Transparent polymeric films with near-uniform, continuous nanoprotrusions show high water pinning abilities
A*STAR researchers have used nanoimprinting methods to make patterned polymeric films with surface topography inspired by that of a rose petal, producing a range of transparent films with high water pinning forces(1).
A surface to which a water droplet adheres, even when it is turned upside down, is described as having strong water pinning characteristics. A rose petal and a lotus leaf are both superhydrophobic, yet dissimilarities in their water pinning properties cause a water droplet to stick to a rose petal but roll off a lotus leaf.
The two leaf types differ in their micro- and nanoscale surface topography and it is these topographical details that alter the water pinning force. The rose petal has almost uniformly distributed, conical-shaped microscale protrusions with nanoscale folds on these protrusions, while the lotus leaf has randomly distributed microscale protrusions.
The imprinted surfaces developed by Jaslyn Law and colleagues at the A*STAR Institute of Materials Research and Engineering and the Singapore University of Technology and Design have uniformly distributed patterns of nanoscale protrusions that are either conical or parabolic in shape.
The researchers found that the water pinning forces on these continuously patterned surfaces were much greater than on non-patterned surfaces and surfaces composed of isolated nanopillared structures or nanoscale gratings. They could then achieve high water pinning forces by patterning the nanoprotrusions onto polymeric films with a range of different non-patterned hydrophobicities, including polycarbonate, poly(methyl methacrylate) and polydimethylsiloxane (see image).
“Other methods that recreate the water pinning effect have used actual rose petals as the mold, but unless special care is taken, there are likely to be defects and inconsistencies in the recreated pattern,” says co-author Andrew Ng. “While bottom-up approaches for making patterns — for example, laser ablation, liquid flame spray or chemical vapor deposition — are more consistent, these methods are limited in the types of patterns that can be used and the scale at which a substrate can be patterned.”
In contrast, nanoimprinting methods are capable of fabricating versatile and large-scale surfaces, and can be combined with roll-to-roll techniques, hence potentially enabling more commercial applications.
The patterned polycarbonate surfaces were also shown to reduce the ‘coffee-ring’ effect: the unevenly deposited film left behind upon the evaporation of a solute-laden droplet. This mitigation of the coffee-ring effect may assist microfluidic technologies and, more generally, the patterned surfaces could be used in arid regions for dew collection or in anti-drip applications such as in greenhouses.
The A*STAR-affiliated researchers contributing to this research are from the Institute of Materials Research and Engineering
(1) Law, J. B. K., Ng, A. M. H., He, A. Y. & Low, H. Y. Bioinspired ultrahigh water pinning nanostructures. Langmuir 30, 325–331 (2014).
New approach to revolutionize the production of molecular hydrogen
22.05.2017 | Technische Universität Dresden
Photocatalyst makes hydrogen production 10 times more efficient
19.05.2017 | Kobe University
Two-dimensional magnetic structures are regarded as a promising material for new types of data storage, since the magnetic properties of individual molecular building blocks can be investigated and modified. For the first time, researchers have now produced a wafer-thin ferrimagnet, in which molecules with different magnetic centers arrange themselves on a gold surface to form a checkerboard pattern. Scientists at the Swiss Nanoscience Institute at the University of Basel and the Paul Scherrer Institute published their findings in the journal Nature Communications.
Ferrimagnets are composed of two centers which are magnetized at different strengths and point in opposing directions. Two-dimensional, quasi-flat ferrimagnets...
An Australian-Chinese research team has created the world's thinnest hologram, paving the way towards the integration of 3D holography into everyday...
In the race to produce a quantum computer, a number of projects are seeking a way to create quantum bits -- or qubits -- that are stable, meaning they are not much affected by changes in their environment. This normally needs highly nonlinear non-dissipative elements capable of functioning at very low temperatures.
In pursuit of this goal, researchers at EPFL's Laboratory of Photonics and Quantum Measurements LPQM (STI/SB), have investigated a nonlinear graphene-based...
Dental plaque and the viscous brown slime in drainpipes are two familiar examples of bacterial biofilms. Removing such bacterial depositions from surfaces is...
For the first time, scientists have succeeded in studying the strength of hydrogen bonds in a single molecule using an atomic force microscope. Researchers from the University of Basel’s Swiss Nanoscience Institute network have reported the results in the journal Science Advances.
Hydrogen is the most common element in the universe and is an integral part of almost all organic compounds. Molecules and sections of macromolecules are...
22.05.2017 | Event News
17.05.2017 | Event News
16.05.2017 | Event News
22.05.2017 | Materials Sciences
22.05.2017 | Life Sciences
22.05.2017 | Physics and Astronomy