month!”
Already his team has used insight from studying the “mini-cellulose” to make significant progress in understanding wood chemistry, Dauenhauer says. Using the faster computer simulations, they can track the conversion of wood all the way to the chemical vapor products. These reactions include creating furans, molecules that are important for the production of biofuels.
The discovered reactions occurring within wood will serve as the basis for designing advanced biofuel reactors, Dauenhauer says. By creating reaction models of wood conversion, the scientists can design biomass reactors to optimize the specific reactions that are ideal for production of biofuels. For biofuels production, “We want to maximize our new pathway to produce furans and minimize the formation of gases such as CO2,” says Dauenhauer.
The discovery of “mini-cellulose” was enabled by a new experimental technique for studying high-temperature biomass chemistry called “thin-film pyrolysis.” It involves creating sheets of cellulose, which makes up 60 percent of wood biomass, that are very thin, just a few microns thick. When the sheets are very rapidly heated at over one million degrees Celsius per minute, they create volatile chemicals which are the precursors of biofuel.
Dauenhauer joined the university in 2009 and conducts his research as part of the Catalysis Center for Energy Innovation in collaboration with the University of Delaware and funded by the U.S. Department of Energy (DOE). His research team includes Professor Dion Vlachos and graduate students Matt Mettler, Alex Paulsen and Samir Mushrif.
Dauenhauer has received several high-profile grants in the past year. In May 2011, he awarded a five-year, $800,000 Early Career Award in Basic Energy Sciences from the DOE. The grant provides support for his research on understanding the catalysts that control the process of breaking down plant matter into chemicals and fuel byproducts.
In February 2011, he was awarded a one-year, $80,000 grant from the National Science Foundation to conduct basic research on pyrolysis. Additionally in 2011, he was awarded a three-year Young Faculty Award from the 3M Corporation.
Paul Dauenhauer | Newswise Science News
Biologists unravel another mystery of what makes DNA go 'loopy'
16.03.2018 | Emory Health Sciences
Scientists map the portal to the cell's nucleus
16.03.2018 | Rockefeller University
Animal photoreceptors capture light with photopigments. Researchers from the University of Göttingen have now discovered that these photopigments fulfill an...
On 15 March, the AWI research aeroplane Polar 5 will depart for Greenland. Concentrating on the furthest northeast region of the island, an international team...
The world’s second-largest ice shelf was the destination for a Polarstern expedition that ended in Punta Arenas, Chile on 14th March 2018. Oceanographers from...
At the 2018 ILA Berlin Air Show from April 25–29, the Fraunhofer Institute for Laser Technology ILT is showcasing extreme high-speed Laser Material Deposition (EHLA): A video documents how for metal components that are highly loaded, EHLA has already proved itself as an alternative to hard chrome plating, which is now allowed only under special conditions.
When the EU restricted the use of hexavalent chromium compounds to special applications requiring authorization, the move prompted a rethink in the surface...
At the ILA Berlin, hall 4, booth 202, Fraunhofer FHR will present two radar sensors for navigation support of drones. The sensors are valuable components in the implementation of autonomous flying drones: they function as obstacle detectors to prevent collisions. Radar sensors also operate reliably in restricted visibility, e.g. in foggy or dusty conditions. Due to their ability to measure distances with high precision, the radar sensors can also be used as altimeters when other sources of information such as barometers or GPS are not available or cannot operate optimally.
Drones play an increasingly important role in the area of logistics and services. Well-known logistic companies place great hope in these compact, aerial...
16.03.2018 | Event News
13.03.2018 | Event News
08.03.2018 | Event News
16.03.2018 | Earth Sciences
16.03.2018 | Physics and Astronomy
16.03.2018 | Life Sciences