Researchers at Rensselaer Polytechnic Institute have developed a new energy storage device that easily could be mistaken for a simple sheet of black paper.
The nanoengineered battery is lightweight, ultra thin, completely flexible, and geared toward meeting the trickiest design and energy requirements of tomorrow’s gadgets, implantable medical equipment, and transportation vehicles.
Along with its ability to function in temperatures up to 300 degrees Fahrenheit and down to 100 below zero, the device is completely integrated and can be printed like paper. The device is also unique in that it can function as both a high-energy battery and a high-power supercapacitor, which are generally separate components in most electrical systems. Another key feature is the capability to use human blood or sweat to help power the battery.
Details of the project are outlined in the paper “Flexible Energy Storage Devices Based on Nanocomposite Paper” published Aug. 13 in the Proceedings of the National Academy of Sciences.
The semblance to paper is no accident: more than 90 percent of the device is made up of cellulose, the same plant cells used in newsprint, loose leaf, lunch bags, and nearly every other type of paper.
Rensselaer researchers infused this paper with aligned carbon nanotubes, which give the device its black color. The nanotubes act as electrodes and allow the storage devices to conduct electricity. The device, engineered to function as both a lithium-ion battery and a supercapacitor, can provide the long, steady power output comparable to a conventional battery, as well as a supercapacitor’s quick burst of high energy.
The device can be rolled, twisted, folded, or cut into any number of shapes with no loss of mechanical integrity or efficiency. The paper batteries can also be stacked, like a ream of printer paper, to boost the total power output.
“It’s essentially a regular piece of paper, but it’s made in a very intelligent way,” said paper co-author Robert Linhardt, the Ann and John H. Broadbent Senior Constellation Professor of Biocatalysis and Metabolic Engineering at Rensselaer.
“We’re not putting pieces together – it’s a single, integrated device,” he said. “The components are molecularly attached to each other: the carbon nanotube print is embedded in the paper, and the electrolyte is soaked into the paper. The end result is a device that looks, feels, and weighs the same as paper.”
The creation of this unique nanocomposite paper drew from a diverse pool of disciplines, requiring expertise in materials science, energy storage, and chemistry. Along with Linhardt, authors of the paper include Pulickel M. Ajayan, professor of materials science and engineering, and Omkaram Nalamasu, professor of chemistry with a joint appointment in materials science and engineering. Senior research specialist Victor Pushparaj, along with postdoctoral research associates Shaijumon M. Manikoth, Ashavani Kumar, and Saravanababu Murugesan, were co-authors and lead researchers of the project. Other co-authors include research associate Lijie Ci and Rensselaer Nanotechnology Center Laboratory Manager Robert Vajtai.
The researchers used ionic liquid, essentially a liquid salt, as the battery’s electrolyte. It’s important to note that ionic liquid contains no water, which means there’s nothing in the batteries to freeze or evaporate. “This lack of water allows the paper energy storage devices to withstand extreme temperatures,” Kumar said.
Along with use in small handheld electronics, the paper batteries’ light weight could make them ideal for use in automobiles, aircraft, and even boats. The paper also could be molded into different shapes, such as a car door, which would enable important new engineering innovations.
“Plus, because of the high paper content and lack of toxic chemicals, it’s environmentally safe,” Shaijumon said.
Paper is also extremely biocompatible and these new hybrid battery/supercapcitors have potential as power supplies for devices implanted in the body. The team printed paper batteries without adding any electrolytes, and demonstrated that naturally occurring electrolytes in human sweat, blood, and urine can be used to activate the battery device.
“It’s a way to power a small device such as a pacemaker without introducing any harsh chemicals – such as the kind that are typically found in batteries – into the body,” Pushparaj said.
The materials required to create the paper batteries are inexpensive, Murugesan said, but the team has not yet developed a way to inexpensively mass produce the devices. The end goal is to print the paper using a roll-to-roll system similar to how newspapers are printed.
“When we get this technology down, we’ll basically have the ability to print batteries and print supercapacitors,” Ajayan said. “We see this as a technology that’s just right for the current energy market, as well as the electronics industry, which is always looking for smaller, lighter power sources. Our device could make its way into any number of different applications.”
The team of researchers has already filed a patent protecting the invention. They are now working on ways to boost the efficiency of the batteries and supercapacitors, and investigating different manufacturing techniques.
"Energy storage is an area that can be addressed by nanomanufacturing technologies and our truly inter-disciplinary collaborative activity that brings together advances and expertise in nanotechnology, room-temperature ionic liquids, and energy storage devices in a creative way to devise novel battery and supercapacitor devices," Nalamasu said.
Michael Mullaney | EurekAlert!
Failures in power grids: Dynamically induced cascades
25.05.2018 | Technische Universität Dresden
Beyond the limits of conventional electronics: stable organic molecular nanowires
24.05.2018 | Tokyo Institute of Technology
The more electronics steer, accelerate and brake cars, the more important it is to protect them against cyber-attacks. That is why 15 partners from industry and academia will work together over the next three years on new approaches to IT security in self-driving cars. The joint project goes by the name Security For Connected, Autonomous Cars (SecForCARs) and has funding of €7.2 million from the German Federal Ministry of Education and Research. Infineon is leading the project.
Vehicles already offer diverse communication interfaces and more and more automated functions, such as distance and lane-keeping assist systems. At the same...
A research team led by physicists at the Technical University of Munich (TUM) has developed molecular nanoswitches that can be toggled between two structurally different states using an applied voltage. They can serve as the basis for a pioneering class of devices that could replace silicon-based components with organic molecules.
The development of new electronic technologies drives the incessant reduction of functional component sizes. In the context of an international collaborative...
At the LASYS 2018, from June 5th to 7th, the Laser Zentrum Hannover e.V. (LZH) will be showcasing processes for the laser material processing of tomorrow in hall 4 at stand 4E75. With blown bomb shells the LZH will present first results of a research project on civil security.
At this year's LASYS, the LZH will exhibit light-based processes such as cutting, welding, ablation and structuring as well as additive manufacturing for...
There are videos on the internet that can make one marvel at technology. For example, a smartphone is casually bent around the arm or a thin-film display is rolled in all directions and with almost every diameter. From the user's point of view, this looks fantastic. From a professional point of view, however, the question arises: Is that already possible?
At Display Week 2018, scientists from the Fraunhofer Institute for Applied Polymer Research IAP will be demonstrating today’s technological possibilities and...
So-called quantum many-body scars allow quantum systems to stay out of equilibrium much longer, explaining experiment | Study published in Nature Physics
Recently, researchers from Harvard and MIT succeeded in trapping a record 53 atoms and individually controlling their quantum state, realizing what is called a...
25.05.2018 | Event News
02.05.2018 | Event News
13.04.2018 | Event News
25.05.2018 | Event News
25.05.2018 | Machine Engineering
25.05.2018 | Life Sciences