Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

First Elucidation of Cause of Long-Term Stability Deterioration in Solid Oxide Fuel Cells

25.11.2011
NIMS and the University of Queensland Centre for Microscopy and Microanalysis, the Dalian Polytechnic University and the Dalian Institute of Chemical Physics clarified for the first time the cluster structure which has an extremely large effect on the long-term stability of solid oxide fuel cells for independent distributed power generation.

Dr. Toshiyuki Mori, Group Leader of the Hetero-interface Design Group, Battery and Fuel Cell Field, Global Research Center for Environment and Energy Based on Materials Science (GREEN), National Institute for Materials Science (President: Sukekatsu Ushioda), and Dr. Zhipeng Li, a Postdoctoral Researcher at GREEN, in joint research with Prof. John Drennan of the University of Queensland Centre for Microscopy and Microanalysis (Australia), the Dalian Polytechnic University (China), and the Dalian Institute of Chemical Physics, Chinese Academy of Science (China), clarified for the first time the cluster structure which has an extremely large effect on the long-term stability of solid oxide fuel cells (SOFC) for independent distributed power generation. This result was achieved by transmission electron microscope (TEM) observation and computer simulation based on the results thereof.

Active development of fuel cells for home use and large-scale generating systems using SOFC has been underway up to the present. However, while it was possible to manufacture devices which sufficiently satisfied performance requirements, elements of instability remained from the viewpoints of reliability and life, and these were major obstacles to practical application.

In this experiment, the nanoscale defect structures of high performance specimens and specimens which exhibited serious deterioration in performance were observed using a high resolution transmission electron microscope (TEM), and their distinctive features were then analyzed in computer simulations. This research ascertained for the first time that a “new oxygen defect cluster structure” which has a structure different from the “oxygen defect (oxygen vacancy) cluster structure” long considered to be the cause of reduced performance, forms in the material, triggering a phase transition, and this has a negative impact on the reliability and durability of fuel cells.

Various puzzling phenomena in SOFC, had been un-explained until now. These are (1) reason why a crystal phase transition occurs together with performance deterioration, (2) reason why adequate reliability cannot be maintained, etc., and they can be interpreted rationally using a model of this oxygen defect cluster structure. As a result effective solutions to these problems can be proposed based on materials science, and the development of high performance, high reliability, long life SOFC materials for use in independent distributed generation is expected to become possible.

These results were published online on November 7 in “Rapid communications” in the journal of the American Institute of Physics, Physical Review B.

Mikiko Tanifuji | Research asia research news
Further information:
http://www.­nims.­go.­jp/­eng/­
http://www.researchsea.com

More articles from Materials Sciences:

nachricht Manchester scientists tie the tightest knot ever achieved
13.01.2017 | University of Manchester

nachricht CWRU directly measures how perovskite solar films efficiently convert light to power
12.01.2017 | Case Western Reserve University

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Designing Architecture with Solar Building Envelopes

Among the general public, solar thermal energy is currently associated with dark blue, rectangular collectors on building roofs. Technologies are needed for aesthetically high quality architecture which offer the architect more room for manoeuvre when it comes to low- and plus-energy buildings. With the “ArKol” project, researchers at Fraunhofer ISE together with partners are currently developing two façade collectors for solar thermal energy generation, which permit a high degree of design flexibility: a strip collector for opaque façade sections and a solar thermal blind for transparent sections. The current state of the two developments will be presented at the BAU 2017 trade fair.

As part of the “ArKol – development of architecturally highly integrated façade collectors with heat pipes” project, Fraunhofer ISE together with its partners...

Im Focus: How to inflate a hardened concrete shell with a weight of 80 t

At TU Wien, an alternative for resource intensive formwork for the construction of concrete domes was developed. It is now used in a test dome for the Austrian Federal Railways Infrastructure (ÖBB Infrastruktur).

Concrete shells are efficient structures, but not very resource efficient. The formwork for the construction of concrete domes alone requires a high amount of...

Im Focus: Bacterial Pac Man molecule snaps at sugar

Many pathogens use certain sugar compounds from their host to help conceal themselves against the immune system. Scientists at the University of Bonn have now, in cooperation with researchers at the University of York in the United Kingdom, analyzed the dynamics of a bacterial molecule that is involved in this process. They demonstrate that the protein grabs onto the sugar molecule with a Pac Man-like chewing motion and holds it until it can be used. Their results could help design therapeutics that could make the protein poorer at grabbing and holding and hence compromise the pathogen in the host. The study has now been published in “Biophysical Journal”.

The cells of the mouth, nose and intestinal mucosa produce large quantities of a chemical called sialic acid. Many bacteria possess a special transport system...

Im Focus: Newly proposed reference datasets improve weather satellite data quality

UMD, NOAA collaboration demonstrates suitability of in-orbit datasets for weather satellite calibration

"Traffic and weather, together on the hour!" blasts your local radio station, while your smartphone knows the weather halfway across the world. A network of...

Im Focus: Repairing defects in fiber-reinforced plastics more efficiently

Fiber-reinforced plastics (FRP) are frequently used in the aeronautic and automobile industry. However, the repair of workpieces made of these composite materials is often less profitable than exchanging the part. In order to increase the lifetime of FRP parts and to make them more eco-efficient, the Laser Zentrum Hannover e.V. (LZH) and the Apodius GmbH want to combine a new measuring device for fiber layer orientation with an innovative laser-based repair process.

Defects in FRP pieces may be production or operation-related. Whether or not repair is cost-effective depends on the geometry of the defective area, the tools...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

12V, 48V, high-voltage – trends in E/E automotive architecture

10.01.2017 | Event News

2nd Conference on Non-Textual Information on 10 and 11 May 2017 in Hannover

09.01.2017 | Event News

Nothing will happen without batteries making it happen!

05.01.2017 | Event News

 
Latest News

Multiregional brain on a chip

16.01.2017 | Power and Electrical Engineering

New technology enables 5-D imaging in live animals, humans

16.01.2017 | Information Technology

Researchers develop environmentally friendly soy air filter

16.01.2017 | Power and Electrical Engineering

VideoLinks
B2B-VideoLinks
More VideoLinks >>>