Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Discovery of new material state counterintuitive to laws of physics

13.06.2013
When you squeeze something, it gets smaller. Unless you’re at Argonne National Laboratory.
At the suburban Chicago laboratory, a group of scientists has seemingly defied the laws of physics and found a way to apply pressure to make a material expand instead of compress/contract.

“It’s like squeezing a stone and forming a giant sponge,” said Karena Chapman, a chemist at the U.S. Department of Energy laboratory. “Materials are supposed to become denser and more compact under pressure. We are seeing the exact opposite. The pressure-treated material has half the density of the original state. This is counterintuitive to the laws of physics.”

Because this behavior seems impossible, Chapman and her colleagues spent several years testing and retesting the material until they believed the unbelievable and understood how the impossible could be possible. For every experiment, they got the same mind-bending results.

“The bonds in the material completely rearrange,” Chapman said. “This just blows my mind.”

This discovery will do more than rewrite the science text books; it could double the variety of porous framework materials available for manufacturing, health care and environmental sustainability.

Scientists use these framework materials, which have sponge-like holes in their structure, to trap, store and filter materials. The shape of the sponge-like holes makes them selectable for specific molecules, allowing their use as water filters, chemical sensors and compressible storage for carbon dioxide sequestration of hydrogen fuel cells. By tailoring release rates, scientists can adapt these frameworks to deliver drugs and initiate chemical reactions for the production of everything from plastics to foods.

“This could not only open up new materials to being porous, but it could also give us access to new structures for selectability and new release rates,” said Peter Chupas, an Argonne chemist who helped discover the new materials.

The team published the details of their work in the May 22 issue of the Journal of the American Chemical Society in an article titled “Exploiting High Pressures to Generate Porosity, Polymorphism, And Lattice Expansion in the Nonporous Molecular Framework Zn(CN)2 .”

The scientists put zinc cyanide, a material used in electroplating, in a diamond-anvil cell at the Advanced Photon Source (APS) at Argonne and applied high pressures of 0.9 to 1.8 gigapascals, or about 9,000 to 18,000 times the pressure of the atmosphere at sea level. This high pressure is within the range affordably reproducible by industry for bulk storage systems. By using different fluids around the material as it was squeezed, the scientists were able to create five new phases of material, two of which retained their new porous ability at normal pressure. The type of fluid used determined the shape of the sponge-like pores. This is the first time that hydrostatic pressure has been able to make dense materials with interpenetrated atomic frameworks into novel porous materials. Several series of in situ high-pressure X-ray powder diffraction experiments were performed at the 1-BM, 11-ID-B, and 17-BM beamlines of the APS to study the material transitions.

“By applying pressure, we were able to transform a normally dense, nonporous material into a range of new porous materials that can hold twice as much stuff,” Chapman said. “This counterintuitive discovery will likely double the amount of available porous framework materials, which will greatly expand their use in pharmaceutical delivery, sequestration, material separation and catalysis.”

The scientists will continue to test the new technique on other materials.

The research is funded by the U.S. Department of Energy's Office of Science.

The Advanced Photon Source at Argonne National Laboratory is one of five national synchrotron radiation light sources supported by the U.S. Department of Energy’s Office of Science to carry out applied and basic research to understand, predict, and ultimately control matter and energy at the electronic, atomic, and molecular levels, provide the foundations for new energy technologies, and support DOE missions in energy, environment, and national security. To learn more about the Office of Science X-ray user facilities, visit the Office of Science website.

Argonne National Laboratory seeks solutions to pressing national problems in science and technology. The nation's first national laboratory, Argonne conducts leading-edge basic and applied scientific research in virtually every scientific discipline. Argonne researchers work closely with researchers from hundreds of companies, universities, and federal, state and municipal agencies to help them solve their specific problems, advance America's scientific leadership and prepare the nation for a better future. With employees from more than 60 nations, Argonne is managed by UChicago Argonne, LLC for the U.S. Department of Energy's Office of Science.

Tona Kunz | EurekAlert!
Further information:
http://www.anl.gov

More articles from Materials Sciences:

nachricht Robust and functional – surface finishing by suspension spraying
19.09.2017 | Fraunhofer-Institut für Keramische Technologien und Systeme IKTS

nachricht Graphene and other carbon nanomaterials can replace scarce metals
19.09.2017 | Chalmers University of Technology

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Tiny lasers from a gallery of whispers

New technique promises tunable laser devices

Whispering gallery mode (WGM) resonators are used to make tiny micro-lasers, sensors, switches, routers and other devices. These tiny structures rely on a...

Im Focus: Ultrafast snapshots of relaxing electrons in solids

Using ultrafast flashes of laser and x-ray radiation, scientists at the Max Planck Institute of Quantum Optics (Garching, Germany) took snapshots of the briefest electron motion inside a solid material to date. The electron motion lasted only 750 billionths of the billionth of a second before it fainted, setting a new record of human capability to capture ultrafast processes inside solids!

When x-rays shine onto solid materials or large molecules, an electron is pushed away from its original place near the nucleus of the atom, leaving a hole...

Im Focus: Quantum Sensors Decipher Magnetic Ordering in a New Semiconducting Material

For the first time, physicists have successfully imaged spiral magnetic ordering in a multiferroic material. These materials are considered highly promising candidates for future data storage media. The researchers were able to prove their findings using unique quantum sensors that were developed at Basel University and that can analyze electromagnetic fields on the nanometer scale. The results – obtained by scientists from the University of Basel’s Department of Physics, the Swiss Nanoscience Institute, the University of Montpellier and several laboratories from University Paris-Saclay – were recently published in the journal Nature.

Multiferroics are materials that simultaneously react to electric and magnetic fields. These two properties are rarely found together, and their combined...

Im Focus: Fast, convenient & standardized: New lab innovation for automated tissue engineering & drug

MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems Holding GmbH about commercial use of a multi-well tissue plate for automated and reliable tissue engineering & drug testing.

MBM ScienceBridge GmbH successfully negotiated a license agreement between University Medical Center Göttingen (UMG) and the biotech company Tissue Systems...

Im Focus: Silencing bacteria

HZI researchers pave the way for new agents that render hospital pathogens mute

Pathogenic bacteria are becoming resistant to common antibiotics to an ever increasing degree. One of the most difficult germs is Pseudomonas aeruginosa, a...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

“Lasers in Composites Symposium” in Aachen – from Science to Application

19.09.2017 | Event News

I-ESA 2018 – Call for Papers

12.09.2017 | Event News

EMBO at Basel Life, a new conference on current and emerging life science research

06.09.2017 | Event News

 
Latest News

Molecular Force Sensors

20.09.2017 | Life Sciences

Producing electricity during flight

20.09.2017 | Power and Electrical Engineering

Tiny lasers from a gallery of whispers

20.09.2017 | Physics and Astronomy

VideoLinks
B2B-VideoLinks
More VideoLinks >>>