A new strategy towards ultra-soft yet dry rubber
Medical implants mimic the softness of human tissue by mixing liquids such oil with long silicone polymers to create a squishy, wet gel. While implants have improved dramatically over the years, there is still a chance of the liquid leaking, which can be painful and sometimes dangerous.
This is an ultra-soft elastomer fabricated by crosslinking bottlebrush polymers contains only crosslinks (red chains) and no entanglements.
(Image courtesy of Li-Heng Cai, Harvard SEAS.)
Now, led by David A. Weitz, Mallinckrodt Professor of Physics and Applied Physics at Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS) and associate faculty member at the Wyss Institute for Biologically Inspired Engineering at Harvard, a team of polymer physicists and chemists has developed a way to create an ultra-soft dry silicone rubber. This new rubber features tunable softness to match a variety of biological tissues, opening new opportunities in biomedical research and engineering.
The material is featured on the cover of the journal Advanced Materials.
"Conventional elastomers are intrinsically stiff because of how they are made," said lead author Li-Heng Cai, a postdoctoral fellow at SEAS. "The network strands are very long and are entangled, similar to a bunch of Christmas lights, in which the cords are entangled and form knots. These fixed entanglements set up an intrinsic lower limit for the softness of conventional elastomers."
In order to fabricate a soft elastomer, the team needed to eliminate the entanglements from the beginning by developing a new type of polymer that was fatter and less prone to entanglement than linear polymers. The polymers, nicknamed bottlebrushes, are easily synthesized by mixing three types of commercially available linear silicone polymers.
"Typically the fabrication of such bottlebrush molecules requires complex chemical synthesis," said co-first author Thomas E. Kodger, Ph.D.' 2015, now a postdoctoral fellow at University of Amsterdam. "But we found a very simple strategy by carefully designing the chemistry. This system creates soft elastomers as easily as silicone kits sold commercially."
The softness of the elastomers can be precisely controlled by adjusting the amount of cross-linked polymers to mimic everything from soft brain tissue and relatively stiff cells.
"If there are no crosslinks, all the bottlebrush molecules are mobile and the material will flow like a viscous liquid such as honey," said Cai. "Adding crosslinks connects the bottlebrush molecules and solidifies the liquid, increasing the material stiffness."
In addition to controlling the softness, the team also found a way to independently control the liquid-like behavior of the elastomer.
"To make the conventional elastomer softer, one needs to swell it in a liquid," said coauthor Michael Rubinstein, John P. Barker Distinguished Professor in Chemistry at the University of North Carolina at Chapel Hill. "But now we can adjust the length of 'hairy' polymers on the bottlebrush molecules to tune the liquid-like behavior of soft elastomers -- without swelling -- allowing us to make these elastomers exceptionally non-adhesive yet ultra-soft."
These qualities make the material not only ideal for medical devices, such as implants, but also for commercial products such as cosmetics.
"The independent control over both softness and liquid-like behavior of the soft elastomers will also enable us to answer fundamental questions in biomedical research," said Weitz. "For example, stem cell differentiation not only depends on the softness of materials with which they are in contact, but recent findings suggest that it is also affected by how liquid-like the materials are. This discovery will provide entirely new materials to study the cell behavior on soft substrates."
"The exceptional combination of softness and negligible adhesiveness will greatly broaden the application of silicon-based elastomers in both industry and research," said Weitz.
In addition to his role on the faculty at SEAS, Weitz is the director of Harvard's Materials Research Science and Engineering Center, co-director of the BASF Advanced Research Initiative, a member of the Kavli Institute for Bionano Science and Technology, and an Associate Faculty Member at the Wyss Institute for Biologically Inspired Engineering.
In addition to Cai, Kodger, Weitz, and Rubinstein, coauthors included Rodrigo E. Guerra, Ph.D.' 2015, now a postdoctoral fellow at New York University; and Adrian F. Pegoraro, a postdoctoral fellow at SEAS.
This research was supported in part by the National Science Foundation (DMR-1310266) and the Harvard Materials Research Science and Engineering Center (DMR-1420570).
Leah Burrows | EurekAlert!
Physics, photosynthesis and solar cells
01.12.2016 | University of California - Riverside
New process produces hydrogen at much lower temperature
01.12.2016 | Waseda University
A multi-institutional research collaboration has created a novel approach for fabricating three-dimensional micro-optics through the shape-defined formation of porous silicon (PSi), with broad impacts in integrated optoelectronics, imaging, and photovoltaics.
Working with colleagues at Stanford and The Dow Chemical Company, researchers at the University of Illinois at Urbana-Champaign fabricated 3-D birefringent...
In experiments with magnetic atoms conducted at extremely low temperatures, scientists have demonstrated a unique phase of matter: The atoms form a new type of quantum liquid or quantum droplet state. These so called quantum droplets may preserve their form in absence of external confinement because of quantum effects. The joint team of experimental physicists from Innsbruck and theoretical physicists from Hannover report on their findings in the journal Physical Review X.
“Our Quantum droplets are in the gas phase but they still drop like a rock,” explains experimental physicist Francesca Ferlaino when talking about the...
The Max Planck Institute for Physics (MPP) is opening up a new research field. A workshop from November 21 - 22, 2016 will mark the start of activities for an innovative axion experiment. Axions are still only purely hypothetical particles. Their detection could solve two fundamental problems in particle physics: What dark matter consists of and why it has not yet been possible to directly observe a CP violation for the strong interaction.
The “MADMAX” project is the MPP’s commitment to axion research. Axions are so far only a theoretical prediction and are difficult to detect: on the one hand,...
Broadband rotational spectroscopy unravels structural reshaping of isolated molecules in the gas phase to accommodate water
In two recent publications in the Journal of Chemical Physics and in the Journal of Physical Chemistry Letters, researchers around Melanie Schnell from the Max...
The efficiency of power electronic systems is not solely dependent on electrical efficiency but also on weight, for example, in mobile systems. When the weight of relevant components and devices in airplanes, for instance, is reduced, fuel savings can be achieved and correspondingly greenhouse gas emissions decreased. New materials and components based on gallium nitride (GaN) can help to reduce weight and increase the efficiency. With these new materials, power electronic switches can be operated at higher switching frequency, resulting in higher power density and lower material costs.
Researchers at the Fraunhofer Institute for Solar Energy Systems ISE together with partners have investigated how these materials can be used to make power...
16.11.2016 | Event News
01.11.2016 | Event News
14.10.2016 | Event News
02.12.2016 | Medical Engineering
02.12.2016 | Agricultural and Forestry Science
02.12.2016 | Physics and Astronomy