Glass has many applications that call for different properties, such as resistance to thermal shock or to chemically harsh environments. Glassmakers commonly use additives such as boron oxide to tweak these properties by changing the atomic structure of glass. Now researchers at the University of California, Davis, have for the first time captured atoms in borosilicate glass flipping from one structure to another as it is placed under high pressure.
Glass has many applications that call for different properties, such as resistance to thermal shock or to chemically harsh environments. Glassmakers commonly use additives such as boron oxide to tweak these properties by changing the atomic structure of glass. Now researchers at UC Davis have for the first time captured atoms in borosilicate glass flipping from a flat triangular configuration with three oxygen atoms around one boron to a tetrahedron, via a pyramidal intermediate.
Credit: Sabyasachi Sen, UC Davis
The findings may have implications for understanding how glasses and similar "amorphous" materials respond at the atomic scale under stress, said Sabyasachi Sen, professor of materials science at UC Davis. Sen is senior author on a paper describing the work published Aug. 29 in the journal Science.
Boron oxide is often added to glass to control a range of properties, including chemical durability, flow resistance, optical transparency and thermal expansion. Material scientists know that the structure around the boron atoms in borosilicate glass changes with pressure and temperature, switching from a flat triangular configuration with three oxygen atoms surrounding one boron atom to a four-sided tetrahedron, with four oxygen atoms surrounding one boron.
Until know, material scientists have only been able to study these structures in one state or the other, but not in transition. Sen and graduate student Trenton Edwards developed a probe that enabled them to make nuclear magnetic resonance (NMR) measurements of the environment of boron atoms in glass under pressures up to 2.5 Gigapascal.
They found that under pressure, the flat triangles of boron and three oxygen atoms first deform into a pyramid shape, with the boron atom pushed up. That may bring it close to another oxygen atom, and let the structure turn into a tetrahedron, with four oxygen atoms surrounding one boron.
Intriguingly, although glass is structurally isotropic and the stress on the glass is the same in all directions, the boron atoms respond by moving in one direction in relation to the rest of the structure.
"This is an unexpected finding that may have far-reaching implications for understanding a wide range of stress-induced phenomena in amorphous materials," Sen said.
The work was done in collaboration with Jeffrey Walton, project scientist with the UC Davis NMR Facility. It was funded by the U.S. National Science Foundation.
Andy Fell | Eurek Alert!
Physics, photosynthesis and solar cells
01.12.2016 | University of California - Riverside
New process produces hydrogen at much lower temperature
01.12.2016 | Waseda University
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
Broadband rotational spectroscopy unravels structural reshaping of isolated molecules in the gas phase to accommodate water
In two recent publications in the Journal of Chemical Physics and in the Journal of Physical Chemistry Letters, researchers around Melanie Schnell from the Max...
The efficiency of power electronic systems is not solely dependent on electrical efficiency but also on weight, for example, in mobile systems. When the weight of relevant components and devices in airplanes, for instance, is reduced, fuel savings can be achieved and correspondingly greenhouse gas emissions decreased. New materials and components based on gallium nitride (GaN) can help to reduce weight and increase the efficiency. With these new materials, power electronic switches can be operated at higher switching frequency, resulting in higher power density and lower material costs.
Researchers at the Fraunhofer Institute for Solar Energy Systems ISE together with partners have investigated how these materials can be used to make power...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
02.12.2016 | Medical Engineering
02.12.2016 | Agricultural and Forestry Science
02.12.2016 | Physics and Astronomy