Researchers at the Department of Energy's Oak Ridge National Laboratory have obtained the first direct observations of atomic diffusion inside a bulk material. The research, which could be used to give unprecedented insight into the lifespan and properties of new materials, is published in the journal Physical Review Letters (06 October 2014, DOI: 10.1103/PhysRevLett.113.155501).
“This is the first time that anyone has directly imaged single dopant atoms moving around inside a material,” said Rohan Mishra of Vanderbilt University who is also a visiting scientist in ORNL’s Materials Science and Technology Division.
Selected frames from a sequence of scanning transmission electron microscope images showing the diffusion pathway of a Ce dopant (the bright atom highlighted with a white arrow) as it moves inside a bulk AlN crystal. The final frame overlays the Ce pathway on the Z-contrast image obtained by averaging each frame.
Semiconductors, which form the basis of modern electronics, are “doped” by adding a small number of impure atoms to tune their properties for specific applications. The study of the dopant atoms and how they move or “diffuse” inside a host lattice is a fundamental issue in materials research.
Traditionally, diffusion of atoms has been studied through indirect macroscopic methods or through theoretical calculations. Diffusion of single atoms has previously been directly observed only on the surface of materials.
The experiment also allowed the researchers to test a surprising prediction: Theory-based calculations for dopant motion in aluminum nitride predicted faster diffusion for cerium atoms than for manganese atoms. This prediction is surprising as cerium atoms are larger than manganese atoms.
“It’s completely counterintuitive that a bigger, heavier atom would move faster than a smaller, lighter atom,” said the Material Science and Technology Division’s Andrew Lupini, a coauthor of the paper.
In the study, the researchers used a scanning transmission electron microscope to observe the diffusion processes of cerium and manganese dopant atoms. The images they captured showed that the larger cerium atoms readily diffused through the material, while the smaller manganese atoms remained fixed in place.
The team’s work could be directly applied in basic material design and technologies such as energy-saving LED lights where dopants can affect color and atom movement can determine the failure modes.
“Diffusion governs how dopants get inside a material and how they move,” said Lupini. “Our study gives a strategy for choosing which dopants will lead to a longer device lifetime.”
See videos of manganese and cerium atom dopant jumps.
This research was conducted in part at ORNL and Lawrence Berkeley National Laboratory’s National Energy Research Scientific Computing Center, a DOE Office of Science User Facility.
The study was funded by the DOE Office of Science, the Australian Research Council, Vanderbilt University and the Japan Society for the Promotion of Science Postdoctoral Fellowship for research abroad.
The project’s authors include Ryo Ishikawa of Oak Ridge National Laboratory and the University of Tokyo; Scott Findlay of Monash University; Takashi Taniguchi of the National Institute for Materials Science; Sokrates Pantelides of Oak Ridge National Laboratory and Vanderbilt University; and Stephen Pennycook of the University of Tennessee.
UT-Battelle manages ORNL for the Department of Energy’s Office of Science. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit http://science.energy.gov/.
Oak Ridge National Laboratory
Chris Samoray | newswise
New gel-like coating beefs up the performance of lithium-sulfur batteries
22.03.2017 | Yale University
Pulverizing electronic waste is green, clean -- and cold
22.03.2017 | Rice University
Astronomers from Bonn and Tautenburg in Thuringia (Germany) used the 100-m radio telescope at Effelsberg to observe several galaxy clusters. At the edges of these large accumulations of dark matter, stellar systems (galaxies), hot gas, and charged particles, they found magnetic fields that are exceptionally ordered over distances of many million light years. This makes them the most extended magnetic fields in the universe known so far.
The results will be published on March 22 in the journal „Astronomy & Astrophysics“.
Galaxy clusters are the largest gravitationally bound structures in the universe. With a typical extent of about 10 million light years, i.e. 100 times the...
Researchers at the Goethe University Frankfurt, together with partners from the University of Tübingen in Germany and Queen Mary University as well as Francis Crick Institute from London (UK) have developed a novel technology to decipher the secret ubiquitin code.
Ubiquitin is a small protein that can be linked to other cellular proteins, thereby controlling and modulating their functions. The attachment occurs in many...
In the eternal search for next generation high-efficiency solar cells and LEDs, scientists at Los Alamos National Laboratory and their partners are creating...
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are less stable. Now researchers at the Technical University of Munich (TUM) have, for the first time ever, produced a composite material combining silicon nanosheets and a polymer that is both UV-resistant and easy to process. This brings the scientists a significant step closer to industrial applications like flexible displays and photosensors.
Silicon nanosheets are thin, two-dimensional layers with exceptional optoelectronic properties very similar to those of graphene. Albeit, the nanosheets are...
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to simulate these confined natural conditions in artificial vesicles for the first time. As reported in the academic journal Small, the results are offering better insight into the development of nanoreactors and artificial organelles.
Enzymes behave differently in a test tube compared with the molecular scrum of a living cell. Chemists from the University of Basel have now been able to...
20.03.2017 | Event News
14.03.2017 | Event News
07.03.2017 | Event News
22.03.2017 | Materials Sciences
22.03.2017 | Physics and Astronomy
22.03.2017 | Materials Sciences