Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Nanohelix structure provides new building block for nanoscale piezoelectric devices

09.09.2005


Scanning electron microscope image shows details of "nanohelix" structures produced from zinc oxide. Color has been added to this image.


Based on superlattice nanobelts

A previously-unknown zinc oxide nanostructure that resembles the helical configuration of DNA could provide engineers with a new building block for creating nanometer-scale sensors, transducers, resonators and other devices that rely on electromechanical coupling.

Based on a superlattice composed of alternating single-crystal "stripes" just a few nanometers wide, the "nanohelix" structure is part of a family of nanobelts – tiny ribbon-like structures with semiconducting and piezoelectric properties – that were first reported in 2001.



The nanohelices, which get their shape from twisting forces created by a small mismatch between the stripes, are produced using a vapor-solid growth process at high temperature. Information about the growth and analysis of the new structures will be reported in the September 9 issue of the journal Science.

The research was sponsored by the National Science Foundation, NASA Vehicle Systems Program, U.S. Department of Defense Research and Engineering (DDR&E), the Defense Advanced Research Projects Agency (DARPA), and the Chinese Academy of Sciences.

"This structure provides a new building block for nanodevices," said Zhong Lin Wang, a Regents professor in the School of Materials Science and Engineering at the Georgia Institute of Technology. "From them we can make resonators, place molecules on their surfaces to create frequency shifts – and because they are piezoelectric, make electromechanical couplings. This adds a new structure to the toolbox of nanomaterials."

With their superlattices composed of many near-parallel single-crystal stripes each about 3.5 nanometers wide and offset about five degrees, the nanohelices are very different from the nanosprings and nanorings of zinc oxide reported by the same research group in Science in 2004. Nanosprings are composed of a single crystal whose shape is governed by balancing the electrostatic forces created by opposite electrical charges on their edges with the elastic deformation energy of the entire structure.

The nanohelices reach lengths of up to 100 microns, with diameters from 300 to 700 nanometers and widths from 100 to 500 nanometers. The nanohelices exist in both right- and left-handed versions, with production split approximately 50-50 between the two directions.

"This is a brand new structure which shows a new growth model for nanomaterials," Wang said. "But from the properties point of view, these are like the earlier nanobelts in having semiconducting and piezoelectric properties which makes them good for electromechanical coupling."

However, unlike the earlier single-crystal nanosprings which are elastic, the nanohelices are rigid and retain their shape even when cut apart.

"When we first saw these structures, we were amazed by their perfection," said Wang, who is also director of Georgia Tech’s Center for Nanoscience and Nanotechnology. "Once you form a nanohelix, it is perfectly uniform."

The nanohelices are formed using a simple process similar to the one used for fabricating other nanobelts. However, changing the growth conditions leads to entirely different structures.

Zinc oxide (ZnO) powder is positioned inside an alumina tube in a horizontal high-temperature tube furnace. Under vacuum, the material is heated to approximately 1,000 degrees Celsius, at which point an argon carrier gas is introduced. Heating continues until the furnace reaches approximately 1,400 degrees. The nanohelix structures form on a polycrystalline aluminum oxide (Al2O3) substrate in the furnace.

"The key difference between growing nanohelices and the earlier types of nanobelt is that we control raising the temperature and when we introduce the carrier gas," explained Wang. "With the earlier structures, we introduced the carrier gas flow at the beginning. With these nanohelices, we only introduce the carrier gas when the temperature reaches a certain level. That allows formation to begin in a vacuum, which is the key to controlling the helix formation."

Heating the zinc oxide powder in a vacuum leads to formation of structures with polar surfaces. When the carrier gas is introduced, the growth changes to minimize the polar surfaces, creating the superlattice structure with mismatches at the crystalline interfaces. The nanohelices begin and end with conventional single-crystal nanobelt structures. "By the time the carrier gas is introduced, the crystal orientation is fixed, but the structures must continue to grow," Wang explained. "Introducing the carrier gas initiates a transition to the superlattice structure."

Formation of a nanohelix is initiated from a single-crystal stiff nanoribbon that is dominated by polar surfaces. An abrupt structural transformation of the single-crystal nanoribbon into stripes of the superlattice-structured nanobelt leads to the formation of a uniform nanohelix due to rigid structural alteration, Wang said. The superlattice nanobelt is a periodic, coherent, epitaxial and parallel assembly of two alternating stripes of zinc oxide crystals oriented with their c-axes perpendicular to one another. Growth of the nanohelix is terminated by transforming the partially polar-surface-dominated nanobelt into a non-polar-surface-dominated single-crystal nanobelt.

"The data suggest that reducing the polar surfaces could be the driving force behind the formation of the superlattice structure, and the rigid structural rotation and twist caused by the superlattice results in the initiation and formation of the nanohelix," Wang explained.

The first dozen batches of nanohelices produced a yield of only about 10 percent, but Wang believes that can be improved over time. Thus far, Wang’s research team has produced nearly 20 different zinc oxide nanostructures, including nanobelts, aligned nanowires, nanotubes, nanopropellor arrays, nanobows, nanosprings, nanorings, nanobowls and others. And there may yet be other structures discovered.

"You never know what other structures might be out there that could be added to this toolbox," he said. "From the richness of this configuration and the complete properties, this is a unique material that could become the new material for nanotechnology following carbon nanotubes."

A wideband semiconductor, zinc oxide also has interesting piezoelectric and optical properties, can produce ultraviolet laser emissions and shows electroluminescence at room temperature. Those properties make it potentially useful in many applications.

"You can use it for spintronics, biomedical applications and many things you can make with silicon technology," Wang said. "Zinc oxide is much cheaper and easier to work with than gallium nitride."

Other collaborators on this work included Pu Xian Gao, Yong Ding, Wenjie Mai, William Hughes, and Changshi Lao, all in Georgia Tech’s School of Materials Science and Engineering.

John Toon | EurekAlert!
Further information:
http://www.edi.gatech.edu

More articles from Materials Sciences:

nachricht Glass's off-kilter harmonies
18.01.2017 | University of Texas at Austin, Texas Advanced Computing Center

nachricht Explaining how 2-D materials break at the atomic level
18.01.2017 | Institute for Basic Science

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: How gut bacteria can make us ill

HZI researchers decipher infection mechanisms of Yersinia and immune responses of the host

Yersiniae cause severe intestinal infections. Studies using Yersinia pseudotuberculosis as a model organism aim to elucidate the infection mechanisms of these...

Im Focus: Interfacial Superconductivity: Magnetic and superconducting order revealed simultaneously

Researchers from the University of Hamburg in Germany, in collaboration with colleagues from the University of Aarhus in Denmark, have synthesized a new superconducting material by growing a few layers of an antiferromagnetic transition-metal chalcogenide on a bismuth-based topological insulator, both being non-superconducting materials.

While superconductivity and magnetism are generally believed to be mutually exclusive, surprisingly, in this new material, superconducting correlations...

Im Focus: Studying fundamental particles in materials

Laser-driving of semimetals allows creating novel quasiparticle states within condensed matter systems and switching between different states on ultrafast time scales

Studying properties of fundamental particles in condensed matter systems is a promising approach to quantum field theory. Quasiparticles offer the opportunity...

Im Focus: Designing Architecture with Solar Building Envelopes

Among the general public, solar thermal energy is currently associated with dark blue, rectangular collectors on building roofs. Technologies are needed for aesthetically high quality architecture which offer the architect more room for manoeuvre when it comes to low- and plus-energy buildings. With the “ArKol” project, researchers at Fraunhofer ISE together with partners are currently developing two façade collectors for solar thermal energy generation, which permit a high degree of design flexibility: a strip collector for opaque façade sections and a solar thermal blind for transparent sections. The current state of the two developments will be presented at the BAU 2017 trade fair.

As part of the “ArKol – development of architecturally highly integrated façade collectors with heat pipes” project, Fraunhofer ISE together with its partners...

Im Focus: How to inflate a hardened concrete shell with a weight of 80 t

At TU Wien, an alternative for resource intensive formwork for the construction of concrete domes was developed. It is now used in a test dome for the Austrian Federal Railways Infrastructure (ÖBB Infrastruktur).

Concrete shells are efficient structures, but not very resource efficient. The formwork for the construction of concrete domes alone requires a high amount of...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

12V, 48V, high-voltage – trends in E/E automotive architecture

10.01.2017 | Event News

2nd Conference on Non-Textual Information on 10 and 11 May 2017 in Hannover

09.01.2017 | Event News

Nothing will happen without batteries making it happen!

05.01.2017 | Event News

 
Latest News

A big nano boost for solar cells

18.01.2017 | Power and Electrical Engineering

Glass's off-kilter harmonies

18.01.2017 | Materials Sciences

Toward a 'smart' patch that automatically delivers insulin when needed

18.01.2017 | Life Sciences

VideoLinks
B2B-VideoLinks
More VideoLinks >>>