Paper is one of the surfaces most commonly tested for fingerprints in forensics. Unfortunately, it is particularly difficult to make fingerprints on paper visible. In the journal Angewandte Chemie, Israeli scientists have now introduced a new method developed specifically for use on paper.
It produces a “negative” of the fingerprint and is, in contrast to conventional methods, independent of the composition of the sweat residue left behind.
In many criminal cases, paper evidence plays an important role and it would be useful to know through whose hands checks, documents, or paper currency have passed. Studies have shown that only about half of the fingerprints present on paper can be made sufficiently visible. The main reason that this does not work consistently seems to be the highly variable composition of the sweat left behind on the paper.
A team led by Daniel Mandler and Joseph Almog at the Hebrew University of Jerusalem has now developed a procedure that avoids these problems. It involves a sort of inversion of an established method in which gold nanoparticles are first deposited onto the invisible fingerprints, followed by elemental silver, similar to the development of a black and white photograph.
In the conventional technique, the gold particles get stuck to components of the sweat in fingerprints. In contrast, the gold nanoparticles in the new method stick directly to the paper, not the sweat. This technique uses the sebum from the fingerprints, which effectively shields the paper beneath it from the gold nanoparticles. Treatment with a developer containing silver, which turns the areas with gold on them black, results in a negative image of the fingerprint.
The secret to the success of these researchers is a special bifunctional reagent. The head of this molecule is an acylpyridazine group, which can bind to cellulose. The tail is made of hydrocarbon chains with a sulfur-containing group at the end, which binds to gold and attaches the molecule to the surface of the gold nanoparticles. When gold particles coated with these molecules are deposited onto paper with a fingerprint on it, the heads bind to the cellulose in the paper, avoiding the fat-containing lines.
Because only the fatty components of the fingerprints are used, the possibly unfavorable composition of the sweat in the fingerprint plays no role in this method. This technique also promises to alleviate another problem: if paper has become wet, it has previously been nearly impossible to detect fingerprints because the amino acids in the sweat, which are the primary substrate for current chemical enhancement reactions, are dissolved and washed away by water. The fatty components are barely effected.About the Author
Title: Visualization of Latent Fingermarks by Using Nanotechnology for Reversed Development on Paper: A Remedy to the Variation in Sweat Composition
Angewandte Chemie International Edition, Permalink to the article: http://dx.doi.org/10.1002/anie.201205259
Joseph Almog | Angewandte Chemie
Multi-institutional collaboration uncovers how molecular machines assemble
02.12.2016 | Salk Institute
Fertilized egg cells trigger and monitor loss of sperm’s epigenetic memory
02.12.2016 | IMBA - Institut für Molekulare Biotechnologie der Österreichischen Akademie der Wissenschaften GmbH
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
Broadband rotational spectroscopy unravels structural reshaping of isolated molecules in the gas phase to accommodate water
In two recent publications in the Journal of Chemical Physics and in the Journal of Physical Chemistry Letters, researchers around Melanie Schnell from the Max...
The efficiency of power electronic systems is not solely dependent on electrical efficiency but also on weight, for example, in mobile systems. When the weight of relevant components and devices in airplanes, for instance, is reduced, fuel savings can be achieved and correspondingly greenhouse gas emissions decreased. New materials and components based on gallium nitride (GaN) can help to reduce weight and increase the efficiency. With these new materials, power electronic switches can be operated at higher switching frequency, resulting in higher power density and lower material costs.
Researchers at the Fraunhofer Institute for Solar Energy Systems ISE together with partners have investigated how these materials can be used to make power...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
02.12.2016 | Medical Engineering
02.12.2016 | Agricultural and Forestry Science
02.12.2016 | Physics and Astronomy