Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Scientists discover novel way to 'heal' defects in materials

02.10.2012
In a paper just published in Nature Materials, a team of researchers that includes William T.M. Irvine, assistant professor in physics at the University of Chicago, has succeeded in creating a defect in the structure of a single-layer crystal by simply inserting an extra particle, and then watching as the crystal “heals” itself. The trick to this self-healing property is that the crystal, an array of microscopic particles, must be curved.
This effect, which carries important implications for improving the conductivity of electronics and other realms of materials science, was predicted six years ago by physicist Mark Bowick of Syracuse University, along with David Nelson, Homin Shin and Alex Travesset, in research supported by the National Science Foundation. NSF also funded the new study.

In order to prove their prediction experimentally, Bowick sought out Paul M. Chaikin of the Center for Soft Matter Research at New York University. Chaikin enlisted the help of Irvine while he was a postdoctoral scientist working in Chaikin’s laboratory.

All three researchers specialize in the branch of materials science called “soft matter,” which studies a wide range of semi-solid substances such as gels, foams and liquid crystals.

Of soft matter and salad dressing

Bowick described the soft matter microemulsions he works with as being similar to a mayonnaise-based ranch dressing.

“Mayonnaise is made from a mixture of olive oil and vinegar (which is essentially water),” he explained. “You have to beat the ingredients for a long time to disperse tiny droplets of the vinegar in the oil to make an emulsion.” But keeping so many droplets mixed evenly throughout the oil requires the presence of a surfactant, a stabilizer that is equally happy in both the oil and the water.

“In ranch dressing, the surfactant used is ground-up mustard seed particles, which arrange themselves at the interface between the water and the oil,” Bowick said. “The mustard seed particles collect on the surface of the water droplets.”

To study curved crystals, the researchers emulated ranch dressing by adding microscopic acrylic glass particles to an emulsion of glycerol droplets, mixed in a base of oil.

Like the mustard seed, the glass particles naturally collect on the surface of individual glycerol droplets. Depending on the experiment, somewhere between 100 and 10,000 particles coat each droplet.

The particles’ positive electric charges repel each other, causing them to arrange themselves naturally in a honeycomb pattern, with each particle equally distant from six others.

Scarred crystals

The regular six-sided pattern doesn’t fit perfectly around the spherical droplet any more than gift-wrapping a soccer ball results in a perfectly flat paper covering. Just as the paper wrinkles when molding it to the surface of the ball, the curved crystal pattern generates 12 defects, or scars, evenly spaced around the sphere.

The number and location of these scars is a fundamental structural property prescribed by the geometry of the sphere. A similar pattern can be seen on the leather cover of the soccer ball, which requires 12 five-sided pentagons (defects) evenly spaced within an overall six-sided pattern.

Bowick was a member of the team that originally discovered this 12-scar property of curved crystals in 2003. After that, he wondered what would happen if they added an extra particle, called an interstitial, right in the middle of the crystal.

“Even though the particles have self-organized into a crystal pattern, they are still free to wiggle about within that structure,” Bowick said. “You’d expect that an additional particle would just push the other ones apart slightly and settle in place, as it would on a flat surface.”

The result would be a defective pattern containing an area of seven- and five-sided shapes, rather than the regular six-sided hexagons. But what Bowick and colleagues predicted using computer models is that on a curved surface, an extra particle added halfway between two scars would create a defect in the pattern that splits into two parts.

They calculated that the strain on the crystalline structure caused by these two defects would “flow” away from site, like ripples on a pond, as the particles readjust their distances from one another. Eventually the defects would migrate to opposite scars, where they would disappear.

Amazingly, the scientists predicted that the original particle’s mass would remain close to where it was placed, and large areas of the hexagonal pattern would have rotated slightly ­— about 30 degrees. But the original defect would be gone.

To prove this remarkable result experimentally, however, required a special instrument.

Making it work

“William Irvine had already begun his beautiful experiments in my lab on colloidal crystals on curved surfaces,” recalled NYU’s Chaikin. “The present study came from a conversation that Mark Bowick and I had on a plane coming back from a meeting several years ago. Mark’s experiment was a natural extension of William’s work.”

“For this project, we had to figure out how to add a particle to the curved crystal, while imaging the particles as they shift around in three-dimensional space,” explained Irvine, who is now at UChicago’s James Franck Institute. “This makes the experiment considerably more complicated.”

Irvine planned to use optical tweezers to grab a microscopic particle from the surrounding emulsion and place it on the surface of a droplet using radiation pressure from a focused laser beam.

“In most experiments, you come in with the laser ‘tweezers’ using the same lens as you use for imaging the particle, and that’s great, because you want to focus the beam on the same plane where you’re looking,” Irvine said.

But for this experiment, the laser tweezers and the microscope had to be separated.

“A confocal microscope selects a very thin slice of the object to be imaged, so that one slice is in focus and the rest of the image (before and after) is out of focus, like a photo of a person with their face in focus and the background blurred,” he explained. “In order to create a full three-dimensional image, you move the objective up and down and bring the different slices into focus one at a time.”

But moving the lens also moves the laser beam holding the particle.

“In order to hold onto a particle and watch what happens as you gradually bring it to the surface of the droplet, you have to essentially build a second microscope on top of the first one,” Irvine said. “Technically, that’s not trivial — you have to get a lot of things to work at the same time.”

But once Irvine had designed and built the instrument, the team tested Bowick’s predictions and actually created video images showing the defects moving across the crystal surface and disappearing into the scars.

Self-healing graphene

“The study of crystals on curved surfaces is interesting and important for systems that range from geodesic domes to viruses to Buckyballs,” said Chaikin, referring to symmetric molecules of carbon. “The defect structure and the ‘healing’ of defects are particularly important in the conductivity, heat and mechanical properties of carbon nanotubes, graphene and similar materials.”

Graphene, a two-dimensional sheet of carbon molecules, is a very strong material and a good conductor of electricity.

“There are always going to be defects that will decrease the conductivity of graphene,” said Bowick. “Ultimately, for electronic devices, you want graphene with high conductivity and as pure as possible.”

And that’s where the researchers’ discovery could prove an ideal solution. “You might be able to simply flex a piece of graphene, remove the defects, and improve the conductivity,” Bowick said.

— Adapted from National Science Foundation release
Citation: “Fractionalization of interstitials in curved colloidal crystals,” by William T.M. Irvine, Mark J. Bowick and Paul M. Chaikin, Nature Materials, published online Sept. 30, 2012.

Funding: National Science Foundation grants DMR-0808812, DMR-0820341, DMR-1105417 and DMR-0820054

Steve Koppes | EurekAlert!
Further information:
http://www.uchicago.edu

More articles from Materials Sciences:

nachricht New biomaterial could replace plastic laminates, greatly reduce pollution
21.09.2017 | Penn State

nachricht Stopping problem ice -- by cracking it
21.09.2017 | Norwegian University of Science and Technology

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: LaserTAB: More efficient and precise contacts thanks to human-robot collaboration

At the productronica trade fair in Munich this November, the Fraunhofer Institute for Laser Technology ILT will be presenting Laser-Based Tape-Automated Bonding, LaserTAB for short. The experts from Aachen will be demonstrating how new battery cells and power electronics can be micro-welded more efficiently and precisely than ever before thanks to new optics and robot support.

Fraunhofer ILT from Aachen relies on a clever combination of robotics and a laser scanner with new optics as well as process monitoring, which it has developed...

Im Focus: The pyrenoid is a carbon-fixing liquid droplet

Plants and algae use the enzyme Rubisco to fix carbon dioxide, removing it from the atmosphere and converting it into biomass. Algae have figured out a way to increase the efficiency of carbon fixation. They gather most of their Rubisco into a ball-shaped microcompartment called the pyrenoid, which they flood with a high local concentration of carbon dioxide. A team of scientists at Princeton University, the Carnegie Institution for Science, Stanford University and the Max Plank Institute of Biochemistry have unravelled the mysteries of how the pyrenoid is assembled. These insights can help to engineer crops that remove more carbon dioxide from the atmosphere while producing more food.

A warming planet

Im Focus: Highly precise wiring in the Cerebral Cortex

Our brains house extremely complex neuronal circuits, whose detailed structures are still largely unknown. This is especially true for the so-called cerebral cortex of mammals, where among other things vision, thoughts or spatial orientation are being computed. Here the rules by which nerve cells are connected to each other are only partly understood. A team of scientists around Moritz Helmstaedter at the Frankfiurt Max Planck Institute for Brain Research and Helene Schmidt (Humboldt University in Berlin) have now discovered a surprisingly precise nerve cell connectivity pattern in the part of the cerebral cortex that is responsible for orienting the individual animal or human in space.

The researchers report online in Nature (Schmidt et al., 2017. Axonal synapse sorting in medial entorhinal cortex, DOI: 10.1038/nature24005) that synapses in...

Im Focus: Tiny lasers from a gallery of whispers

New technique promises tunable laser devices

Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...

Im Focus: Ultrafast snapshots of relaxing electrons in solids

Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!

When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

“Lasers in Composites Symposium” in Aachen – from Science to Application

19.09.2017 | Event News

I-ESA 2018 – Call for Papers

12.09.2017 | Event News

EMBO at Basel Life, a new conference on current and emerging life science research

06.09.2017 | Event News

 
Latest News

Fraunhofer ISE Pushes World Record for Multicrystalline Silicon Solar Cells to 22.3 Percent

25.09.2017 | Power and Electrical Engineering

Usher syndrome: Gene therapy restores hearing and balance

25.09.2017 | Health and Medicine

An international team of physicists a coherent amplification effect in laser excited dielectrics

25.09.2017 | Physics and Astronomy

VideoLinks
B2B-VideoLinks
More VideoLinks >>>