Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


Hydrothermal liquefaction -- the most promising path to a sustainable bio-oil production

Scientists at 2 Danish universities have made a major breakthrough in producing high-quality and cost-effective bio-oil using hydrothermal liquefaction

A new generation of the HTL process can convert all kinds of biomasses to crude bio-oil, which is sufficiently similar to fossil crude oil that a simple thermal upgrade and existing refinery technology can be employed to subsequently obtain all the liquid fuels we know today.

What is more, the HTL process only consumes approximately 10-15 percent of the energy in the feedstock biomass, yielding an energy efficiency of 85-90 percent.

To emphasize, the HTL process accepts all biomasses from modern society – sewage sludge, manure, wood, compost and plant material along with waste from households, meat factories, dairy production and similar industries.

It is by far the most feedstock flexible of any liquid fuel producing process, including pyrolysis, bio-ethanol, gasification with Fischer-Tropsch or catalytic upgrading of different vegetable or agro-industrial residual oils, and does not carry higher costs than these.

Hydrothermal liquefaction is basically pressure cooking, but instead of cooking the biomass in batches, one pot-full at a time, this new generation of HTL is based on flow production, where the biomass is injected into a 400 °C pre-heated reactor, "cooked" under high pressure for ~15 minutes and then quickly cooled down to 70°C.

At 400°C and high pressure the water is in a supercritical state, neither liquid nor gas, at which it easily decomposes the biomass. The process is environmentally friendly, since no harmful solvents are involved, and the energy efficiency is very high: The HTL process only consumes approximately 10-15% of the energy in the feedstock biomass, because the heat energy is recycled between the heating and cooling of the process medium.

The wet medium means that HTL readily accepts moist or wet biomasses, such as those mentioned above. Wet biomasses are in vast majority on Earth. All other known processes for liquid bio-fuel production either require expensive drying or only make use of a limited proportion of the biomass, e.g. the carbohydrate content.

The water phase emanating from the HTL process has low carbon contents and can either be recycled into the process or ultimately be purified to attain drinking water quality, which is the long-term goal. As such HTL replaces the burden of disposal with the benefit of recycling.

The HTL process has the following benefits:
Crude HTL oil has high heating values of approximately 35-39 MJ/kg on a dry ash free basis
The HTL process only consumes approximately 10-15% of the energy in the feedstock biomass, yielding an energy efficiency of 85-90%
Crude HTL oil has very low oxygen, sulphur and water content (compared to e.g. pyrolysis oil which typically contains approx. 50% water)
HTL oil recovers more than 70% of the feedstock carbon content (single pass)
HTL oil is storage stable, and has comparatively low upgrading requirements, due in part to a high fraction of middle distillates in the crude oil. It is much less upgrading intensive than e.g. pyrolysis oil, which needs immediate upgrading in order not to deteriorate.

The bio-oil from HTL can be used as-produced in heavy engines or it can be hydrogenated or thermally upgraded to obtain diesel-, gasoline- or jet-fuels by existing refinery technology. In this sense, HTL bio-oil is directly comparable to fossil crude oil. This is unique among liquid bio-fuels and means that it can directly enter the existing fuel distribution network for automotive transportation in any concentration, giving it full drop-in properties.

In Denmark, Aarhus University and Aalborg University are in partnership on HTL research at all levels. In Aarhus, Dept. of Chemistry focuses on fundamental understanding of the process and quick surveys of the effects of different feedstocks and catalysts along with subsequent upgrading. Dept. of Agro-Ecology develops energy crops while Dept. of Engineering works on pilot-scale HTL. The latter is pursued even more vigorously at Aalborg University (Dept. of Energy Technology), which focuses strongly on pilot-scale production and process efficiency, as well as upgrading of HTL bio-oil along with end user testing of oils and upgraded distillates in engines and turbines. The Dept. of Biotechnology, Chemistry and Environmental Engineering, AAU Esbjerg, directs its activities towards extracting value not only from the oil, but also from the effluents.

The combined efforts and unique results already obtained hold promise of another energy technology endeavor in Denmark comparable only to the breakthrough of the windmill-industry in the 1980's.

About the HTL process:

- HTL operates in hot, compressed water at >300 degrees C and >200 bar, often assisted by catalysts
- Boiling is suppressed, i.e. no energy is expended to overcome the latent heat of evaporation
- Successful HTL is dependent on extremely swift heating and cooling of the biomass, in order to avoid the formation of tar or ash compounds
- Heat energy is recycled between the heating and cooling of the process medium
- A typical Pilot-scale plant yields ~30 liters of bio-oil per day – one such plant is being built at Aalborg University
- An industrial scale plant can be anything from 300 barrels per day up several thousand, comparable to fossil oil wells
- Some HTL has made use of heterogeneous as well as homogeneous catalysts, e.g. ZrO2

- Recently, Aarhus University has shown that ZrO2 has no effect on HTL of the biomass DDGS

Little-known facts on H2O:

- The boiling phenomenon of water is fully suppressed at pressures above 221 atm. This is called the critical pressure.
- There is also a critical temperature – 374oC
- At higher temperatures and pressures, water is said to be in the supercritical domain.
- At slightly lower temperatures (300-350oC) the near-critical domain exists.
- Near-critical water can sustain acid and base ions simultaneously to a factor of 1000 above concentrations at ambient conditions
- Supercritical water is non-polar and mixes freely with oil substances. It also promotes radical-driven chemistry.
- Most scientific literature agree that HTL works best at near-critical conditions

- Recently, Aarhus University has shown that the best HTL oil yields are in fact obtained at supercritical conditions

Jacob Becker | EurekAlert!
Further information:

More articles from Power and Electrical Engineering:

nachricht Organic-inorganic heterostructures with programmable electronic properties
29.03.2017 | Technische Universität Dresden

nachricht Researchers use light to remotely control curvature of plastics
23.03.2017 | North Carolina State University

All articles from Power and Electrical Engineering >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: A Challenging European Research Project to Develop New Tiny Microscopes

The Institute of Semiconductor Technology and the Institute of Physical and Theoretical Chemistry, both members of the Laboratory for Emerging Nanometrology (LENA), at Technische Universität Braunschweig are partners in a new European research project entitled ChipScope, which aims to develop a completely new and extremely small optical microscope capable of observing the interior of living cells in real time. A consortium of 7 partners from 5 countries will tackle this issue with very ambitious objectives during a four-year research program.

To demonstrate the usefulness of this new scientific tool, at the end of the project the developed chip-sized microscope will be used to observe in real-time...

Im Focus: Giant Magnetic Fields in the Universe

Astronomers from Bonn and Tautenburg in Thuringia (Germany) used the 100-m radio telescope at Effelsberg to observe several galaxy clusters. At the edges of these large accumulations of dark matter, stellar systems (galaxies), hot gas, and charged particles, they found magnetic fields that are exceptionally ordered over distances of many million light years. This makes them the most extended magnetic fields in the universe known so far.

The results will be published on March 22 in the journal „Astronomy & Astrophysics“.

Galaxy clusters are the largest gravitationally bound structures in the universe. With a typical extent of about 10 million light years, i.e. 100 times the...

Im Focus: Tracing down linear ubiquitination

Researchers at the Goethe University Frankfurt, together with partners from the University of Tübingen in Germany and Queen Mary University as well as Francis Crick Institute from London (UK) have developed a novel technology to decipher the secret ubiquitin code.

Ubiquitin is a small protein that can be linked to other cellular proteins, thereby controlling and modulating their functions. The attachment occurs in many...

Im Focus: Perovskite edges can be tuned for optoelectronic performance

Layered 2D material improves efficiency for solar cells and LEDs

In the eternal search for next generation high-efficiency solar cells and LEDs, scientists at Los Alamos National Laboratory and their partners are creating...

Im Focus: Polymer-coated silicon nanosheets as alternative to graphene: A perfect team for nanoelectronics

Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are less stable. Now researchers at the Technical University of Munich (TUM) have, for the first time ever, produced a composite material combining silicon nanosheets and a polymer that is both UV-resistant and easy to process. This brings the scientists a significant step closer to industrial applications like flexible displays and photosensors.

Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are...

All Focus news of the innovation-report >>>



Event News

International Land Use Symposium ILUS 2017: Call for Abstracts and Registration open

20.03.2017 | Event News

CONNECT 2017: International congress on connective tissue

14.03.2017 | Event News

ICTM Conference: Turbine Construction between Big Data and Additive Manufacturing

07.03.2017 | Event News

Latest News

Researchers shoot for success with simulations of laser pulse-material interactions

29.03.2017 | Materials Sciences

Igniting a solar flare in the corona with lower-atmosphere kindling

29.03.2017 | Physics and Astronomy

As sea level rises, much of Honolulu and Waikiki vulnerable to groundwater inundation

29.03.2017 | Earth Sciences

More VideoLinks >>>