The chief culprit is fossil fuel combustion, which releases nitric oxides into the air that combine with other elements to form smog and acid rain. But it has been difficult to know precisely the extent to which such emissions have altered the nitrogen balance.
Researchers from Brown University and the University of Washington have found a new way to make the link. The scientists show that comparing nitrogen isotopes in their deposited form — nitrates — can reveal the sources of atmospheric nitric oxide. In a paper published this week in Science, the group traces the source of nitrates to nitric oxides released through fossil fuel burning that parallels the beginning of the Industrial Revolution. The group also reveals that the greatest change in nitrogen isotope ratios occurred between 1950 and 1980, following a rapid increase in fossil fuel emissions.
"What we find is there has been this significant change to the nitrogen cycle over the past 300 years," said Meredith Hastings, assistant professor of geological sciences at Brown and the paper's lead author. "So we've added this new source — and not just a little bit of it, but a lot of it."
To make the link, Hastings, with Julia Jarvis and Eric Steig from the Department of Earth and Space Sciences at the University of Washington, examined at high resolution for the first time two isotopes of nitrogen found in nitrates in a Greenland ice core. The core, 100 meters long and taken at the peak of the Greenland ice cap in June 2006, contains a record of nitrates from about 1718 to 2006, according to the group.
Tests showed the ratio of the nitrogen-15 isotope to the more common nitrogen-14 isotope had changed from pre-industrial times to the present.
"The only way I can explain the trend over time," Hastings said, "are the nitric oxide sources, because we've introduced this whole new source — and that's fossil fuels burning."
"For example in Narragansett Bay, we could distinguish between nitrogen caused by sewage overflows or vehicular pollution, power plants, fertilizers, or other sources and know how to attack the problem," Hastings said.
Even more, the researchers want to quantify changes in the natural sources of nitric oxides and see whether climate change is influencing those processes.
The task is complicated, however, because nitrogen, when cycling through the atmosphere or deposited on land or in water, is subject to influences that can alter the isotopic ratios, thus masking the source. So, the scientists will need to tease out the extent of those alterations to trace the isotopic signatures of nitric oxide sources accurately.
The research was funded by the National Science Foundation's Office of Polar Programs and the Joint Institute for the Study of the Atmosphere and the Ocean (JISAO).
Richard Lewis | EurekAlert!
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