Joseph Wang has successfully printed thick-film electrochemical sensors directly on flexible wetsuit material, paving the way for nano devices to detect underwater explosives or ocean contamination.
“We have a long-term interest in on-body electrochemical monitoring for medical and security applications,” said Wang, a professor in the Department of NanoEngineering in UC San Diego’s Jacobs School of Engineering. “In the past three years we’ve been working on flexible, printable sensors, and the capabilities of our group made it possible to extend these systems for use underwater.”
Wang notes that some members of his team – including electrical-engineering graduate student Joshua Windmiller – are surfers. Given the group’s continued funding from the U.S. Navy, and its location in La Jolla, it was a logical leap to see if it would be possible to print sensors on neoprene, the synthetic-rubber fabric typically used in wetsuits for divers and surfers.
The result: development of “wearable electrochemical sensors for in situ analysis in marine environments.” The paper, published last month in the journal Analyst*, was co-authored by UCSD’s Wang, Windmiller and visiting scholar Gabriela Valdés-Ramírez from Mexico, as well as Michael J. Schöning and Kerstin Malzahn from the Institute of Nano- and Biotechnologies of Germany’s Aachen University of Applied Sciences. (Malzahn is currently a visiting graduate student at UCSD from the German university.)
UCSD has a full U.S. patent pending on the technology, and has begun talks on licensing the system to a Fortune 500 company.
Wang’s 20-person research group is a world leader in the field of printable sensors. But to prove that the sensors printed on neoprene could take a beating and continue working, some of Wang’s colleagues took to the water.
“Anyone trying to take chemical readings under the water will typically have to carry a portable analyzer if they want to detect pollutants,” said Wang, whose group is based in the California Institute for Telecommunications and Information Technology (Calit2) at UCSD. “Instead, we printed a three-electrode sensor directly on the arm of the wetsuit, and inside the neoprene we embedded a 3-volt battery and electronics.”
The electrochemical sensors are based on applying voltage to drive a reduction-oxidation (redox) reaction in a target threat or contaminant – which loses or gains electrons – then measuring the current output. The wearable microsystem provides a visual indication and alert if the levels of harmful contaminants or explosives exceed a pre-defined threshold. It does so by mixing different enzymes into the carbon ink layer before printing on the fabric. (For example, if the enzyme tyrosinase interacts with the pollutant phenol, the LED light switches from green to red.)
The electronics are packed into a device known as a potentiostat that is barely 19mm by 19mm. (The battery is stored on the reverse side of the circuit board.)
In the experiments described in the Analyst article, Wang and his team tested sensors for three potential hazards: a toxic metal (copper); a common industrial pollutant, phenol; and an explosive (TNT). The device also has the potential to detect multiple hazards. “In the paper we used only one electrode,” noted Wang, “but you can have an array of electrodes, each with its own reagent to detect simultaneously multiple contaminants.”
The researchers believe that neoprene is a particularly good fabric on which to print sensors because it is elastic and repels water. It permits high-resolution printing with no apparent defects.
The UCSD team tested the sensor for explosives because of the security hazard highlighted by the 2000 attack on the USS Cole in Yemen. The Navy commonly checks for underwater explosives using a bulky device that a diver must carry underwater to scan the ship’s hull. Using the microsystem developed by Wang and his team, the sensor printed on a wetsuit can quickly and easily alert the diver to nearby explosives.
Wang’s lab has extensive experience printing sensors on flexible fabrics, most recently demonstrating that biosensors printed on the rubber waistband of underwear can be used continuously to monitor the vital signs of soldiers or athletes. The researchers were uncertain, however, about whether bending the printed sensors under water – and in seawater – would still let them continue functioning properly.
In the end, even underwater, and with bending and other deformations, the sensors continued to perform well. “We still need to validate and test it with the Navy,” said Wang. “While the primary security interest will be in the detection of explosives, the Navy in San Diego bay has also detected large concentrations of toxic metals from the paint on Navy ships, so in principle we should be able to print sensors that can detect metals and explosives simultaneously.”
Wang’s work in flexible sensors grew out of 20 years’ experience with innovations in glucose monitoring, ultimately in the form of flexible glucose strips that now account for a $10 billion market worldwide.
Work on the underwater sensors was supported by the Office of Naval Research.
* Wearable electrochemical sensors for in situ analysis in marine environments, Kerstin Malzahn, Joshua Ray Windmiller, Gabriela Valdés-Ramírez, Michael J. Schöning and Joseph Wang, Analyst, June 2011.
Doug Ramsey | Newswise Science News
Further reports about: > Applied Science > Autonomous underwater vehicle > Flexible Arbeitszeiten > Hazards > Navy > Printable Sensors > Sensors > UCSD > Underwater Hazards > chemical sensor > electrochemical sensors > light switch > marine environment > on-body electrochemical monitoring > security applications > thick-film electrochemical sensors > toxic metal
Waste from paper and pulp industry supplies raw material for development of new redox flow batteries
12.10.2017 | Johannes Gutenberg-Universität Mainz
Low-cost battery from waste graphite
11.10.2017 | Empa - Eidgenössische Materialprüfungs- und Forschungsanstalt
University of Maryland researchers contribute to historic detection of gravitational waves and light created by event
On August 17, 2017, at 12:41:04 UTC, scientists made the first direct observation of a merger between two neutron stars--the dense, collapsed cores that remain...
Seven new papers describe the first-ever detection of light from a gravitational wave source. The event, caused by two neutron stars colliding and merging together, was dubbed GW170817 because it sent ripples through space-time that reached Earth on 2017 August 17. Around the world, hundreds of excited astronomers mobilized quickly and were able to observe the event using numerous telescopes, providing a wealth of new data.
Previous detections of gravitational waves have all involved the merger of two black holes, a feat that won the 2017 Nobel Prize in Physics earlier this month....
Material defects in end products can quickly result in failures in many areas of industry, and have a massive impact on the safe use of their products. This is why, in the field of quality assurance, intelligent, nondestructive sensor systems play a key role. They allow testing components and parts in a rapid and cost-efficient manner without destroying the actual product or changing its surface. Experts from the Fraunhofer IZFP in Saarbrücken will be presenting two exhibits at the Blechexpo in Stuttgart from 7–10 November 2017 that allow fast, reliable, and automated characterization of materials and detection of defects (Hall 5, Booth 5306).
When quality testing uses time-consuming destructive test methods, it can result in enormous costs due to damaging or destroying the products. And given that...
Using a new cooling technique MPQ scientists succeed at observing collisions in a dense beam of cold and slow dipolar molecules.
How do chemical reactions proceed at extremely low temperatures? The answer requires the investigation of molecular samples that are cold, dense, and slow at...
Scientists from the Max Planck Institute of Quantum Optics, using high precision laser spectroscopy of atomic hydrogen, confirm the surprisingly small value of the proton radius determined from muonic hydrogen.
It was one of the breakthroughs of the year 2010: Laser spectroscopy of muonic hydrogen resulted in a value for the proton charge radius that was significantly...
17.10.2017 | Event News
10.10.2017 | Event News
10.10.2017 | Event News
17.10.2017 | Life Sciences
17.10.2017 | Life Sciences
17.10.2017 | Earth Sciences