Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Novel recycling methods: The fluorescent fingerprint of plastics

22.08.2014

LMU researchers have developed a new process which will greatly simplify the process of sorting plastics in recycling plants. The method enables automated identification of polymers, facilitating rapid separation of plastics for re-use.

A team of researchers led by Professor Heinz Langhals of LMU’s Department of Chemistry has taken a significant step which promises to markedly expedite the recycling of plastic waste. They have developed a technique which provides for automated recognition of their polymer constituents, thus improving the efficiency of recycling and re-use of the various types of plastic.


Photo: Alterfalter / Fotolia.com

The technique takes advantage of the polymer-specific nature of the intrinsic fluorescence induced by photoexcitation. “Plastics emit fluorescent light when exposed to a brief flash of light, and the emission decays with time in a distinctive pattern.

Thus, their fluorescence lifetimes are highly characteristic for the different types of polymers, and can serve as an identifying fingerprint,” Langhals explains. Details of the new method appear in the latest issue of the journal “Green and Sustainable Chemistry”.

The new technique, which is the subject of a patent application, involves exposing particles of plastic to a brief flash of light which causes the material to fluoresce. Photoelectric sensors then measure the intensity of the light emitted in response to the inducing photoexcitation to determine the dynamics of its decay.

Because the different polymer materials used in the manufacture of plastics display specific fluorescence lifetimes, the form of the decay curve can be used to identify their chemical nature. “With this process, errors in measurement are practically ruled out; for any given material, one will always obtain the same value for the fluorescence half-life, just as in the case of radioactive decay,” says Langhals.

Turning bottles into windcheaters
Unlike metals, the quality of which often suffers during the recycling process itself, recycled plastics can be processed quite efficiently. “Polymers represent an interesting basis for the sustainable cycling of technological materials. The crucial requirement is that the recycled material should be chemically pure. In that case, bottles made of PET, for example, can be relatively easily turned into synthetic fiber for use in waterproof windcheaters,” says Langhals.

The vast majority of technical polymers are processed as thermoplastics, i.e., they are melted at high temperature and the finished article is produced by injecting the molten material into an appropriate mold, where it allowed to set. Reheating of recycled plastic can, however, lead to deleterious alterations in its properties of the material unless the sorted material is of high purity.

Contamination levels as low as 5% are sufficient to significantly reduce the quality of the reformed product. The reason for this “down-cycling” effect is that, as a general rule, polymers tend to be immiscible, as they are chemically incompatible with one another.

Remelting of polymer mixtures therefore often leads to partitioning of the different polymers into distinct domains separated by grain boundaries, which compromises the quality of the final product. For this reason, high-quality plastics are always manufactured exclusively from pristine precursors – never from recycled material.

The new method developed by the LMU team could, however, change this. “The waste problem can only be solved by chemical means, and our process can make a significant contribution to environmental protection, because it makes automated sorting feasible,” says Langhals. Indeed, the use of fluorescence lifetime measurements permits the identification and sorting of up to 1.5 tons of plastic per hour. In other words, the method in its present form already meets the specifications required for its application on an industrial scale.
(Green and Sustainable Chemistry, 2014)                       

Luise Dirscherl | Eurek Alert!
Further information:
http://www.en.uni-muenchen.de/news/newsarchiv/2014/langhals_plastikmuell.html

More articles from Ecology, The Environment and Conservation:

nachricht Engineers purify sea and wastewater in 2.5 minutes
17.04.2015 | Investigación y Desarrollo

nachricht Expanding rubber plantations 'catastrophic' for endangered species in Southeast Asia
17.04.2015 | University of East Anglia

All articles from Ecology, The Environment and Conservation >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Astronomers reveal supermassive black hole's intense magnetic field

Astronomers from Chalmers University of Technology have used the giant telescope Alma to reveal an extremely powerful magnetic field very close to a supermassive black hole in a distant galaxy

Astronomers from Chalmers University of Technology have used the giant telescope Alma to reveal an extremely powerful magnetic field very close to a...

Im Focus: A “pin ball machine” for atoms and photons

A team of physicists from MPQ, Caltech, and ICFO proposes the combination of nano-photonics with ultracold atoms for simulating quantum many-body systems and creating new states of matter.

Ultracold atoms in the so-called optical lattices, that are generated by crosswise superposition of laser beams, have been proven to be one of the most...

Im Focus: UV light robot to clean hospital rooms could help stop spread of 'superbugs'

Can a robot clean a hospital room just as well as a person?

According to new research out of the Texas A&M Health Science Center College of Medicine, that is indeed the case. Chetan Jinadatha, M.D., M.P.H., assistant...

Im Focus: Graphene pushes the speed limit of light-to-electricity conversion

Researchers from ICFO, MIT and UC Riverside have been able to develop a graphene-based photodetector capable of converting absorbed light into an electrical voltage at ultrafast timescales

The efficient conversion of light into electricity plays a crucial role in many technologies, ranging from cameras to solar cells.

Im Focus: Study shows novel pattern of electrical charge movement through DNA

Electrical charges not only move through wires, they also travel along lengths of DNA, the molecule of life. The property is known as charge transport.

In a new study appearing in the journal Nature Chemistry, authors, Limin Xiang, Julio Palma, Christopher Bruot and others at Arizona State University's...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

HHL's Entrepreneurship Conference on FinTech

13.04.2015 | Event News

World Conference On Regenerative Medicine 2015: Registration And Abstract Submission Now Open

25.03.2015 | Event News

University presidents from all over the world meet in Hamburg

19.03.2015 | Event News

 
Latest News

Engineer Improves Rechargeable Batteries with MoS2 Nano 'Sandwich'

17.04.2015 | Power and Electrical Engineering

Comparing Climate Models to Real World Shows Differences in Precipitation Intensity

17.04.2015 | Earth Sciences

A blueprint for clearing the skies of space debris

17.04.2015 | Physics and Astronomy

VideoLinks
B2B-VideoLinks
More VideoLinks >>>