"We're trying to mimic the process in nature that forms crude oil with marine organisms," said Phil Savage, an Arthur F. Thurnau professor and a professor of chemical engineering at the University of Michigan.
The findings will be presented Nov. 1 at the 2012 American Institute of Chemical Engineers Annual Meeting in Pittsburgh.
Savage's ocean-going organism of choice is the green marine micro-alga of the genus Nannochloropsis.
To make their one-minute biocrude, Savage and Julia Faeth, a doctoral student in Savage's lab, filled a steel pipe connector with 1.5 milliliters of wet algae, capped it and plunged it into 1,100-degree Fahrenheit sand. The small volume ensured that the algae was heated through, but with only a minute to warm up, the algae's temperature should have just grazed the 550-degree mark before the team pulled the reactor back out.
Previously, Savage and his team heated the algae for times ranging from 10 to 90 minutes. They saw their best results, with about half of the algae converted to biocrude, after treating it for 10 to 40 minutes at 570 degrees.
Why are the one-minute results so much better? Savage and Faeth won't be sure until they have done more experiments, but they have some ideas.
"My guess is that the reactions that produce biocrude are actually must faster than previously thought," Savage said.
Faeth suggests that the fast heating might boost the biocrude by keeping unwanted reactions at bay.
"For example, the biocrude might decompose into substances that dissolve in water, and the fast heating rates might discourage that reaction," Faeth said.
The team points out that shorter reaction times mean that the reactors don't have to be as large.
"By reducing the reactor volume, the cost of building a biocrude production plant also decreases," Faeth said, though both she and Savage cautioned that they couldn't say for sure whether the new method is faster and cheaper until the process is further developed.
Current commercial makers of algae-based fuel first dry the algae and then extract the natural oil. But at over $20 per gallon, this fuel is a long way from the gas pump.
"Companies know that that approach is not economical, so they are looking at approaches for using wet algae, as are we," Savage said.
One of the advantages of the wet method is that it doesn't just extract the existing fat from the algae—it also breaks down proteins and carbohydrates. The minute method did this so successfully that the oil contained about 90 percent of the energy in the original algae.
"That result is near the upper bound of what is possible," Savage said.
Before biocrude can be fed into the existing refinery system for petroleum, it needs pre-refining to get rid of the extra oxygen and nitrogen atoms that abound in living things. The Savage lab also is developing better methods for this leg of biofuel production, breaking the record with a biocrude that was 97 percent carbon and hydrogen earlier this year. A paper on this work is currently under review.
Once producing biofuel from algae is economical, researchers estimate that an area the size of New Mexico could provide enough oil to match current U.S. petroleum consumption. And, unlike corn produced for ethanol—which already accounts for half that area—the algae won't need to occupy good farmland, thriving in brackish ponds instead.
The research, "The Effects of Heating Rate and Reaction Time on Hydrothermal Liquefaction of Microalgae," was funded by the Emerging Frontiers in Research and Innovation program of the National Science Foundation. The university is pursuing patent protection for the intellectual property, and is seeking commercialization partners to help bring the technology to market.
Savage Lab: http://savageresearchlab.wordpress.com
EDITORS: Watch and link to a video about Savage's work on biofuels at http://www.youtube.com/watch?feature=player_embedded&v=dvGssEM4bLg#
Nicole Casal Moore | Newswise Science News
How protons move through a fuel cell
22.06.2017 | Empa - Eidgenössische Materialprüfungs- und Forschungsanstalt
Fraunhofer IZFP acquires lucrative EU project for increasing nuclear power plant safety
21.06.2017 | Fraunhofer-Institut für Zerstörungsfreie Prüfverfahren IZFP
An international team of scientists has proposed a new multi-disciplinary approach in which an array of new technologies will allow us to map biodiversity and the risks that wildlife is facing at the scale of whole landscapes. The findings are published in Nature Ecology and Evolution. This international research is led by the Kunming Institute of Zoology from China, University of East Anglia, University of Leicester and the Leibniz Institute for Zoo and Wildlife Research.
Using a combination of satellite and ground data, the team proposes that it is now possible to map biodiversity with an accuracy that has not been previously...
Heatwaves in the Arctic, longer periods of vegetation in Europe, severe floods in West Africa – starting in 2021, scientists want to explore the emissions of the greenhouse gas methane with the German-French satellite MERLIN. This is made possible by a new robust laser system of the Fraunhofer Institute for Laser Technology ILT in Aachen, which achieves unprecedented measurement accuracy.
Methane is primarily the result of the decomposition of organic matter. The gas has a 25 times greater warming potential than carbon dioxide, but is not as...
Hydrogen is regarded as the energy source of the future: It is produced with solar power and can be used to generate heat and electricity in fuel cells. Empa researchers have now succeeded in decoding the movement of hydrogen ions in crystals – a key step towards more efficient energy conversion in the hydrogen industry of tomorrow.
As charge carriers, electrons and ions play the leading role in electrochemical energy storage devices and converters such as batteries and fuel cells. Proton...
Scientists from the Excellence Cluster Universe at the Ludwig-Maximilians-Universität Munich have establised "Cosmowebportal", a unique data centre for cosmological simulations located at the Leibniz Supercomputing Centre (LRZ) of the Bavarian Academy of Sciences. The complete results of a series of large hydrodynamical cosmological simulations are available, with data volumes typically exceeding several hundred terabytes. Scientists worldwide can interactively explore these complex simulations via a web interface and directly access the results.
With current telescopes, scientists can observe our Universe’s galaxies and galaxy clusters and their distribution along an invisible cosmic web. From the...
Temperature measurements possible even on the smallest scale / Molecular ruby for use in material sciences, biology, and medicine
Chemists at Johannes Gutenberg University Mainz (JGU) in cooperation with researchers of the German Federal Institute for Materials Research and Testing (BAM)...
19.06.2017 | Event News
13.06.2017 | Event News
13.06.2017 | Event News
23.06.2017 | Physics and Astronomy
23.06.2017 | Physics and Astronomy
23.06.2017 | Information Technology