Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

New insight into thermoelectric materials may boost green technologies

15.05.2014

A University of Miami physicist and his collaborators find remarkable thermoelectric properties for a metal that may impact the search for materials useful in power generation, refrigeration or energy detection

Thermoelectric materials can turn a temperature difference into an electric voltage. Among their uses in a variety of specialized applications: generating power on space probes and cooling seats in fancy cars.


Lithium purple-bronze (LiPB) is a thermoelectric material comprised of aligned conducting, zig-zag chains of molybdenum and oxygen (left image, pink and white circles with green bonds). When an electric current was applied in a direction slightly misaligned with the chains (depicted as gray lines, right image), heat flowed perpendicular to the current, a phenomenon known as the transverse Peltier effect. The efficiency of this effect in LiPB was among the largest known for a single compound.

Credit: Dr. Joshua Cohn, University of Miami

University of Miami (UM) physicist Joshua Cohn and his collaborators report new surprising properties of a metal named lithium purple-bronze (LiPB) that may impact the search for materials useful in power generation, refrigeration, or energy detection. The findings are published in the journal Physical Review Letters.

"If current efficiencies of thermoelectric materials were doubled, thermoelectric coolers might replace the conventional gas refrigerators in your home," said Cohn, professor and chairman of the UM Department of Physics in the College of Arts and Sciences and lead author of the study. "Converting waste heat into electric power, for example, using vehicle exhaust, is a near-term 'green' application of such materials."

Useful thermoelectric materials produce a large voltage for a given temperature difference, with the ratio known as "thermopower." LiPB is comprised of aligned conducting chains. The researchers found that this material has very different thermopowers when the temperature difference is applied parallel or perpendicular to the conducting chains.

When an electric current was applied in a direction slightly misaligned with the chains, heat flowed perpendicular to the current, a phenomenon known as the "transverse Peltier effect." The efficiency of this effect in LiPB was among the largest known for a single compound.

"That such a large directional difference in thermopower exists in a single compound is exceedingly rare and makes applications possible," Cohn said. "This is significant because transverse Peltier devices typically employ a sandwich of different compounds that is more complicated and costly to fabricate."

As their motivation for the work, Cohn noted that metals with a similar electronic structure often exhibit interesting physics and the thermoelectric properties of LiPB had never been studied in detail. "The present material," he said, "might be useful as it is, but the larger implication of our work is that the ingredients underlying its special properties may serve as a guide to finding or engineering new and improved materials."

###

The study is titled "Extreme Thermopower Anisotropy and Interchain Transport in the Quasi-One-Dimensional Metal Li0.9Mo6O17" Other authors of the study are Saeed Moshfeghyeganeh,Ph.D. student in the Department of Physics at UM; Carlos A. M. dos Santos, professor at the Escola de Engenharia de Lorena in Brazil and John J. Neumeier, professor in the Department of Physics, Montana State University.

Annette Gallagher | Eurek Alert!
Further information:
http://www.miami.edu/

More articles from Materials Sciences:

nachricht Melting solid below the freezing point
23.01.2017 | Carnegie Institution for Science

nachricht An innovative high-performance material: biofibers made from green lacewing silk
20.01.2017 | Fraunhofer-Institut für Angewandte Polymerforschung IAP

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Quantum optical sensor for the first time tested in space – with a laser system from Berlin

For the first time ever, a cloud of ultra-cold atoms has been successfully created in space on board of a sounding rocket. The MAIUS mission demonstrates that quantum optical sensors can be operated even in harsh environments like space – a prerequi-site for finding answers to the most challenging questions of fundamental physics and an important innovation driver for everyday applications.

According to Albert Einstein's Equivalence Principle, all bodies are accelerated at the same rate by the Earth's gravity, regardless of their properties. This...

Im Focus: Traffic jam in empty space

New success for Konstanz physicists in studying the quantum vacuum

An important step towards a completely new experimental access to quantum physics has been made at University of Konstanz. The team of scientists headed by...

Im Focus: How gut bacteria can make us ill

HZI researchers decipher infection mechanisms of Yersinia and immune responses of the host

Yersiniae cause severe intestinal infections. Studies using Yersinia pseudotuberculosis as a model organism aim to elucidate the infection mechanisms of these...

Im Focus: Interfacial Superconductivity: Magnetic and superconducting order revealed simultaneously

Researchers from the University of Hamburg in Germany, in collaboration with colleagues from the University of Aarhus in Denmark, have synthesized a new superconducting material by growing a few layers of an antiferromagnetic transition-metal chalcogenide on a bismuth-based topological insulator, both being non-superconducting materials.

While superconductivity and magnetism are generally believed to be mutually exclusive, surprisingly, in this new material, superconducting correlations...

Im Focus: Studying fundamental particles in materials

Laser-driving of semimetals allows creating novel quasiparticle states within condensed matter systems and switching between different states on ultrafast time scales

Studying properties of fundamental particles in condensed matter systems is a promising approach to quantum field theory. Quasiparticles offer the opportunity...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

Sustainable Water use in Agriculture in Eastern Europe and Central Asia

19.01.2017 | Event News

12V, 48V, high-voltage – trends in E/E automotive architecture

10.01.2017 | Event News

2nd Conference on Non-Textual Information on 10 and 11 May 2017 in Hannover

09.01.2017 | Event News

 
Latest News

Tracking movement of immune cells identifies key first steps in inflammatory arthritis

23.01.2017 | Health and Medicine

Electrocatalysis can advance green transition

23.01.2017 | Physics and Astronomy

New technology for mass-production of complex molded composite components

23.01.2017 | Process Engineering

VideoLinks
B2B-VideoLinks
More VideoLinks >>>