Without the Shockley equation, the computers of today would not be possible.
Developed in 1949 by William Shockley, the inventor of the transistor, the Shockley equation describes the relationship between electric current and voltage in inorganic semiconductors such as silicon.
The new equation describes the relationship of current to voltage at the junctions of organic semiconductors---carbon-rich compounds that don't necessarily come from a biological source, but resemble them. Organic semiconductors present special challenges for researchers because they are more disordered than their inorganic counterparts. But they could enable advanced solar cells, thin and intense OLED (organic light-emitting diode) displays, and high-efficiency lighting.
"The field of organic semiconductor research is still in its infancy. We're not making complicated circuits with them yet, but in order to do that someday, we need to know the precise relationship of current and voltage. Our new equation gives us fundamental insights into how charge moves in this class of materials. From my perspective, it's a very significant advance," said Steve Forrest, the William Gould Dow Collegiate Professor of Electrical Engineering and U-M vice president for research.
Forrest and his doctoral students, Noel Giebink (now at Argonne National Laboratories) and Brian Lassiter, in the U-M Department of Electrical Engineering and Computer Science, contributed to this research. Two papers on the work are published in the current edition of Physical Review B.
About six years ago, researchers in Forrest's lab realized that they could use Shockley's equation to describe the current/voltage relationship in their organic solar cells to a degree.
"It fit nicely if you didn't look too hard," Forrest said.
Their findings were published, and from that time on, many physicists and engineers used the Shockley equation for organic semiconductors even though it didn't describe the physics perfectly. The new equation does.
Forrest says it will allow researchers to better describe and predict the properties of the different organic semiconductors they're working with. And in that way, they'll be able to more efficiently choose which material best suits the needs of the device they're working on.
"People have been investigating organic semiconductors for 70 or 80 years, but we're just entering the world of applications," Forrest said. "This work will help advance the field forward."
The papers are titled, "The Ideal Diode Equation for Organic Heterojunctions. I. Derivation and Application," and "The Ideal Diode Equation for Organic Heterojunctions. II. The Role of Polaron Pair Recombination."
Forrest is also a professor in the departments of Physics, and Materials Science and Engineering. Others contributing to this work are affiliated with Argonne National Laboratory's Center for Nanoscale Materials and Northwestern University.
This research is funded in party by the Department of Energy's Office of Basic Energy Sciences through the U-M Center for Solar and Thermal Energy Conversion, and the Argonne-Northwestern Solar Energy Research Center.
For more information: Steve Forrest: http://www.umich.edu/~ocm/Michigan Engineering:
Waste from paper and pulp industry supplies raw material for development of new redox flow batteries
12.10.2017 | Johannes Gutenberg-Universität Mainz
Low-cost battery from waste graphite
11.10.2017 | Empa - Eidgenössische Materialprüfungs- und Forschungsanstalt
University of Maryland researchers contribute to historic detection of gravitational waves and light created by event
On August 17, 2017, at 12:41:04 UTC, scientists made the first direct observation of a merger between two neutron stars--the dense, collapsed cores that remain...
Seven new papers describe the first-ever detection of light from a gravitational wave source. The event, caused by two neutron stars colliding and merging together, was dubbed GW170817 because it sent ripples through space-time that reached Earth on 2017 August 17. Around the world, hundreds of excited astronomers mobilized quickly and were able to observe the event using numerous telescopes, providing a wealth of new data.
Previous detections of gravitational waves have all involved the merger of two black holes, a feat that won the 2017 Nobel Prize in Physics earlier this month....
Material defects in end products can quickly result in failures in many areas of industry, and have a massive impact on the safe use of their products. This is why, in the field of quality assurance, intelligent, nondestructive sensor systems play a key role. They allow testing components and parts in a rapid and cost-efficient manner without destroying the actual product or changing its surface. Experts from the Fraunhofer IZFP in Saarbrücken will be presenting two exhibits at the Blechexpo in Stuttgart from 7–10 November 2017 that allow fast, reliable, and automated characterization of materials and detection of defects (Hall 5, Booth 5306).
When quality testing uses time-consuming destructive test methods, it can result in enormous costs due to damaging or destroying the products. And given that...
Using a new cooling technique MPQ scientists succeed at observing collisions in a dense beam of cold and slow dipolar molecules.
How do chemical reactions proceed at extremely low temperatures? The answer requires the investigation of molecular samples that are cold, dense, and slow at...
Scientists from the Max Planck Institute of Quantum Optics, using high precision laser spectroscopy of atomic hydrogen, confirm the surprisingly small value of the proton radius determined from muonic hydrogen.
It was one of the breakthroughs of the year 2010: Laser spectroscopy of muonic hydrogen resulted in a value for the proton charge radius that was significantly...
17.10.2017 | Event News
10.10.2017 | Event News
10.10.2017 | Event News
20.10.2017 | Information Technology
20.10.2017 | Materials Sciences
20.10.2017 | Interdisciplinary Research