Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

ORNL Researchers Make First Observation of Atoms Moving Inside Bulk Material

14.10.2014

Researchers at the Department of Energy's Oak Ridge National Laboratory have obtained the first direct observations of atomic diffusion inside a bulk material. The research, which could be used to give unprecedented insight into the lifespan and properties of new materials, is published in the journal Physical Review Letters (06 October 2014, DOI: 10.1103/PhysRevLett.113.155501).

“This is the first time that anyone has directly imaged single dopant atoms moving around inside a material,” said Rohan Mishra of Vanderbilt University who is also a visiting scientist in ORNL’s Materials Science and Technology Division.


ORNL

Selected frames from a sequence of scanning transmission electron microscope images showing the diffusion pathway of a Ce dopant (the bright atom highlighted with a white arrow) as it moves inside a bulk AlN crystal. The final frame overlays the Ce pathway on the Z-contrast image obtained by averaging each frame.

Semiconductors, which form the basis of modern electronics, are “doped” by adding a small number of impure atoms to tune their properties for specific applications. The study of the dopant atoms and how they move or “diffuse” inside a host lattice is a fundamental issue in materials research.

Traditionally, diffusion of atoms has been studied through indirect macroscopic methods or through theoretical calculations. Diffusion of single atoms has previously been directly observed only on the surface of materials.

The experiment also allowed the researchers to test a surprising prediction: Theory-based calculations for dopant motion in aluminum nitride predicted faster diffusion for cerium atoms than for manganese atoms. This prediction is surprising as cerium atoms are larger than manganese atoms.

“It’s completely counterintuitive that a bigger, heavier atom would move faster than a smaller, lighter atom,” said the Material Science and Technology Division’s Andrew Lupini, a coauthor of the paper.

In the study, the researchers used a scanning transmission electron microscope to observe the diffusion processes of cerium and manganese dopant atoms. The images they captured showed that the larger cerium atoms readily diffused through the material, while the smaller manganese atoms remained fixed in place.

The team’s work could be directly applied in basic material design and technologies such as energy-saving LED lights where dopants can affect color and atom movement can determine the failure modes.

“Diffusion governs how dopants get inside a material and how they move,” said Lupini. “Our study gives a strategy for choosing which dopants will lead to a longer device lifetime.”

See videos of manganese and cerium atom dopant jumps.
This research was conducted in part at ORNL and Lawrence Berkeley National Laboratory’s National Energy Research Scientific Computing Center, a DOE Office of Science User Facility.

The study was funded by the DOE Office of Science, the Australian Research Council, Vanderbilt University and the Japan Society for the Promotion of Science Postdoctoral Fellowship for research abroad.

The project’s authors include Ryo Ishikawa of Oak Ridge National Laboratory and the University of Tokyo; Scott Findlay of Monash University; Takashi Taniguchi of the National Institute for Materials Science; Sokrates Pantelides of Oak Ridge National Laboratory and Vanderbilt University; and Stephen Pennycook of the University of Tennessee.

UT-Battelle manages ORNL for the Department of Energy’s Office of Science. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit http://science.energy.gov/.

Contact Information

Chris Samoray
Oak Ridge National Laboratory
865-241-0709; samoraycr@ornl.gov

Chris Samoray | newswise

More articles from Materials Sciences:

nachricht Physics, photosynthesis and solar cells
01.12.2016 | University of California - Riverside

nachricht New process produces hydrogen at much lower temperature
01.12.2016 | Waseda University

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Novel silicon etching technique crafts 3-D gradient refractive index micro-optics

A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.

Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...

Im Focus: Quantum Particles Form Droplets

In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.

“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...

Im Focus: MADMAX: Max Planck Institute for Physics takes up axion research

The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.

The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...

Im Focus: Molecules change shape when wet

Broadband rotational spectroscopy unravels structural reshaping of isolated molecules in the gas phase to accommodate water

In two recent publications in the Journal of Chemical Physics and in the Journal of Physical Chemistry Letters, researchers around Melanie Schnell from the Max...

Im Focus: Fraunhofer ISE Develops Highly Compact, High Frequency DC/DC Converter for Aviation

The efficiency of power electronic systems is not solely dependent on electrical efficiency but also on weight, for example, in mobile systems. When the weight of relevant components and devices in airplanes, for instance, is reduced, fuel savings can be achieved and correspondingly greenhouse gas emissions decreased. New materials and components based on gallium nitride (GaN) can help to reduce weight and increase the efficiency. With these new materials, power electronic switches can be operated at higher switching frequency, resulting in higher power density and lower material costs.

Researchers at the Fraunhofer Institute for Solar Energy Systems ISE together with partners have investigated how these materials can be used to make power...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

ICTM Conference 2017: Production technology for turbomachine manufacturing of the future

16.11.2016 | Event News

Innovation Day Laser Technology – Laser Additive Manufacturing

01.11.2016 | Event News

#IC2S2: When Social Science meets Computer Science - GESIS will host the IC2S2 conference 2017

14.10.2016 | Event News

 
Latest News

UTSA study describes new minimally invasive device to treat cancer and other illnesses

02.12.2016 | Medical Engineering

Plasma-zapping process could yield trans fat-free soybean oil product

02.12.2016 | Agricultural and Forestry Science

What do Netflix, Google and planetary systems have in common?

02.12.2016 | Physics and Astronomy

VideoLinks
B2B-VideoLinks
More VideoLinks >>>