Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Water pollutants purged

04.02.2002


Glowing catalyst can spot one part pollutant per million of water
© PhotoDisc


Smart process cleans up contaminated water.

A smart material identifies and destroys toxic pollutants in water. When exposed to the offending molecules, tiny light-emitting zinc oxide particles glow dimly, burn them up, and glow brightly to show they’ve finished1.

The advantage of such an approach, say Prashant Kamat and co-workers at the University of Notre Dame in Indiana, is that the energy-consuming burn-up stage switches on only when pollutants are present.



Kamat’s team is training its cross-hairs on organic aromatic pollutants such as chlorinated phenols. These are used as wood preservatives and pesticides, and are often the by-products of paper pulp milling.

Polychlorinated biphenyls (PCBs) are related substances that are widespread contaminants in industrialized nations. They are used to manufacture paints, plastics, adhesives and electrical goods, and as hydraulic and cooling fluids. Municipal incinerators produce similar chlorinated aromatic compounds called dioxins.

All these chemicals are toxic in high doses, and are possibly carcinogenic.

One widely studied new method for decontaminating water is photocatalytic oxidation: the burning-up of organic molecules in air, stimulated by a light-sensitive catalyst. The most common catalyst in these studies (which have not yet delivered a commercial process) is titanium dioxide.

Zinc oxide might prove more versatile, the Notre Dame group thinks. It destroys organic molecules in much the same way as titanium dioxide, but can also sense the presence of these compounds in the first place.

Zinc oxide is fluorescent: it absorbs ultraviolet light and re-emits the energy as green light. This light level falls by 15% when zinc oxide is exposed to just one part per million of chlorinated aromatic molecules - a few drops in a bath of water.

When such a solution is exposed to strong UV irradiation, a film of zinc oxide particles reacts with the organic molecules, converting them to harmless substances. After several hours of irradiation, the film’s fluorescence increases, because there is less chlorinated compound left.

In a water-purification system, this brightening green light could signal that most of the contaminant has been destroyed, triggering a shutdown of the ultraviolet irradiation.

Whether such a system will be commercially viable depends on whether the contaminants can be removed efficiently and quickly enough.

References

  1. Kamat, P. V., Huehn, R. & Nicolaescu, R. A ’sense and shoot’ approach for photocatalytic degradation of organic contaminants in water. Journal of Physical Chemistry B, 106, 788 - 794, (2002).


PHILIP BALL | © Nature News Service

More articles from Ecology, The Environment and Conservation:

nachricht Global threat to primates concerns us all
19.01.2017 | Deutsches Primatenzentrum GmbH - Leibniz-Institut für Primatenforschung

nachricht Reducing household waste with less energy
18.01.2017 | FIZ Karlsruhe – Leibniz-Institut für Informationsinfrastruktur GmbH

All articles from Ecology, The Environment and Conservation >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Traffic jam in empty space

New success for Konstanz physicists in studying the quantum vacuum

An important step towards a completely new experimental access to quantum physics has been made at University of Konstanz. The team of scientists headed by...

Im Focus: How gut bacteria can make us ill

HZI researchers decipher infection mechanisms of Yersinia and immune responses of the host

Yersiniae cause severe intestinal infections. Studies using Yersinia pseudotuberculosis as a model organism aim to elucidate the infection mechanisms of these...

Im Focus: Interfacial Superconductivity: Magnetic and superconducting order revealed simultaneously

Researchers from the University of Hamburg in Germany, in collaboration with colleagues from the University of Aarhus in Denmark, have synthesized a new superconducting material by growing a few layers of an antiferromagnetic transition-metal chalcogenide on a bismuth-based topological insulator, both being non-superconducting materials.

While superconductivity and magnetism are generally believed to be mutually exclusive, surprisingly, in this new material, superconducting correlations...

Im Focus: Studying fundamental particles in materials

Laser-driving of semimetals allows creating novel quasiparticle states within condensed matter systems and switching between different states on ultrafast time scales

Studying properties of fundamental particles in condensed matter systems is a promising approach to quantum field theory. Quasiparticles offer the opportunity...

Im Focus: Designing Architecture with Solar Building Envelopes

Among the general public, solar thermal energy is currently associated with dark blue, rectangular collectors on building roofs. Technologies are needed for aesthetically high quality architecture which offer the architect more room for manoeuvre when it comes to low- and plus-energy buildings. With the “ArKol” project, researchers at Fraunhofer ISE together with partners are currently developing two façade collectors for solar thermal energy generation, which permit a high degree of design flexibility: a strip collector for opaque façade sections and a solar thermal blind for transparent sections. The current state of the two developments will be presented at the BAU 2017 trade fair.

As part of the “ArKol – development of architecturally highly integrated façade collectors with heat pipes” project, Fraunhofer ISE together with its partners...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

Sustainable Water use in Agriculture in Eastern Europe and Central Asia

19.01.2017 | Event News

12V, 48V, high-voltage – trends in E/E automotive architecture

10.01.2017 | Event News

2nd Conference on Non-Textual Information on 10 and 11 May 2017 in Hannover

09.01.2017 | Event News

 
Latest News

Helmholtz International Fellow Award for Sarah Amalia Teichmann

20.01.2017 | Awards Funding

An innovative high-performance material: biofibers made from green lacewing silk

20.01.2017 | Materials Sciences

Ion treatments for cardiac arrhythmia — Non-invasive alternative to catheter-based surgery

20.01.2017 | Life Sciences

VideoLinks
B2B-VideoLinks
More VideoLinks >>>