Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


Hydrothermal liquefaction -- the most promising path to a sustainable bio-oil production

Scientists at 2 Danish universities have made a major breakthrough in producing high-quality and cost-effective bio-oil using hydrothermal liquefaction

A new generation of the HTL process can convert all kinds of biomasses to crude bio-oil, which is sufficiently similar to fossil crude oil that a simple thermal upgrade and existing refinery technology can be employed to subsequently obtain all the liquid fuels we know today.

What is more, the HTL process only consumes approximately 10-15 percent of the energy in the feedstock biomass, yielding an energy efficiency of 85-90 percent.

To emphasize, the HTL process accepts all biomasses from modern society – sewage sludge, manure, wood, compost and plant material along with waste from households, meat factories, dairy production and similar industries.

It is by far the most feedstock flexible of any liquid fuel producing process, including pyrolysis, bio-ethanol, gasification with Fischer-Tropsch or catalytic upgrading of different vegetable or agro-industrial residual oils, and does not carry higher costs than these.

Hydrothermal liquefaction is basically pressure cooking, but instead of cooking the biomass in batches, one pot-full at a time, this new generation of HTL is based on flow production, where the biomass is injected into a 400 °C pre-heated reactor, "cooked" under high pressure for ~15 minutes and then quickly cooled down to 70°C.

At 400°C and high pressure the water is in a supercritical state, neither liquid nor gas, at which it easily decomposes the biomass. The process is environmentally friendly, since no harmful solvents are involved, and the energy efficiency is very high: The HTL process only consumes approximately 10-15% of the energy in the feedstock biomass, because the heat energy is recycled between the heating and cooling of the process medium.

The wet medium means that HTL readily accepts moist or wet biomasses, such as those mentioned above. Wet biomasses are in vast majority on Earth. All other known processes for liquid bio-fuel production either require expensive drying or only make use of a limited proportion of the biomass, e.g. the carbohydrate content.

The water phase emanating from the HTL process has low carbon contents and can either be recycled into the process or ultimately be purified to attain drinking water quality, which is the long-term goal. As such HTL replaces the burden of disposal with the benefit of recycling.

The HTL process has the following benefits:
Crude HTL oil has high heating values of approximately 35-39 MJ/kg on a dry ash free basis
The HTL process only consumes approximately 10-15% of the energy in the feedstock biomass, yielding an energy efficiency of 85-90%
Crude HTL oil has very low oxygen, sulphur and water content (compared to e.g. pyrolysis oil which typically contains approx. 50% water)
HTL oil recovers more than 70% of the feedstock carbon content (single pass)
HTL oil is storage stable, and has comparatively low upgrading requirements, due in part to a high fraction of middle distillates in the crude oil. It is much less upgrading intensive than e.g. pyrolysis oil, which needs immediate upgrading in order not to deteriorate.

The bio-oil from HTL can be used as-produced in heavy engines or it can be hydrogenated or thermally upgraded to obtain diesel-, gasoline- or jet-fuels by existing refinery technology. In this sense, HTL bio-oil is directly comparable to fossil crude oil. This is unique among liquid bio-fuels and means that it can directly enter the existing fuel distribution network for automotive transportation in any concentration, giving it full drop-in properties.

In Denmark, Aarhus University and Aalborg University are in partnership on HTL research at all levels. In Aarhus, Dept. of Chemistry focuses on fundamental understanding of the process and quick surveys of the effects of different feedstocks and catalysts along with subsequent upgrading. Dept. of Agro-Ecology develops energy crops while Dept. of Engineering works on pilot-scale HTL. The latter is pursued even more vigorously at Aalborg University (Dept. of Energy Technology), which focuses strongly on pilot-scale production and process efficiency, as well as upgrading of HTL bio-oil along with end user testing of oils and upgraded distillates in engines and turbines. The Dept. of Biotechnology, Chemistry and Environmental Engineering, AAU Esbjerg, directs its activities towards extracting value not only from the oil, but also from the effluents.

The combined efforts and unique results already obtained hold promise of another energy technology endeavor in Denmark comparable only to the breakthrough of the windmill-industry in the 1980's.

About the HTL process:

- HTL operates in hot, compressed water at >300 degrees C and >200 bar, often assisted by catalysts
- Boiling is suppressed, i.e. no energy is expended to overcome the latent heat of evaporation
- Successful HTL is dependent on extremely swift heating and cooling of the biomass, in order to avoid the formation of tar or ash compounds
- Heat energy is recycled between the heating and cooling of the process medium
- A typical Pilot-scale plant yields ~30 liters of bio-oil per day – one such plant is being built at Aalborg University
- An industrial scale plant can be anything from 300 barrels per day up several thousand, comparable to fossil oil wells
- Some HTL has made use of heterogeneous as well as homogeneous catalysts, e.g. ZrO2

- Recently, Aarhus University has shown that ZrO2 has no effect on HTL of the biomass DDGS

Little-known facts on H2O:

- The boiling phenomenon of water is fully suppressed at pressures above 221 atm. This is called the critical pressure.
- There is also a critical temperature – 374oC
- At higher temperatures and pressures, water is said to be in the supercritical domain.
- At slightly lower temperatures (300-350oC) the near-critical domain exists.
- Near-critical water can sustain acid and base ions simultaneously to a factor of 1000 above concentrations at ambient conditions
- Supercritical water is non-polar and mixes freely with oil substances. It also promotes radical-driven chemistry.
- Most scientific literature agree that HTL works best at near-critical conditions

- Recently, Aarhus University has shown that the best HTL oil yields are in fact obtained at supercritical conditions

Jacob Becker | EurekAlert!
Further information:

More articles from Power and Electrical Engineering:

nachricht Fraunhofer ISE Pushes World Record for Multicrystalline Silicon Solar Cells to 22.3 Percent
25.09.2017 | Fraunhofer-Institut für Solare Energiesysteme ISE

nachricht Producing electricity during flight
20.09.2017 | Albert-Ludwigs-Universität Freiburg im Breisgau

All articles from Power and Electrical Engineering >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: LaserTAB: More efficient and precise contacts thanks to human-robot collaboration

At the productronica trade fair in Munich this November, the Fraunhofer Institute for Laser Technology ILT will be presenting Laser-Based Tape-Automated Bonding, LaserTAB for short. The experts from Aachen will be demonstrating how new battery cells and power electronics can be micro-welded more efficiently and precisely than ever before thanks to new optics and robot support.

Fraunhofer ILT from Aachen relies on a clever combination of robotics and a laser scanner with new optics as well as process monitoring, which it has developed...

Im Focus: The pyrenoid is a carbon-fixing liquid droplet

Plants and algae use the enzyme Rubisco to fix carbon dioxide, removing it from the atmosphere and converting it into biomass. Algae have figured out a way to increase the efficiency of carbon fixation. They gather most of their Rubisco into a ball-shaped microcompartment called the pyrenoid, which they flood with a high local concentration of carbon dioxide. A team of scientists at Princeton University, the Carnegie Institution for Science, Stanford University and the Max Plank Institute of Biochemistry have unravelled the mysteries of how the pyrenoid is assembled. These insights can help to engineer crops that remove more carbon dioxide from the atmosphere while producing more food.

A warming planet

Im Focus: Highly precise wiring in the Cerebral Cortex

Our brains house extremely complex neuronal circuits, whose detailed structures are still largely unknown. This is especially true for the so-called cerebral cortex of mammals, where among other things vision, thoughts or spatial orientation are being computed. Here the rules by which nerve cells are connected to each other are only partly understood. A team of scientists around Moritz Helmstaedter at the Frankfiurt Max Planck Institute for Brain Research and Helene Schmidt (Humboldt University in Berlin) have now discovered a surprisingly precise nerve cell connectivity pattern in the part of the cerebral cortex that is responsible for orienting the individual animal or human in space.

The researchers report online in Nature (Schmidt et al., 2017. Axonal synapse sorting in medial entorhinal cortex, DOI: 10.1038/nature24005) that synapses in...

Im Focus: Tiny lasers from a gallery of whispers

New technique promises tunable laser devices

Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...

Im Focus: Ultrafast snapshots of relaxing electrons in solids

Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!

When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...

All Focus news of the innovation-report >>>



Event News

“Lasers in Composites Symposium” in Aachen – from Science to Application

19.09.2017 | Event News

I-ESA 2018 – Call for Papers

12.09.2017 | Event News

EMBO at Basel Life, a new conference on current and emerging life science research

06.09.2017 | Event News

Latest News

Fraunhofer ISE Pushes World Record for Multicrystalline Silicon Solar Cells to 22.3 Percent

25.09.2017 | Power and Electrical Engineering

Usher syndrome: Gene therapy restores hearing and balance

25.09.2017 | Health and Medicine

An international team of physicists a coherent amplification effect in laser excited dielectrics

25.09.2017 | Physics and Astronomy

More VideoLinks >>>