Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:


Researchers Find Simple, Cheap Way to Increase Solar Cell Efficiency

Researchers from North Carolina State University and the Chinese Academy of Sciences have found an easy way to modify the molecular structure of a polymer commonly used in solar cells. Their modification can increase solar cell efficiency by more than 30 percent.

Polymer-based solar cells have two domains, consisting of an electron acceptor and an electron donor material. Excitons are the energy particles created by solar cells when light is absorbed. In order to be harnessed effectively as an energy source, excitons must be able to travel quickly to the interface of the donor and acceptor domains and retain as much of the light’s energy as possible.

One way to increase solar cell efficiency is to adjust the difference between the highest occupied molecular orbit (HOMO) of the acceptor and lowest unoccupied molecular orbit (LUMO) levels of the polymer so that the exciton can be harvested with minimal loss. One of the most common ways to accomplish this is by adding a fluorine atom to the polymer’s molecular backbone, a difficult, multi-step process that can increase the solar cell’s performance, but has considerable material fabrication costs.

A team of chemists led by Jianhui Hou from the Chinese Academy of Sciences created a polymer known as PBT-OP from two commercially available monomers and one easily synthesized monomer. Wei Ma, a post-doctoral physics researcher from NC State and corresponding author on a paper describing the research, conducted the X-ray analysis of the polymer’s structure and the donor:acceptor morphology.

PBT-OP was not only easier to make than other commonly used polymers, but a simple manipulation of its chemical structure gave it a lower HOMO level than had been seen in other polymers with the same molecular backbone. PBT-OP showed an open circuit voltage (the voltage available from a solar cell) value of 0.78 volts, a 36 percent increase over the ~ 0.6 volt average from similar polymers.

According to NC State physicist and co-author Harald Ade, the team’s approach has several advantages. “The possible drawback in changing the molecular structure of these materials is that you may enhance one aspect of the solar cell but inadvertently create unintended consequences in devices that defeat the initial intent,” he says. “In this case, we have found a chemically easy way to change the electronic structure and enhance device efficiency by capturing a lager fraction of the light’s energy, without changing the material’s ability to absorb, create and transport energy.”

The researchers’ findings appear in Advanced Materials. The research was funded by the U.S. Department of Energy, Office of Science, Basic Energy Science and the Chinese Ministry of Science and Technology. Dr. Maojie Zhang synthesized the polymers; Xia Guo,Shaoqing Zhang and Lijun Huo from the Chinese Academy of Sciences also contributed to the work.

Tracey Peake | EurekAlert!
Further information:

More articles from Materials Sciences:

nachricht From ancient fossils to future cars
21.10.2016 | University of California - Riverside

nachricht Study explains strength gap between graphene, carbon fiber
20.10.2016 | Rice University

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: New 3-D wiring technique brings scalable quantum computers closer to reality

Researchers from the Institute for Quantum Computing (IQC) at the University of Waterloo led the development of a new extensible wiring technique capable of controlling superconducting quantum bits, representing a significant step towards to the realization of a scalable quantum computer.

"The quantum socket is a wiring method that uses three-dimensional wires based on spring-loaded pins to address individual qubits," said Jeremy Béjanin, a PhD...

Im Focus: Scientists develop a semiconductor nanocomposite material that moves in response to light

In a paper in Scientific Reports, a research team at Worcester Polytechnic Institute describes a novel light-activated phenomenon that could become the basis for applications as diverse as microscopic robotic grippers and more efficient solar cells.

A research team at Worcester Polytechnic Institute (WPI) has developed a revolutionary, light-activated semiconductor nanocomposite material that can be used...

Im Focus: Diamonds aren't forever: Sandia, Harvard team create first quantum computer bridge

By forcefully embedding two silicon atoms in a diamond matrix, Sandia researchers have demonstrated for the first time on a single chip all the components needed to create a quantum bridge to link quantum computers together.

"People have already built small quantum computers," says Sandia researcher Ryan Camacho. "Maybe the first useful one won't be a single giant quantum computer...

Im Focus: New Products - Highlights of COMPAMED 2016

COMPAMED has become the leading international marketplace for suppliers of medical manufacturing. The trade fair, which takes place every November and is co-located to MEDICA in Dusseldorf, has been steadily growing over the past years and shows that medical technology remains a rapidly growing market.

In 2016, the joint pavilion by the IVAM Microtechnology Network, the Product Market “High-tech for Medical Devices”, will be located in Hall 8a again and will...

Im Focus: Ultra-thin ferroelectric material for next-generation electronics

'Ferroelectric' materials can switch between different states of electrical polarization in response to an external electric field. This flexibility means they show promise for many applications, for example in electronic devices and computer memory. Current ferroelectric materials are highly valued for their thermal and chemical stability and rapid electro-mechanical responses, but creating a material that is scalable down to the tiny sizes needed for technologies like silicon-based semiconductors (Si-based CMOS) has proven challenging.

Now, Hiroshi Funakubo and co-workers at the Tokyo Institute of Technology, in collaboration with researchers across Japan, have conducted experiments to...

All Focus news of the innovation-report >>>



Event News

#IC2S2: When Social Science meets Computer Science - GESIS will host the IC2S2 conference 2017

14.10.2016 | Event News

Agricultural Trade Developments and Potentials in Central Asia and the South Caucasus

14.10.2016 | Event News

World Health Summit – Day Three: A Call to Action

12.10.2016 | Event News

Latest News

Resolving the mystery of preeclampsia

21.10.2016 | Health and Medicine

Stanford researchers create new special-purpose computer that may someday save us billions

21.10.2016 | Information Technology

From ancient fossils to future cars

21.10.2016 | Materials Sciences

More VideoLinks >>>