A team led by Hansan Liu, Gilbert Brown and Parans Paranthaman of the Department of Energy lab's Chemical Sciences Division found that titanium dioxide creates a highly desirable material that increases surface area and features a fast charge-discharge capability for lithium ion batteries. Compared to conventional technologies, the differences in charge time and capacity are striking.
"We can charge our battery to 50 percent of full capacity in six minutes while the traditional graphite-based lithium ion battery would be just 10 percent charged at the same current," Liu said.
Compared to commercial lithium titanate material, the ORNL compound also boasts a higher capacity – 256 vs. 165 milliampere hour per gram – and a sloping discharge voltage that is good for controlling state of charge. This characteristic combined with the fact oxide materials are extremely safe and long-lasting alternatives to commercial graphite make it well-suited for hybrid electric vehicles and other high-power applications.
The results, recently published in Advanced Materials, could also have special significance for applications in stationary energy storage systems for solar and wind power, and for smart grids. The titanium dioxide with a bronze polymorph also has the advantage of being potentially inexpensive, according to Liu.
At the heart of the breakthrough is the novel architecture of titanium dioxide, named mesoporous TiO2-B microspheres, which features channels and pores that allow for unimpeded flow of ions with a capacitor-like mechanism. Consequently, a lithium ion battery that substitutes TiO2-B for the graphite electrode charges and discharges quickly.
"Theoretical studies have uncovered that this pseudocapacitive behavior originates from the unique sites and energetics of lithium absorption and diffusion in TiO2-B structure," the authors write in their paper, titled "Mesoporous TiO2-B Microspheres with Superior Rate Performance for Lithium Ion Batteries."
Paranthaman noted that the microsphere shape of the material allows for traditional electrode fabrication and creates compact electrode layers. He also observed, however, that the production process of this material is complex and involves many steps, so more research remains to determine whether it is scalable.
Other authors of the paper are Zhonghe Bi, Xiao-Guang Sun, Raymond Unocic and Sheng Dai. The research was supported by DOE's Office of Science, ORNL's Laboratory Directed Research and Development program, and ORNL's SHaRE User Facility, which is sponsored by Basic Energy Sciences.
ORNL is managed by UT-Battelle for the Department of Energy's Office of Science.
NOTE TO EDITORS: You may read other press releases from Oak Ridge National Laboratory or learn more about the lab at http://www.ornl.gov/news. Additional information about ORNL is available at the sites below:
Twitter - http://twitter.com/oakridgelabnews
RSS Feeds - http://www.ornl.gov/ornlhome/rss_feeds.shtml
Flickr - http://www.flickr.com/photos/oakridgelab
YouTube - http://www.youtube.com/user/OakRidgeNationalLab
LinkedIn - http://www.linkedin.com/companies/oak-ridge-national-laboratory
Facebook - http://www.facebook.com/Oak.Ridge.National.Laboratory
Ron Walli | EurekAlert!
Scientists announce the quest for high-index materials
24.07.2017 | Moscow Institute of Physics and Technology
ADIR Project: Lasers Recover Valuable Materials
24.07.2017 | Fraunhofer-Institut für Lasertechnik ILT
3-D shape acquisition using water displacement as the shape sensor for the reconstruction of complex objects
A global team of computer scientists and engineers have developed an innovative technique that more completely reconstructs challenging 3D objects. An ancient...
Physicists have developed a new technique that uses electrical voltages to control the electron spin on a chip. The newly-developed method provides protection from spin decay, meaning that the contained information can be maintained and transmitted over comparatively large distances, as has been demonstrated by a team from the University of Basel’s Department of Physics and the Swiss Nanoscience Institute. The results have been published in Physical Review X.
For several years, researchers have been trying to use the spin of an electron to store and transmit information. The spin of each electron is always coupled...
What is the mass of a proton? Scientists from Germany and Japan successfully did an important step towards the most exact knowledge of this fundamental constant. By means of precision measurements on a single proton, they could improve the precision by a factor of three and also correct the existing value.
To determine the mass of a single proton still more accurate – a group of physicists led by Klaus Blaum and Sven Sturm of the Max Planck Institute for Nuclear...
The research team of Prof. Dr. Oliver Einsle at the University of Freiburg's Institute of Biochemistry has long been exploring the functioning of nitrogenase....
A one trillion tonne iceberg - one of the biggest ever recorded -- has calved away from the Larsen C Ice Shelf in Antarctica, after a rift in the ice,...
21.07.2017 | Event News
19.07.2017 | Event News
12.07.2017 | Event News
24.07.2017 | Power and Electrical Engineering
24.07.2017 | Materials Sciences
24.07.2017 | Materials Sciences