For the first time, Würzburg scientists have successfully bound multiple carbon monoxide molecules to the main group element boron. They report on their work in the latest issue of the scientific journal Nature.
Scientists of Professor Holger Braunschweig's team of the Institute of Inorganic Chemistry at the University of Würzburg have successfully bound two carbon monoxide molecules (CO) to the main group element boron in a direct synthesis for the first time. The result is a borylene-dicarbonyl complex.
Such complexes, or coordination complexes, are generally made up of one or more central molecules and one or more ligands. The central molecules are usually atoms of transition metals.
"Binding one CO molecule to a main group element is already extraordinary. Bonding two molecules two one non-metal atom is even more extraordinary," says chemist Rian Dewhurst. Dewhurst, who is working on Professor Holger Braunschweig's team, submitted the article together with several co-authors. It is the first work of the institute to have been accepted by the journal Nature.
"In future, borylene-dicarbonyls could be used to mimic the properties of transition metal carbonyl complexes," Dewhurst further. Transition metals have specific electronic properties. These elements from group four to twelve in the periodic table have the ability to bind multiple carbon monoxide molecules relatively easily.
Advantages of boron compounds
Generally, boron compounds are important for various industrial applications. They are used, for example, in catalytic processes, in various molecular and solid materials or in the production of pharmaceutical drugs. A catalyst accelerates a desired chemical reaction without being consumed in the process.
Boron has the advantage of being readily available and comparably low-priced. It occurs naturally mostly in mineral form and is mined in borate mines in California and Turkey, for example. Moreover, the element is non-toxic for humans and other mammals. "Combined with its unique electronic properties, this makes boron very interesting for industrial and other commercial uses," Dewhurst explains.
Boron is a highly reactive element. With three electrons on the outer shells, boron strives to form bonds that enable eight electrons, which the noble gases neon, argon or xenon already have in their basic state.
Lone electron pair at the central molecule
The borylene-dicarbonyl complex also has eight electrons involved in the bonds to the boron atom. With two electrons, respectively, presenting the bonds to the two CO molecules and two others binding one hydrocarbyl, the researchers were able to establish one lone electron pair amounting to eight electrons in total. "It is the lone electron pair that makes the complex special. The hydrocarbyl assures stability. It shields the structure in a manner of speaking," says Marco Nutz, a doctoral candidate. He adds: "Most compounds that can be isolated in this way are unstable outside a protective atmosphere." The Würzburg discovery, however, remains stable for several days even in a "normal" environment exposed to air and moisture.
Dewhurst and Nutz are conducting basic research. "In a next step, we are going to further investigate the compound we have presented. We are pursuing different angles here," Dewhurst says. One focus will be to compare the properties of conventional transition metal carbonyl complexes with those of the borylene-carbonyl complex in detail.
In recent years, the attention of natural science has progressively focused on boron. According to Dewhurst, the increasing significance of boron is also reflected in the growing interest in the element on the part of organic chemistry and in the fact that material science, too, is closely following the advances made in boron complex research.
"Multiple Complexation of CO and Related Ligands to a Main Group Element" by Holger Braunschweig, Rian D. Dewhurst, Florian Hupp, Marco Nutz, Krzysztof Radacki, Christopher W. Tate, Alfredo Vargas, Qing Ye. Nature vol 522, issue 7556 pp.327-330, DOI 10.1038/nature14489
Prof. Holger Braunschweig, Institute of Inorganic Chemistry at the University of Würzburg
Phone: +49 931 31-88104, e-mail: email@example.com
http://www.presse.uni-wuerzburg.de University's press office
Marco Bosch | Julius-Maximilians-Universität Würzburg
Further reports about: > CO molecules > Julius-Maximilians-Universität > basic research > bonds > carbon monoxide > carbon monoxide molecules > catalytic processes > chemical reaction > electronic properties > industrial applications > material science > natural science > noble gases > organic chemistry > pharmaceutical drugs > solid materials > transition metal
Newly designed molecule binds nitrogen
23.02.2018 | Julius-Maximilians-Universität Würzburg
Atomic Design by Water
23.02.2018 | Max-Planck-Institut für Eisenforschung GmbH
A newly developed laser technology has enabled physicists in the Laboratory for Attosecond Physics (jointly run by LMU Munich and the Max Planck Institute of Quantum Optics) to generate attosecond bursts of high-energy photons of unprecedented intensity. This has made it possible to observe the interaction of multiple photons in a single such pulse with electrons in the inner orbital shell of an atom.
In order to observe the ultrafast electron motion in the inner shells of atoms with short light pulses, the pulses must not only be ultrashort, but very...
A group of researchers led by Andrea Cavalleri at the Max Planck Institute for Structure and Dynamics of Matter (MPSD) in Hamburg has demonstrated a new method enabling precise measurements of the interatomic forces that hold crystalline solids together. The paper Probing the Interatomic Potential of Solids by Strong-Field Nonlinear Phononics, published online in Nature, explains how a terahertz-frequency laser pulse can drive very large deformations of the crystal.
By measuring the highly unusual atomic trajectories under extreme electromagnetic transients, the MPSD group could reconstruct how rigid the atomic bonds are...
Quantum computers may one day solve algorithmic problems which even the biggest supercomputers today can’t manage. But how do you test a quantum computer to...
For the first time, a team of researchers at the Max-Planck Institute (MPI) for Polymer Research in Mainz, Germany, has succeeded in making an integrated circuit (IC) from just a monolayer of a semiconducting polymer via a bottom-up, self-assembly approach.
In the self-assembly process, the semiconducting polymer arranges itself into an ordered monolayer in a transistor. The transistors are binary switches used...
Breakthrough provides a new concept of the design of molecular motors, sensors and electricity generators at nanoscale
Researchers from the Institute of Organic Chemistry and Biochemistry of the CAS (IOCB Prague), Institute of Physics of the CAS (IP CAS) and Palacký University...
15.02.2018 | Event News
13.02.2018 | Event News
12.02.2018 | Event News
23.02.2018 | Physics and Astronomy
23.02.2018 | Health and Medicine
23.02.2018 | Physics and Astronomy