Materials that emit visible light after being exposed to sunlight are commonplace and can be found in everything from emergency signage to glow-in-the-dark stickers. But until now, scientists have had little success creating materials that emit light in the near-infrared range, a portion of the spectrum that only can be seen with the aid of night vision devices.
In a paper just published in the early online edition of the journal Nature Materials, however, University of Georgia scientists describe a new material that emits a long-lasting, near-infrared glow after a single minute of exposure to sunlight. Lead author Zhengwei Pan, associate professor of physics and engineering in the Franklin College of Arts and Sciences and the Faculty of Engineering, said the material has the potential to revolutionize medical diagnostics, give the military and law enforcement agencies a "secret" source of illumination and provide the foundation for highly efficient solar cells.
"When you bring the material anywhere outside of a building, one minute of exposure to light can create a 360-hour release of near-infrared light," Pan said. "It can be activated by indoor fluorescent lighting as well, and it has many possible applications."
The material can be fabricated into nanoparticles that bind to cancer cells, for example, and doctors could visualize the location of small metastases that otherwise might go undetected. For military and law enforcement use, the material can be fashioned into ceramic discs that serve as a source of illumination that only those wearing night vision goggles can see. Similarly, the material can be turned into a powder and mixed into a paint whose luminescence is only visible to a select few.
The starting point for Pan's material is the trivalent chromium ion, a well-known emitter of near-infrared light. When exposed to light, its electrons at ground state quickly move to a higher energy state. As the electrons return to the ground state, energy is released as near-infrared light. The period of light emission is generally short, typically on the order of a few milliseconds. The innovation in Pan's material, which uses matrix of zinc and gallogermanate to host the trivalent chromium ions, is that its chemical structure creates a labyrinth of "traps" that capture excitation energy and store it for an extended period. As the stored energy is thermally released back to the chromium ions at room temperature, the compound persistently emits near-infrared light over period of up to two weeks.
In a process that Pan likens to perfecting a recipe, he and postdoctoral researcher Feng Liu and doctoral student Yi-Ying Lu spent three years developing the material. Initial versions emitted light for minutes, but through modifications to the chemical ingredients and the preparation—just the right amounts of sintering temperature and time—they were able to increase the afterglow from minutes to days and, ultimately, weeks.
"Even now, we don't think we've found the best compound," Pan said. "We will continuously tune the parameters so that we may find a much better one."
The researchers spent an additional year testing the material—indoors and out, as well as on sunny days, cloudy days and rainy days—to prove its versatility. They placed it in freshwater, saltwater and even a corrosive bleach solution for three months and found no decrease in performance.
In addition to exploring biomedical applications, Pan's team aims to use it to collect, store and convert solar energy. "This material has an extraordinary ability to capture and store energy," Pan said, "so this means that it is a good candidate for making solar cells significantly more efficient."
The U.S. Office of Naval Research, the National Science Foundation, the American Chemical Society Petroleum Research Fund and the UGA Research Foundation supported the research.
Zhengwei Pan | EurekAlert!
Researchers shoot for success with simulations of laser pulse-material interactions
29.03.2017 | DOE/Oak Ridge National Laboratory
Nanomaterial makes laser light more applicable
28.03.2017 | Christian-Albrechts-Universität zu Kiel
The Institute of Semiconductor Technology and the Institute of Physical and Theoretical Chemistry, both members of the Laboratory for Emerging Nanometrology (LENA), at Technische Universität Braunschweig are partners in a new European research project entitled ChipScope, which aims to develop a completely new and extremely small optical microscope capable of observing the interior of living cells in real time. A consortium of 7 partners from 5 countries will tackle this issue with very ambitious objectives during a four-year research program.
To demonstrate the usefulness of this new scientific tool, at the end of the project the developed chip-sized microscope will be used to observe in real-time...
Astronomers from Bonn and Tautenburg in Thuringia (Germany) used the 100-m radio telescope at Effelsberg to observe several galaxy clusters. At the edges of these large accumulations of dark matter, stellar systems (galaxies), hot gas, and charged particles, they found magnetic fields that are exceptionally ordered over distances of many million light years. This makes them the most extended magnetic fields in the universe known so far.
The results will be published on March 22 in the journal „Astronomy & Astrophysics“.
Galaxy clusters are the largest gravitationally bound structures in the universe. With a typical extent of about 10 million light years, i.e. 100 times the...
Researchers at the Goethe University Frankfurt, together with partners from the University of Tübingen in Germany and Queen Mary University as well as Francis Crick Institute from London (UK) have developed a novel technology to decipher the secret ubiquitin code.
Ubiquitin is a small protein that can be linked to other cellular proteins, thereby controlling and modulating their functions. The attachment occurs in many...
In the eternal search for next generation high-efficiency solar cells and LEDs, scientists at Los Alamos National Laboratory and their partners are creating...
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are less stable. Now researchers at the Technical University of Munich (TUM) have, for the first time ever, produced a composite material combining silicon nanosheets and a polymer that is both UV-resistant and easy to process. This brings the scientists a significant step closer to industrial applications like flexible displays and photosensors.
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are...
20.03.2017 | Event News
14.03.2017 | Event News
07.03.2017 | Event News
29.03.2017 | Materials Sciences
29.03.2017 | Physics and Astronomy
29.03.2017 | Earth Sciences