Forum for Science, Industry and Business

Sponsored by:     3M 
Search our Site:

 

Bringing Down the Cost of Fuel Cells

22.06.2012
Engineers at the University of Wisconsin-Milwaukee (UWM) have identified a catalyst that provides the same level of efficiency in microbial fuel cells (MFCs) as the currently used platinum catalyst, but at 5% of the cost.
Since more than 60% of the investment in making microbial fuel cells is the cost of platinum, the discovery may lead to much more affordable energy conversion and storage devices.

The material – nitrogen-enriched iron-carbon nanorods – also has the potential to replace the platinum catalyst used in hydrogen-producing microbial electrolysis cells (MECs), which use organic matter to generate a possible alternative to fossil fuels.

“Fuel cells are capable of directly converting fuel into electricity,” says UWM Professor Junhong Chen, who created the nanorods and is testing them with Assistant Professor Zhen (Jason) He. “With fuel cells, electrical power from renewable energy sources can be delivered where and when required, cleanly, efficiently and sustainably.”

The scientists also found that the nanorod catalyst outperformed a graphene-based alternative being developed elsewhere. In fact, the pair tested the material against two other contenders to replace platinum and found the nanorods’ performance consistently superior over a six-month period.

The nanorods have been proved stable and are scalable, says Chen, but more investigation is needed to determine how easily they can be mass-produced. More study is also required to determine the exact interaction responsible for the nanorods’ performance.

The work was published in March in the journal Advanced Materials ("Nitrogen-Enriched Core-Shell Structured Fe/Fe3C-C Nanorods as Advanced Catalysts for Oxygen Reduction Reaction").

The right recipe
MFCs generate electricity while removing organic contaminants from wastewater. On the anode electrode of an MFC, colonies of bacteria feed on organic matter, releasing electrons that create a current as they break down the waste.

On the cathode side, the most important reaction in MFCs is the oxygen reduction reaction (ORR). Platinum speeds this slow reaction, increasing efficiency of the cell, but it is expensive.

Microbial electrolysis cells (MECs) are related to MFCs. However, instead of electricity, MECs produce hydrogen. In addition to harnessing microorganisms at the anode, MECS also use decomposition of organic matter and platinum in a catalytic process at their cathodes.

Chen and He’s nanorods incorporate the best characteristics of other reactive materials, with nitrogen attached to the surface of the carbon rod and a core of iron carbide. Nitrogen’s effectiveness at improving the carbon catalyst is already well known. Iron carbide, also known for its catalytic capabilities, interacts with the carbon on the rod surface, providing “communication” with the core. Also, the material’s unique structure is optimal for electron transport, which is necessary for ORR.

When the nanorods were tested for potential use in MECs, the material did a better job than the graphene-based catalyst material, but it was still not as efficient as platinum.

“But it shows that there could be more diverse applications for this material, compared to graphene,” says He. “And it gave us clues for why the nanorods performed differently in MECs.”

Research with MECs was published in June in the journal Nano Energy ("Carbon/Iron-based Nanorod Catalysts for Hydrogen Production in Microbial Electrolysis Cells").

Zhen (Jason) He, UWM assistant professor of civil engineering, 414-229-5846, zhenhe@uwm.edu

Zhen (Jason) He | Newswise Science News
Further information:
http://www.uwm.edu

More articles from Materials Sciences:

nachricht Scientists channel graphene to understand filtration and ion transport into cells
11.12.2017 | National Institute of Standards and Technology (NIST)

nachricht Successful Mechanical Testing of Nanowires
07.12.2017 | Helmholtz-Zentrum Geesthacht - Zentrum für Material- und Küstenforschung

All articles from Materials Sciences >>>

The most recent press releases about innovation >>>

Die letzten 5 Focus-News des innovations-reports im Überblick:

Im Focus: Long-lived storage of a photonic qubit for worldwide teleportation

MPQ scientists achieve long storage times for photonic quantum bits which break the lower bound for direct teleportation in a global quantum network.

Concerning the development of quantum memories for the realization of global quantum networks, scientists of the Quantum Dynamics Division led by Professor...

Im Focus: Electromagnetic water cloak eliminates drag and wake

Detailed calculations show water cloaks are feasible with today's technology

Researchers have developed a water cloaking concept based on electromagnetic forces that could eliminate an object's wake, greatly reducing its drag while...

Im Focus: Scientists channel graphene to understand filtration and ion transport into cells

Tiny pores at a cell's entryway act as miniature bouncers, letting in some electrically charged atoms--ions--but blocking others. Operating as exquisitely sensitive filters, these "ion channels" play a critical role in biological functions such as muscle contraction and the firing of brain cells.

To rapidly transport the right ions through the cell membrane, the tiny channels rely on a complex interplay between the ions and surrounding molecules,...

Im Focus: Towards data storage at the single molecule level

The miniaturization of the current technology of storage media is hindered by fundamental limits of quantum mechanics. A new approach consists in using so-called spin-crossover molecules as the smallest possible storage unit. Similar to normal hard drives, these special molecules can save information via their magnetic state. A research team from Kiel University has now managed to successfully place a new class of spin-crossover molecules onto a surface and to improve the molecule’s storage capacity. The storage density of conventional hard drives could therefore theoretically be increased by more than one hundred fold. The study has been published in the scientific journal Nano Letters.

Over the past few years, the building blocks of storage media have gotten ever smaller. But further miniaturization of the current technology is hindered by...

Im Focus: Successful Mechanical Testing of Nanowires

With innovative experiments, researchers at the Helmholtz-Zentrums Geesthacht and the Technical University Hamburg unravel why tiny metallic structures are extremely strong

Light-weight and simultaneously strong – porous metallic nanomaterials promise interesting applications as, for instance, for future aeroplanes with enhanced...

All Focus news of the innovation-report >>>

Anzeige

Anzeige

Event News

See, understand and experience the work of the future

11.12.2017 | Event News

Innovative strategies to tackle parasitic worms

08.12.2017 | Event News

AKL’18: The opportunities and challenges of digitalization in the laser industry

07.12.2017 | Event News

 
Latest News

Plasmonic biosensors enable development of new easy-to-use health tests

14.12.2017 | Health and Medicine

New type of smart windows use liquid to switch from clear to reflective

14.12.2017 | Physics and Astronomy

BigH1 -- The key histone for male fertility

14.12.2017 | Life Sciences

VideoLinks
B2B-VideoLinks
More VideoLinks >>>