Ocean “acidification” occurs when chemical compounds such as carbon dioxide, sulfur, or nitrogen mix with seawater, a process which lowers the pH and reduces the storage of carbon.
Ocean acidification hampers the ability of marine organisms—such as sea urchins, corals, and certain types of plankton—to harness calcium carbonate for making hard outer shells or “exoskeletons.” These organisms provide essential food and habitat to other species, so their demise could affect entire ocean ecosystems.
The findings were published this week in the online “early edition” of the Proceedings of the National Academy of Sciences; a printed version will be issued later this month.
“Acid rain isn’t just a problem of the land; it’s also affecting the ocean,” said Scott Doney, lead author of the study and a senior scientist in the Department of Marine Chemistry and Geochemistry at the Woods Hole Oceanographic Institution (WHOI). “That effect is most pronounced near the coasts, which are already some of the most heavily affected and vulnerable parts of the ocean due to pollution, over-fishing, and climate change.”
In addition to acidification, excess nitrogen inputs from the atmosphere promote increased growth of phytoplankton and other marine plants which, in turn, may cause more frequent harmful algal blooms and eutrophication (the creation of oxygen-depleted “dead zones”) in some parts of the ocean.
Doney collaborated on the project with Natalie Mahowald, Jean-Francois Lamarque, and Phil Rasch of the National Center for Atmospheric Research, Richard Feely of the Pacific Marine Environmental Laboratory, Fred Mackenzie of the University of Hawaii, and Ivan Lima of the WHOI Marine Chemistry and Geochemistry Department.
“Most studies have traditionally focused only on fossil fuel emissions and the role of carbon dioxide in ocean acidification, which is certainly the dominant issue,” Doney said. “But no one has really addressed the role of acid rain and nitrogen.”
The research team compiled and analyzed many publicly available data sets on fossil fuel emissions, agricultural, and other atmospheric emissions. They built theoretical and computational models of the ocean and atmosphere to simulate where the nitrogen and sulfur emissions were likely to have the most impact. They also compared their model results with field observations made by other scientists in the coastal waters around the United States.
Farming, livestock husbandry, and the combustion of fossil fuels cause excess sulfur dioxide, ammonia, and nitrogen oxides to be released to the atmosphere, where they are transformed into nitric acid and sulfuric acid. Though much of that acid is deposited on land (since it does not remain in the air for long), some of it can be carried in the air all the way to the coastal ocean.
When nitrogen and sulfur compounds from the atmosphere are mixed into coastal waters, the researchers found, the change in water chemistry was as much as 10 to 50 percent of the total changes caused by acidification from carbon dioxide.
This rain of chemicals changes the chemistry of seawater, with the increase in acidic compounds lowering the pH of the water while reducing the capacity of the upper ocean to store carbon.
The most heavily affected areas tend to be downwind of power plants (particularly coal-fired plants) and predominantly on the eastern edges of North America, Europe, and south and east of Asia.
Seawater is slightly basic (pH usually between 7.5 and 8.4), but the ocean surface is already 0.1 pH units lower than it was before the Industrial Revolution. Previous research by Doney and others has suggested that the ocean will become another 0.3 to 0.4 pH units lower by the end of the century, which translates to a 100 to 150 percent increase in acidity.
Funding for this research was provided by the National Science Foundation, the National Aeronautics and Space Administration, and the National Oceanic and Atmospheric Administration.
Woods Hole Oceanographic Institution is a private, independent organization in Falmouth, Mass., dedicated to marine research, engineering, and higher education. Established in 1930 on a recommendation from the National Academy of Sciences, its primary mission is to understand the oceans and their interaction with the Earth as a whole, and to communicate a basic understanding of the ocean's role in the changing global environment.
WHOI Media Relations | EurekAlert!
Successful calculation of human and natural influence on cloud formation
04.11.2016 | Goethe-Universität Frankfurt am Main
Invasive Insects Cost the World Billions Per Year
04.10.2016 | University of Adelaide
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
Broadband rotational spectroscopy unravels structural reshaping of isolated molecules in the gas phase to accommodate water
In two recent publications in the Journal of Chemical Physics and in the Journal of Physical Chemistry Letters, researchers around Melanie Schnell from the Max...
The efficiency of power electronic systems is not solely dependent on electrical efficiency but also on weight, for example, in mobile systems. When the weight of relevant components and devices in airplanes, for instance, is reduced, fuel savings can be achieved and correspondingly greenhouse gas emissions decreased. New materials and components based on gallium nitride (GaN) can help to reduce weight and increase the efficiency. With these new materials, power electronic switches can be operated at higher switching frequency, resulting in higher power density and lower material costs.
Researchers at the Fraunhofer Institute for Solar Energy Systems ISE together with partners have investigated how these materials can be used to make power...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
02.12.2016 | Medical Engineering
02.12.2016 | Agricultural and Forestry Science
02.12.2016 | Physics and Astronomy