Research carried out at UPV/EHU, DIPC and CNRS advances the understanding of electric contacts in future carbon-based nanoelectronics
Carbon-based nanostructures such as nanotubes, graphene sheets, and nanoribbons are unique building blocks showing versatile nanomechanical and nanoelectronic properties. These materials which are ordered in the nanoscale, that is, in the dimension of a millionth of millimetre, are promising candidates to envision applications in nanoscale devices, ranging from energy conversion to nano-electronic transistors.
A good connection between carbon-based materials and external metallic leads is of major importance in nanodevice performance, an aspect where an important step has been surmounted by researchers from UPV/EHU, DIPC and CNRS by studying contacts of carbon nanostructures with atoms of different chemical nature.
The chemical nature of contacting leads is of major importance as it affects the electronic properties and the geometry of the contact. The impact of these two aspects on the transport properties are entangled and this group studied these two parameters for contacts shrunk to the limit of individual atoms as for large structures it is challenging to address them separately.
In close collaboration, the researchers used a prototype carbon-based molecule made of 60 carbon atoms arranged in a sphere that can be viewed as a graphene sheet rolled into a tiny ball. The experimental team in Strasbourg led by Guillaume Schull, attached this molecule to the apex of an extremely tiny metal needle of a scanning tunnelling microscope.
The molecule-terminated needle was then cautiously approached to individual metallic atoms of different chemical nature up to the formation of a robust connection. By simultaneously measuring the electrical current passing through these connections, they could deduce which of the individual metallic atom is injecting charges to the carbon-made molecule with the greatest efficiency.
Large-scale computer simulations performed by the theoretical team in San Sebastian led by Thomas Frederiksen, Ikerbasque Research Professor at the DIPC, revealed a fascinating and unexpected aspect of these extremely tiny connections: their electric and mechanical properties are in fact representative for much larger carbon-based materials.
These results, published in the prestigious journal Nature Communications, set the bases to find extremely efficient contacts in the near future. The study paves the way to probe a great number of different metallic species (as well as tiny alloys made of two or three different metallic atoms), allowing for a systematic classification of their abilities to inject electrons into emerging carbon-based electronic devices.
Full research publication (open access)
Chemical control of electrical contact to sp2 carbon atoms
T. Frederiksen, G. Foti, F. Scheurer, V. Speisser, & G. Schul. Nature Communications (2014).
Thomas Frederiksen | Eurek Alert!
Fraunhofer ISE Supports Market Development of Solar Thermal Power Plants in the MENA Region
21.02.2018 | Fraunhofer-Institut für Solare Energiesysteme ISE
New tech for commercial Lithium-ion batteries finds they can be charged 5 times fast
20.02.2018 | University of Warwick
A newly developed laser technology has enabled physicists in the Laboratory for Attosecond Physics (jointly run by LMU Munich and the Max Planck Institute of Quantum Optics) to generate attosecond bursts of high-energy photons of unprecedented intensity. This has made it possible to observe the interaction of multiple photons in a single such pulse with electrons in the inner orbital shell of an atom.
In order to observe the ultrafast electron motion in the inner shells of atoms with short light pulses, the pulses must not only be ultrashort, but very...
A group of researchers led by Andrea Cavalleri at the Max Planck Institute for Structure and Dynamics of Matter (MPSD) in Hamburg has demonstrated a new method enabling precise measurements of the interatomic forces that hold crystalline solids together. The paper Probing the Interatomic Potential of Solids by Strong-Field Nonlinear Phononics, published online in Nature, explains how a terahertz-frequency laser pulse can drive very large deformations of the crystal.
By measuring the highly unusual atomic trajectories under extreme electromagnetic transients, the MPSD group could reconstruct how rigid the atomic bonds are...
Quantum computers may one day solve algorithmic problems which even the biggest supercomputers today can’t manage. But how do you test a quantum computer to...
For the first time, a team of researchers at the Max-Planck Institute (MPI) for Polymer Research in Mainz, Germany, has succeeded in making an integrated circuit (IC) from just a monolayer of a semiconducting polymer via a bottom-up, self-assembly approach.
In the self-assembly process, the semiconducting polymer arranges itself into an ordered monolayer in a transistor. The transistors are binary switches used...
Breakthrough provides a new concept of the design of molecular motors, sensors and electricity generators at nanoscale
Researchers from the Institute of Organic Chemistry and Biochemistry of the CAS (IOCB Prague), Institute of Physics of the CAS (IP CAS) and Palacký University...
15.02.2018 | Event News
13.02.2018 | Event News
12.02.2018 | Event News
23.02.2018 | Physics and Astronomy
23.02.2018 | Health and Medicine
23.02.2018 | Physics and Astronomy