Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


Building a better battery


Texas A&M chemist says trapped electrons to blame for lack of battery efficiency

Forget mousetraps -- today's scientists will get the cheese if they manage to build a better battery.

Mapping electron density in order of increasing lithiation levels using spectral imaging. Each colored region corresponds to sites where electron density is localized, which also corresponds to high concentrations of Li-ions. "The stripes mark regions that have been extensively lithiated and reduced," Banerjee notes.

Credit: Luis De Jesús / Texas A&M University

An international team led by Texas A&M University chemist Sarbajit Banerjee is one step closer, thanks to new research published today (June 28) in the journal Nature Communications that has the potential to create more efficient batteries by shedding light on the cause of one of their biggest problems -- a "traffic jam" of ions that slows down their charging and discharging process.

All batteries have three main components: two electrodes and an intervening electrolyte. Lithium ion batteries work under the so-called rocking-chair model. Imagine discharging and charging a battery as similar to the back-and-forth motion of a rocking chair. As the chair rocks one way, using its stored energy, lithium ions flow out of one electrode through the electrolyte and into the other electrode. Then as the chair rocks the other way, charging the battery after a day's use, the reverse happens, emptying the second electrode of lithium ions.

"Fundamentally, when you have a battery, every time you use it, it starts to die a little bit," Banerjee said. "The more you use it, the more it dies. Eventually, it becomes unusable. Theoretically speaking, you expect a certain performance from a battery, and you rarely ever get there. People have been at a loss to understand all the factors that contribute to this lack of full capacity. This study points us in that direction."

Using one of the world's most powerful soft X-ray microscopes -- the Scanning Transmission X-ray Microscope (STXM) -- at the Canadian Light Source (CLS) in tandem with decades of combined experience in materials science, Banerjee and collaborators from the Lawrence Berkeley National Laboratory, Binghamton University and the National Institute of Standards and Technology (NIST) were able to image a traffic jam of lithium ions chemically driven through the nanowire-based channels of a simulated battery.

"For a battery to function properly, you need to get lithium ions in, and you need to be able to pull them out," Banerjee said. "Once our lithium ions got in, we were seeing that they sort of stop at some point along the way."

Banerjee points to this interruption as a veritable ghost in the machine that not only slows everything down but also sometimes prevents the device -- be it a cell phone or a laptop computer -- from exploiting its full battery potential. He says the devil is in the details, which in this case clearly show that the electrons, once coupled with the lithium ions, appear content to sit instead of moving freely, thereby distorting the electronic structure and, in essence, trapping or stranding the flow of energy.

Two of Banerjee's graduate students, Luis De Jesús and Gregory Horrocks, are joint first authors on the Nature paper detailing the team's National Science Foundation-funded research, which also features a third Texas A&M graduate student, Abhishek Parija. Berkeley Lab staff scientist David Prendergast and postdoctoral fellow Yufeng Liang at Berkeley Lab's Molecular Foundry, a U.S. Department of Energy National User Facility for Nanoscale Science Research, helped the Texas A&M team design and implement their calculations, which were experimentally verified by colleagues at Binghamton and using NIST National Synchrotron Light Source beamlines at Brookhaven National Laboratory supervised by Daniel Fischer. Calculations were conducted using Molecular Foundry as well as Texas A&M computing resources.

Berkeley Lab's Prendergast notes that the team's work demonstrates how X-rays can "see" small polarons -- the combination of a charged particle (electron) and an associated structural distortion -- through their impact on electronic structure around the oxygen atoms in the cathode. Small polarons previously have been proposed to be present in transport within Li-ion cathodes but have not been "seen" directly until now.

In order to make way for additional lithium to enter the structure, Prendergast says, the lithium ions need to diffuse, bringing their electrons in tow. But as a small polaron, it also has to carry along the structural distortion -- a real drag for transport of charge in a material.

"Imagine wanting to move a house to a different site," Prendergast said. "A wooden house can be transported in one piece, but a brick or stone house might have to be dismantled or demolished first."

The team also was able to identify the specific site where the electron sits within the particle, down to the orbital. Interestingly enough, De Jesús says, the holdup always occurs at the same material-dependent point.

Once the lithium gets in, Banerjee notes there's a very slight distortion that causes the electrons to get trapped in a plane, where they form what he describes as "puddles of charge" that are unable to link up and move as they should through the material.

"You can always draw an analogy between water and electrons," Banerjee said. "They are making these little puddles, but until the puddles are connected, they can't flow. Once you have enough electrons coming in, they can all link up and start flowing. But until that happens, they're all stranded, and they can't move to charge or discharge something. And so they go out and hang in different areas of the particle. They're all sort of sitting, defining different regions, and they aren't able to move easily."

Banerjee, who joined the Texas A&M Department of Chemistry in 2014 and is an affiliated faculty member in the Department of Materials Science and Engineering, has been working for a number of years to understand ion intercalation, the process by which ions like lithium move in and out of other materials. He says the resulting analysis can be applied in many different areas, including one of his group's specialties -- design of better logic circuitry.

"One of the things we look at is, why do devices like cell phones and computers use up so much energy?" Banerjee said. "We're trying to develop new materials to make better circuits that are less energy guzzling. This work hones in on the problem, and it's a really good measurement. In the end, we were able to get to the bottom of the problem."

For Banerjee, it's a result driven by the most basic of energies: curiosity. A couple of years ago, he and Horrocks realized while using conventional laboratory techniques to study the lithiation process in cathode materials that lithium ions would enter nanostructures much faster than they would larger structures. Right then and there, they made it their mission to figure out why smaller was faster -- a quest that eventually led them to the Canadian Light Source and an expanded research team featuring, among other top-caliber colleagues, CLS Spectromicroscopy beamline scientist Jian Wang.

"Jian Wang was greatly instrumental, because the reviewers pushed us really hard on making 100 percent sure that what we were seeing was real," Banerjee said. "The Binghamton group helped us verify some of the predictions in theory. We had an observation; we calculated and matched that in models and then from there the models predicted some other things. They basically said, 'Well, if you're filling an electron into these certain states and they're no longer visible to you by X-ray imaging in a particular region of the spectrum, that means they're already full, so you should be looking for them somewhere else.' So the Binghamton group helped us look elsewhere, and we saw that, too. Once again, that really brings home the entire story."

Binghamton physicist Louis Piper adds that his group has been studying polaron formation and migration in other Li-ion battery cathodes using X-ray spectroscopy methodology. For this particular project, he says, their role was to confirm that the team's calculations were predicting the polaron well by making direct comparisons using another observation method, spatially-averaging hard X-ray photoelectron spectroscopy (HAXPES), which is able to probe occupied energy states.

"The STXM is spatially-resolving but looks at empty states," Piper said. "In my opinion, the STXM shows the spatial effects of the polarons, which is very exciting, while the HAXPES confirmed the energies. The combination meant that we could use the calculations to artificially 'zoom in' with the model.

"I consider our role at Binghamton as keeping the calculations honest. It was nice to see all the approaches converge in this study."

Ultimately, Horrocks and Banerjee agree that building a better battery boils down to figuring out a better way to move electrons -- a feat in which size matters and everything points to material.

"There are two ways to solve the problem of moving electrons through cathode material better," Banerjee says. "One, you can make the stuff smaller or design architectures. Two, you can come up with entirely new materials, which is what we're trying to do. Basically, you prevent the electron from getting stranded because you design the material in such a way that it doesn't have orbitals where they would get stranded. You force them to always be de-localized. We have several materials in mind and are trying to get that research published."


To learn more about the study, see the team's complete paper, Mapping Polaronic States and Lithiation Gradients in Individual V2O5 Nanowires.

For additional information on Banerjee and his research, visit

About Research at Texas A&M University: As one of the world's leading research institutions, Texas A&M is at the forefront in making significant contributions to scholarship and discovery, including that of science and technology. Research conducted at Texas A&M represented annual expenditures of more than $866.6 million in fiscal year 2015. Texas A&M ranked in the top 20 of the National Science Foundation's Higher Education Research and Development survey (2014), based on expenditures of more than $854 million in fiscal year 2014. Texas A&M's research creates new knowledge that provides basic, fundamental and applied contributions resulting in many cases in economic benefits to the state, nation and world. To learn more, visit

Media Contact

Shana Hutchins

Shana Hutchins | EurekAlert!

Further reports about: Electrons X-ray battery cathode electrode lithium ions polarons

More articles from Life Sciences:

nachricht Don't Give the Slightest Chance to Toxic Elements in Medicinal Products
23.03.2018 | Physikalisch-Technische Bundesanstalt (PTB)

nachricht North and South Cooperation to Combat Tuberculosis
22.03.2018 | Universität Zürich

All articles from Life Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Space observation with radar to secure Germany's space infrastructure

Satellites in near-Earth orbit are at risk due to the steady increase in space debris. But their mission in the areas of telecommunications, navigation or weather forecasts is essential for society. Fraunhofer FHR therefore develops radar-based systems which allow the detection, tracking and cataloging of even the smallest particles of debris. Satellite operators who have access to our data are in a better position to plan evasive maneuvers and prevent destructive collisions. From April, 25-29 2018, Fraunhofer FHR and its partners will exhibit the complementary radar systems TIRA and GESTRA as well as the latest radar techniques for space observation across three stands at the ILA Berlin.

The "traffic situation" in space is very tense: the Earth is currently being orbited not only by countless satellites but also by a large volume of space...

Im Focus: Researchers Discover New Anti-Cancer Protein

An international team of researchers has discovered a new anti-cancer protein. The protein, called LHPP, prevents the uncontrolled proliferation of cancer cells in the liver. The researchers led by Prof. Michael N. Hall from the Biozentrum, University of Basel, report in “Nature” that LHPP can also serve as a biomarker for the diagnosis and prognosis of liver cancer.

The incidence of liver cancer, also known as hepatocellular carcinoma, is steadily increasing. In the last twenty years, the number of cases has almost doubled...

Im Focus: Researchers at Fraunhofer monitor re-entry of Chinese space station Tiangong-1

In just a few weeks from now, the Chinese space station Tiangong-1 will re-enter the Earth's atmosphere where it will to a large extent burn up. It is possible that some debris will reach the Earth's surface. Tiangong-1 is orbiting the Earth uncontrolled at a speed of approx. 29,000 km/h.Currently the prognosis relating to the time of impact currently lies within a window of several days. The scientists at Fraunhofer FHR have already been monitoring Tiangong-1 for a number of weeks with their TIRA system, one of the most powerful space observation radars in the world, with a view to supporting the German Space Situational Awareness Center and the ESA with their re-entry forecasts.

Following the loss of radio contact with Tiangong-1 in 2016 and due to the low orbital height, it is now inevitable that the Chinese space station will...

Im Focus: Alliance „OLED Licht Forum“ – Key partner for OLED lighting solutions

Fraunhofer Institute for Organic Electronics, Electron Beam and Plasma Technology FEP, provider of research and development services for OLED lighting solutions, announces the founding of the “OLED Licht Forum” and presents latest OLED design and lighting solutions during light+building, from March 18th – 23rd, 2018 in Frankfurt a.M./Germany, at booth no. F91 in Hall 4.0.

They are united in their passion for OLED (organic light emitting diodes) lighting with all of its unique facets and application possibilities. Thus experts in...

Im Focus: Mars' oceans formed early, possibly aided by massive volcanic eruptions

Oceans formed before Tharsis and evolved together, shaping climate history of Mars

A new scenario seeking to explain how Mars' putative oceans came and went over the last 4 billion years implies that the oceans formed several hundred million...

All Focus news of the innovation-report >>>



Industry & Economy
Event News

New solar solutions for sustainable buildings and cities

23.03.2018 | Event News

Virtual reality conference comes to Reutlingen

19.03.2018 | Event News

Ultrafast Wireless and Chip Design at the DATE Conference in Dresden

16.03.2018 | Event News

Latest News

For graphite pellets, just add elbow grease

23.03.2018 | Materials Sciences

Unique communication strategy discovered in stem cell pathway controlling plant growth

23.03.2018 | Agricultural and Forestry Science

Sharpening the X-ray view of the nanocosm

23.03.2018 | Physics and Astronomy

Science & Research
Overview of more VideoLinks >>>