Braun's group developed a three-dimensional nanostructure for battery cathodes that allows for dramatically faster charging and discharging without sacrificing energy storage capacity. The researchers' findings will be published in the March 20 advance online edition of the journal Nature Nanotechnology.
Aside from quick-charge consumer electronics, batteries that can store a lot of energy, release it fast and recharge quickly are desirable for electric vehicles, medical devices, lasers and military applications.
"This system that we have gives you capacitor-like power with battery-like energy," said Braun, a professor of materials science and engineering. "Most capacitors store very little energy. They can release it very fast, but they can't hold much. Most batteries store a reasonably large amount of energy, but they can't provide or receive energy rapidly. This does both."
The performance of typical lithium-ion (Li-ion) or nickel metal hydride (NiMH) rechargeable batteries degrades significantly when they are rapidly charged or discharged. Making the active material in the battery a thin film allows for very fast charging and discharging, but reduces the capacity to nearly zero because the active material lacks volume to store energy.
Braun's group wraps a thin film into three-dimensional structure, achieving both high active volume (high capacity) and large current. They have demonstrated battery electrodes that can charge or discharge in a few seconds, 10 to 100 times faster than equivalent bulk electrodes, yet can perform normally in existing devices.
This kind of performance could lead to phones that charge in seconds or laptops that charge in minutes, as well as high-power lasers and defibrillators that don't need time to power up before or between pulses.
Braun is particularly optimistic for the batteries' potential in electric vehicles. Battery life and recharging time are major limitations of electric vehicles. Long-distance road trips can be their own form of start-and-stop driving if the battery only lasts for 100 miles and then requires an hour to recharge.
"If you had the ability to charge rapidly, instead of taking hours to charge the vehicle you could potentially have vehicles that would charge in similar times as needed to refuel a car with gasoline," Braun said. "If you had five-minute charge capability, you would think of this the same way you do an internal combustion engine. You would just pull up to a charging station and fill up."
All of the processes the group used are also used at large scales in industry so the technique could be scaled up for manufacturing.
They key to the group's novel 3-D structure is self-assembly. They begin by coating a surface with tiny spheres, packing them tightly together to form a lattice. Trying to create such a uniform lattice by other means is time-consuming and impractical, but the inexpensive spheres settle into place automatically.
Then the researchers fill the space between and around the spheres with metal. The spheres are melted or dissolved, leaving a porous 3-D metal scaffolding, like a sponge. Next, a process called electropolishing uniformly etches away the surface of the scaffold to enlarge the pores and make an open framework. Finally, the researchers coat the frame with a thin film of the active material.
The result is a bicontinuous electrode structure with small interconnects, so the lithium ions can move rapidly; a thin-film active material, so the diffusion kinetics are rapid; and a metal framework with good electrical conductivity.
The group demonstrated both NiMH and Li-ion batteries, but the structure is general, so any battery material that can be deposited on the metal frame could be used.
"We like that it's very universal, so if someone comes up with a better battery chemistry, this concept applies," said Braun, who is also affiliated with the Materials Research Laboratory and the Beckman Institute for Advanced Science and Technology at Illinois. "This is not linked to one very specific kind of battery, but rather it's a new paradigm in thinking about a battery in three dimensions for enhancing properties."
The U.S. Army Research Laboratory and the Department of Energy supported this work. Visiting scholar Huigang Zhang and former graduate student Xindi Yu were co-authors of the paper.
Editor's note: To reach Paul V. Braun, call 217-244-7293; e-mail email@example.com
Liz Ahlberg | EurekAlert!
Further reports about: > battery > 3-D image > Illinois River Watershed > Laboratory > Li-Ion > Lithium-Ion > Materials Science > NIMH > batteries > battery-like energy > capacitor-like power > defibrillators > electric vehicle > electric vehicles > high-power lasers > medical devices > military applications > quick-charge consumer electronics
Supersonic waves may help electronics beat the heat
18.05.2018 | DOE/Oak Ridge National Laboratory
Researchers control the properties of graphene transistors using pressure
17.05.2018 | Columbia University
So-called quantum many-body scars allow quantum systems to stay out of equilibrium much longer, explaining experiment | Study published in Nature Physics
Recently, researchers from Harvard and MIT succeeded in trapping a record 53 atoms and individually controlling their quantum state, realizing what is called a...
The historic first detection of gravitational waves from colliding black holes far outside our galaxy opened a new window to understanding the universe. A...
A team led by Austrian experimental physicist Rainer Blatt has succeeded in characterizing the quantum entanglement of two spatially separated atoms by observing their light emission. This fundamental demonstration could lead to the development of highly sensitive optical gradiometers for the precise measurement of the gravitational field or the earth's magnetic field.
The age of quantum technology has long been heralded. Decades of research into the quantum world have led to the development of methods that make it possible...
Cardiovascular tissue engineering aims to treat heart disease with prostheses that grow and regenerate. Now, researchers from the University of Zurich, the Technical University Eindhoven and the Charité Berlin have successfully implanted regenerative heart valves, designed with the aid of computer simulations, into sheep for the first time.
Producing living tissue or organs based on human cells is one of the main research fields in regenerative medicine. Tissue engineering, which involves growing...
A team of scientists of the Max Planck Institute for the Structure and Dynamics of Matter (MPSD) at the Center for Free-Electron Laser Science in Hamburg investigated optically-induced superconductivity in the alkali-doped fulleride K3C60under high external pressures. This study allowed, on one hand, to uniquely assess the nature of the transient state as a superconducting phase. In addition, it unveiled the possibility to induce superconductivity in K3C60 at temperatures far above the -170 degrees Celsius hypothesized previously, and rather all the way to room temperature. The paper by Cantaluppi et al has been published in Nature Physics.
Unlike ordinary metals, superconductors have the unique capability of transporting electrical currents without any loss. Nowadays, their technological...
02.05.2018 | Event News
13.04.2018 | Event News
12.04.2018 | Event News
18.05.2018 | Power and Electrical Engineering
18.05.2018 | Information Technology
18.05.2018 | Information Technology