These circular chambers were designed to amplify and direct sound waves so that, when standing in the right spot, a whisper could be heard from across the room. Now, scientists at the University of Pennsylvania have applied the same principle on the nanoscale to drastically reduce emission lifetime, a key property of semiconductors, which can lead to the development of new ultrafast photonic devices.
The research was conducted by associate professor Ritesh Agarwal, postdoctoral fellows Chang-Hee Cho and Sung-Wook Nam and graduate student Carlos O. Aspetti, all of the Department of Materials Science and Engineering in Penn’s School of Engineering and Applied Science. Michael E. Turk and James M. Kikkawa of the Department of Physics and Astronomy in the School of Arts and Sciences also contributed to the study.
Their research was published in the journal Nature Materials.
“When you excite a semiconductor, then it takes a few nanoseconds to get back to the ground state accompanied by emission of light,” Agarwal said. “That’s the emission lifetime. It’s roughly the amount of time the light is on, and hence is the amount of time it takes for it to be ready to be turned on again.
“If you’re making a modulator, something that switches back and forth, you’re limited by this time constant. What we’ve done is reduced it to less than a picosecond. It’s more than a thousand times faster than anything currently available.”
In semiconductors, the excited state is when energy is present in the system, and the ground state is when there is none. Normally, the semiconductor must first “cool down” in the excited state, releasing energy as heat, before “jumping” back to the ground state, releasing the remaining energy as light. The Penn team’s semiconductor nanowires, however, can jump directly from a high-energy excited state to the ground, all but eliminating the cool-down period.
The advancement in emission lifetime is due to the unique construction of the team’s nanowires. At their core, they are cadmium sulfide, a common nanowire material. But they are also wrapped in a buffer layer of silicon dioxide, and, critically, an outer layer of silver. The silver coating supports what are known as surface plasmons, unique waves that are a combination of oscillating metal electrons and of light. These surface plasmons are highly confined to the surface the silicon dioxide and silver layers meet.
“The previous state of the art was taking a nanowire, just like ours, and laying it on a metal surface,” Agarwal said. “We curved the metal surface around the wire, making a complete nanoscale plasmonic cavity and the whispering gallery effect.”
For certain nanowire sizes, the silver coating creates pockets of resonance and hence highly confined electromagnetic fields within the nanostructure. Emission lifetime can then be engineered by precisely controlling high intensity electromagnetic fields inside the light-emitting medium, which is the cadmium sulfide core.
To reach an emission lifetime measured in femtoseconds, the researchers needed to optimally balance this high-confinement electromagnetic field with an appropriate “quality factor,” the measurement of how good a cavity is at storing energy. To complicate matters, quality factor and confinement have an inverse relationship; the higher the quality-factor a cavity has the bigger it is and the smaller its confinement. However, by opting for a reasonable quality factor, the researchers could vastly increase the confinement of the electric field inside the nanowire by using resonant surface plasmons and get the record-breaking emission lifetime.
This many-orders-of-magnitude improvement could find a home in a variety of applications such as LEDs, detectors and other nanophotonic devices with novel properties.
“Plasmonic computers could make good use of these nanowires,” Cho said. “We could increase modulation speed into the terahertz range whereas electronic computers are limited to a few gigahertz range.”
“The same physics governs emission and absorption, so these nanowires could also be used for increasing efficiency of absorption in solar cells,” Agarwal said.
The research was supported by the U.S. Army Research Office, the National Institutes of Health, the National Science Foundation, Penn’s Nano/Bio Interface Center and the U.S. Department of Energy.
Evan Lerner | EurekAlert!
Serendipity uncovers borophene's potential
23.02.2017 | Northwestern University
20.02.2017 | Arizona State University
In the field of nanoscience, an international team of physicists with participants from Konstanz has achieved a breakthrough in understanding heat transport
Cells need to repair damaged DNA in our genes to prevent the development of cancer and other diseases. Our cells therefore activate and send “repair-proteins”...
The Fraunhofer IWS Dresden and Technische Universität Dresden inaugurated their jointly operated Center for Additive Manufacturing Dresden (AMCD) with a festive ceremony on February 7, 2017. Scientists from various disciplines perform research on materials, additive manufacturing processes and innovative technologies, which build up components in a layer by layer process. This technology opens up new horizons for component design and combinations of functions. For example during fabrication, electrical conductors and sensors are already able to be additively manufactured into components. They provide information about stress conditions of a product during operation.
The 3D-printing technology, or additive manufacturing as it is often called, has long made the step out of scientific research laboratories into industrial...
Nature does amazing things with limited design materials. Grass, for example, can support its own weight, resist strong wind loads, and recover after being...
Nanometer-scale magnetic perforated grids could create new possibilities for computing. Together with international colleagues, scientists from the Helmholtz Zentrum Dresden-Rossendorf (HZDR) have shown how a cobalt grid can be reliably programmed at room temperature. In addition they discovered that for every hole ("antidot") three magnetic states can be configured. The results have been published in the journal "Scientific Reports".
Physicist Dr. Rantej Bali from the HZDR, together with scientists from Singapore and Australia, designed a special grid structure in a thin layer of cobalt in...
13.02.2017 | Event News
10.02.2017 | Event News
09.02.2017 | Event News
24.02.2017 | Life Sciences
24.02.2017 | Life Sciences
24.02.2017 | Trade Fair News