Using building blocks that make up ordinary plastics, but putting them together in a whole new way, University of Michigan researchers have created a class of lightweight, rigid polymers they predict will be useful for storing hydrogen fuel. The work is described in today’s (Nov. 17) issue of the journal Science.
The trick to making the new materials, called covalent organic frameworks (COFs), was coaxing them to assume predictable crystal structures---something that never had been done with rigid plastics.
"Normally, rigid plastics are synthesized by rapid reactions that randomly cross-link polymers," said postdoctoral fellow Adrien Côté, who is first author on the Science paper. "Just as in anything you might do, if you do it really fast, it can get disorganized." For that reason, the exact internal structures of such materials are poorly understood, making it difficult to predict their properties. But Côté and colleagues tweaked reaction conditions to slow down the process, allowing the materials to crystallize in an organized fashion instead of assembling helter skelter.
Nancy Ross-Flanigan | EurekAlert!
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A newly developed laser technology has enabled physicists in the Laboratory for Attosecond Physics (jointly run by LMU Munich and the Max Planck Institute of Quantum Optics) to generate attosecond bursts of high-energy photons of unprecedented intensity. This has made it possible to observe the interaction of multiple photons in a single such pulse with electrons in the inner orbital shell of an atom.
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A group of researchers led by Andrea Cavalleri at the Max Planck Institute for Structure and Dynamics of Matter (MPSD) in Hamburg has demonstrated a new method enabling precise measurements of the interatomic forces that hold crystalline solids together. The paper Probing the Interatomic Potential of Solids by Strong-Field Nonlinear Phononics, published online in Nature, explains how a terahertz-frequency laser pulse can drive very large deformations of the crystal.
By measuring the highly unusual atomic trajectories under extreme electromagnetic transients, the MPSD group could reconstruct how rigid the atomic bonds are...
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For the first time, a team of researchers at the Max-Planck Institute (MPI) for Polymer Research in Mainz, Germany, has succeeded in making an integrated circuit (IC) from just a monolayer of a semiconducting polymer via a bottom-up, self-assembly approach.
In the self-assembly process, the semiconducting polymer arranges itself into an ordered monolayer in a transistor. The transistors are binary switches used...
Breakthrough provides a new concept of the design of molecular motors, sensors and electricity generators at nanoscale
Researchers from the Institute of Organic Chemistry and Biochemistry of the CAS (IOCB Prague), Institute of Physics of the CAS (IP CAS) and Palacký University...
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