Phosgene was still stockpiled in military arsenals well after the Second World War, but its continued presence in the atmosphere today is due to man-made chlorinated hydrocarbons used in the chemical industry.
A team, including Professor Peter Bernath, of the Department of Chemistry at the University of York, has carried out the first study of the global distribution of the gas. The team also involved scientists from the Universities of Waterloo and Toronto in Canada, NASA’s Jet Propulsion Laboratory and the New Mexico Institute of Mining and Technology in the USA.
Between February 2004 and May 2006, they used the Canadian Atmospheric Chemistry Experiment (ACE) satellite to measure the incidence of the gas. The research, which was financed by the Canada Space Agency (CSA) and the Natural Sciences and Engineering Research Council of Canada, is published in the latest edition of Geophysics Research Letters.
The scientists discovered that the main atmospheric concentration of the gas was above the Equator, though it was present in some quantity in all latitudes. They found that levels of phosgene in the atmosphere had reduced since previous studies in the 1980s and 1990s, though its continued presence is a contributor to ozone depletion.
Phosgene plays a major role in the preparation of pharmaceuticals, herbicides, insecticides, synthetic foams, resins and polymers, though its use is being reduced.
Professor Bernath said: ”There is a small, but not negligible, concentration of phosgene in the troposphere. Chlorinated hydrocarbons don't occur in nature but as chlorinated solvents they are used by industry. They are short-lived and they decay rapidly, but they decay into phosgene.
“It's very toxic and pretty nasty stuff - its reputation is well deserved. Considering the health hazards associated with phosgene, the chemical industry is trying to find substitutes to eliminate its use. But the use of chlorinated hydrocarbons is being reduced because of the legal restrictions of the Montreal Protocol, so phosgene is also decreasing.”
Higher up in the atmosphere phosgene can be slowly oxidized by ultraviolet rays, and so it continues to play a role in the depletion of the ozone layer.
David Garner | alfa
Global threat to primates concerns us all
19.01.2017 | Deutsches Primatenzentrum GmbH - Leibniz-Institut für Primatenforschung
Reducing household waste with less energy
18.01.2017 | FIZ Karlsruhe – Leibniz-Institut für Informationsinfrastruktur GmbH
An important step towards a completely new experimental access to quantum physics has been made at University of Konstanz. The team of scientists headed by...
Yersiniae cause severe intestinal infections. Studies using Yersinia pseudotuberculosis as a model organism aim to elucidate the infection mechanisms of these...
Researchers from the University of Hamburg in Germany, in collaboration with colleagues from the University of Aarhus in Denmark, have synthesized a new superconducting material by growing a few layers of an antiferromagnetic transition-metal chalcogenide on a bismuth-based topological insulator, both being non-superconducting materials.
While superconductivity and magnetism are generally believed to be mutually exclusive, surprisingly, in this new material, superconducting correlations...
Laser-driving of semimetals allows creating novel quasiparticle states within condensed matter systems and switching between different states on ultrafast time scales
Studying properties of fundamental particles in condensed matter systems is a promising approach to quantum field theory. Quasiparticles offer the opportunity...
Among the general public, solar thermal energy is currently associated with dark blue, rectangular collectors on building roofs. Technologies are needed for aesthetically high quality architecture which offer the architect more room for manoeuvre when it comes to low- and plus-energy buildings. With the “ArKol” project, researchers at Fraunhofer ISE together with partners are currently developing two façade collectors for solar thermal energy generation, which permit a high degree of design flexibility: a strip collector for opaque façade sections and a solar thermal blind for transparent sections. The current state of the two developments will be presented at the BAU 2017 trade fair.
As part of the “ArKol – development of architecturally highly integrated façade collectors with heat pipes” project, Fraunhofer ISE together with its partners...
19.01.2017 | Event News
10.01.2017 | Event News
09.01.2017 | Event News
20.01.2017 | Awards Funding
20.01.2017 | Materials Sciences
20.01.2017 | Life Sciences