In a paper published in Advanced Materials, a team led by Amit Naskar of the Materials Science and Technology Division outlined a method that allows not only for production of carbon fiber but also the ability to tailor the final product to specific applications.
Carbon fibers having unique surface geometries, from circular to hollow gear-shaped, are produced from polyethylene using a versatile fabrication method. The resulting carbon fiber exhibits properties that are dependent on processing conditions, rendering them highly amenable to myriad applications.
"Our results represent what we believe will one day provide industry with a flexible technique for producing technologically innovative fibers in myriad configurations such as fiber bundle or non-woven mat assemblies," Naskar said.
Using a combination of multi-component fiber spinning and their sulfonation technique, Naskar and colleagues demonstrated that they can make polyethylene-base fibers with a customized surface contour and manipulate filament diameter down to the submicron scale. The patent-pending process also allows them to tune the porosity, making the material potentially useful for filtration, catalysis and electrochemical energy harvesting.
Naskar noted that the sulfonation process allows for great flexibility as the carbon fibers exhibit properties that are dictated by processing conditions. For this project, the researchers produced carbon fibers with unique cross-sectional geometry, from hollow circular to gear-shaped by using a multi-component melt extrusion-based fiber spinning method.
The possibilities are virtually endless, according to Naskar, who described the process.
"We dip the fiber bundle into an acid containing a chemical bath where it reacts and forms a black fiber that no longer will melt," Naskar said. "It is this sulfonation reaction that transforms the plastic fiber into an infusible form.
"At this stage, the plastic molecules bond, and with further heating cannot melt or flow. At very high temperatures, this fiber retains mostly carbon and all other elements volatize off in different gas or compound forms."
The researchers also noted that their discovery represents a success for DOE, which seeks advances in lightweight materials that can, among other things, help the U.S. auto industry design cars able to achieve more miles per gallon with no compromise in safety or comfort. And the raw material, which could come from grocery store plastic bags, carpet backing scraps and salvage, is abundant and inexpensive.
Other authors of the paper, titled "Patterned functional carbon fibers from polyethylene," are Marcus Hunt, Tomonori Saito and Rebecca Brown of ORNL and Amar Kumbhar of the University of North Carolina's Chapel Hill Analytical and Nanofabrication Laboratory. The paper is published on line here: http://onlinelibrary.wiley.com/doi/10.1002/adma.201104551/pdf
Funding was provided by DOE's Office of Energy Efficiency and Renewable Energy (http://www.eere.energy.gov/). UT-Battelle manages ORNL for DOE's Office of Science, the single largest supporter of basic research in the physical sciences in the United States. The Office of Science is working to address some of the most pressing challenges of our time. For more information, please visit http://science.energy.gov/
Ron Walli | EurekAlert!
A new tool for discovering nanoporous materials
23.05.2017 | Ecole Polytechnique Fédérale de Lausanne
Did you know that packaging is becoming intelligent through flash systems?
23.05.2017 | Heraeus Noblelight GmbH
Staphylococcus aureus is a feared pathogen (MRSA, multi-resistant S. aureus) due to frequent resistances against many antibiotics, especially in hospital infections. Researchers at the Paul-Ehrlich-Institut have identified immunological processes that prevent a successful immune response directed against the pathogenic agent. The delivery of bacterial proteins with RNA adjuvant or messenger RNA (mRNA) into immune cells allows the re-direction of the immune response towards an active defense against S. aureus. This could be of significant importance for the development of an effective vaccine. PLOS Pathogens has published these research results online on 25 May 2017.
Staphylococcus aureus (S. aureus) is a bacterium that colonizes by far more than half of the skin and the mucosa of adults, usually without causing infections....
Physicists from the University of Würzburg are capable of generating identical looking single light particles at the push of a button. Two new studies now demonstrate the potential this method holds.
The quantum computer has fuelled the imagination of scientists for decades: It is based on fundamentally different phenomena than a conventional computer....
An international team of physicists has monitored the scattering behaviour of electrons in a non-conducting material in real-time. Their insights could be beneficial for radiotherapy.
We can refer to electrons in non-conducting materials as ‘sluggish’. Typically, they remain fixed in a location, deep inside an atomic composite. It is hence...
Two-dimensional magnetic structures are regarded as a promising material for new types of data storage, since the magnetic properties of individual molecular building blocks can be investigated and modified. For the first time, researchers have now produced a wafer-thin ferrimagnet, in which molecules with different magnetic centers arrange themselves on a gold surface to form a checkerboard pattern. Scientists at the Swiss Nanoscience Institute at the University of Basel and the Paul Scherrer Institute published their findings in the journal Nature Communications.
Ferrimagnets are composed of two centers which are magnetized at different strengths and point in opposing directions. Two-dimensional, quasi-flat ferrimagnets...
An Australian-Chinese research team has created the world's thinnest hologram, paving the way towards the integration of 3D holography into everyday...
24.05.2017 | Event News
23.05.2017 | Event News
22.05.2017 | Event News
26.05.2017 | Life Sciences
26.05.2017 | Life Sciences
26.05.2017 | Physics and Astronomy