Researchers at the Beckman Institute for Advanced Science and Technology at the University of Illinois at Urbana-Champaign have created a 3D vascular system that allows for high-performance composite materials such as fiberglass to heal autonomously, and repeatedly.
Internal damage in fiber-reinforced composites, materials used in structures of modern airplanes and automobiles, is difficult to detect and nearly impossible to repair by conventional methods. A small, internal crack can quickly develop into irreversible damage from delamination, a process in which the layers separate. This remains one of the most significant factors limiting more widespread use of composite materials.
3D microvascular networks for self-healing composites: Researchers were able to achieve more effective self-healing with the herringbone vascular network (top) over a parallel design (bottom), evidenced by the increased mixing (orange-yellow) of individual healing agents (red and green) across a fracture surface.
However, fiber-composite materials can now heal autonomously through a new self-healing system, developed by researchers in the Beckman Institute’s Autonomous Materials Systems (AMS) Group at the University of Illinois at Urbana-Champaign, led by professors Nancy Sottos, Scott White, and Jeff Moore.
Sottos, White, Moore, and their team created 3D vascular networks—patterns of microchannels filled with healing chemistries—that thread through a fiber-reinforced composite. When damage occurs, the networks within the material break apart and allow the healing chemistries to mix and polymerize, autonomously healing the material, over multiple cycles. These results were detailed in a paper titled “Continuous self-healing life cycle in vascularized structural composites,” published in Advanced Materials.
“This is the first demonstration of repeated healing in a fiber-reinforced composite system,” said Scott White, aerospace engineering professor and co-corresponding author. “Self-healing has been done before in polymers with different techniques and networks, but they couldn’t be translated to fiber-reinforced composites. The missing link was the development of the vascularization technique.”
“The beauty of this self-healing approach is, we don't have to probe the structure and say, this is where the damage occurred and then repair it ourselves,” said Jason Patrick, a Ph.D. candidate in civil engineering and lead author.
The vasculature within the system integrates dual networks that are isolated from one other. Two liquid healing agents (an epoxy resin and hardener) are sequestered in two different microchannel networks.
“When a fracture occurs, this ruptures the separate networks of healing agents, automatically releasing them into the crack plane—akin to a bleeding cut,” Patrick said. “As they come into contact with one another in situ, or within the material, they polymerize to essentially form a structural glue in the damage zone. We tested this over multiple cycles and all cracks healed successfully at nearly 100 percent efficiency.”
Notably, the vascular networks within the structure are not straight lines. In order for the healing agents to combine effectively after being released within the crack, the vessels were overlapped to further promote mixing of the liquids, which both have a consistency similar to maple syrup.
Fiberglass and other composite materials are widely used in aerospace, automotive, naval, civil, and even sporting goods because of their high strength-to-weight ratio—they pack a lot of structural strength into a very lean package. However, because the woven laminates are stacked in layers, it is easier for the structure to separate between the layers, making this self-healing system a promising solution to a long-standing problem and greatly extending their lifetime and reliability.
“Additionally, creating the vasculature integrates seamlessly with typical manufacturing processes of polymer composites, making it a strong candidate for commercial use,” said Nancy Sottos, materials science and engineering professor and co-corresponding author.
Fiber-composite laminates are constructed by weaving and stacking multiple layers of reinforcing fabric, which are then co-infused with a binding polymer resin. Using that same process, the researchers stitched in a sort of fishing line, made from a bio-friendly polymer and coined “sacrificial fiber,” within the composite. Once the composite was fabricated, the entire system was heated to melt and evaporate the sacrificial fibers, leaving behind hollow microchannels, which became the vasculature for the self-healing system.
This work was supported by the Air Force Office of Scientific Research, the Department of Homeland Security Center of Excellence for Explosives Detection, Mitigation, and Response, and the Army Research Laboratory. Jeff Moore, Kevin Hart, Brett Krull, and Charles Diesendruck were also co-authors on the paper.
August Cassens | Eurek Alert!
Strength and ductility for alloys
27.05.2016 | Max-Planck-Institut für Eisenforschung GmbH
Computational high-throughput screening finds hard magnets containing less rare earth elements
25.05.2016 | Fraunhofer-Institut für Werkstoffmechanik IWM
A biological and energy-efficient process, developed and patented by the University of Innsbruck, converts nitrogen compounds in wastewater treatment facilities into harmless atmospheric nitrogen gas. This innovative technology is now being refined and marketed jointly with the United States’ DC Water and Sewer Authority (DC Water). The largest DEMON®-system in a wastewater treatment plant is currently being built in Washington, DC.
The DEMON®-system was developed and patented by the University of Innsbruck 11 years ago. Today this successful technology has been implemented in about 70...
Permanent magnets are very important for technologies of the future like electromobility and renewable energy, and rare earth elements (REE) are necessary for their manufacture. The Fraunhofer Institute for Mechanics of Materials IWM in Freiburg, Germany, has now succeeded in identifying promising approaches and materials for new permanent magnets through use of an in-house simulation process based on high-throughput screening (HTS). The team was able to improve magnetic properties this way and at the same time replaced REE with elements that are less expensive and readily available. The results were published in the online technical journal “Scientific Reports”.
The starting point for IWM researchers Wolfgang Körner, Georg Krugel, and Christian Elsässer was a neodymium-iron-nitrogen compound based on a type of...
In the Beyond EUV project, the Fraunhofer Institutes for Laser Technology ILT in Aachen and for Applied Optics and Precision Engineering IOF in Jena are developing key technologies for the manufacture of a new generation of microchips using EUV radiation at a wavelength of 6.7 nm. The resulting structures are barely thicker than single atoms, and they make it possible to produce extremely integrated circuits for such items as wearables or mind-controlled prosthetic limbs.
In 1965 Gordon Moore formulated the law that came to be named after him, which states that the complexity of integrated circuits doubles every one to two...
Characterization of high-quality material reveals important details relevant to next generation nanoelectronic devices
Quantum mechanics is the field of physics governing the behavior of things on atomic scales, where things work very differently from our everyday world.
When current comes in discrete packages: Viennese scientists unravel the quantum properties of the carbon material graphene
In 2010 the Nobel Prize in physics was awarded for the discovery of the exceptional material graphene, which consists of a single layer of carbon atoms...
24.05.2016 | Event News
20.05.2016 | Event News
19.05.2016 | Event News
27.05.2016 | Awards Funding
27.05.2016 | Life Sciences
27.05.2016 | Life Sciences